Rhodium Phosphine Olefin Complexes of the Weakly Coordinating Anions [BArF4]- and [1-closo-CB11H6Br6]-. Kinetic versus Thermodynamic Factors in Anion Coordination and Complex Reactivity

Solution and solid-state structures for the pair of complexes Rh{P(Cyp2)(η2-C5H7)}{η6-(C6H3(CF3)2)BArF3} and Rh{P(Cyp2)(η2-C5H7)}(1-closo-CB11H6Br6), which contain bound weakly coordinating anions,...