Self-repair of structural and functional composites with intrinsically self-healing polymer matrices: A review

Abstract Self-healing is a smart and promising way to make materials more reliable and longer lasting. In the case of structural or functional composites based on a polymer matrix, very often mechanical damage in the polymer matrix or debonding at the matrix–filler interface is responsible for the decrease in intended properties. This review describes the healing behavior in structural and functional polymer composites with a so-called intrinsically self-healing polymer as the continuous matrix. A clear similarity in the healing of structural and functional properties is demonstrated which can ultimately lead to the design of polymer composites that autonomously restore multiple properties using the same self-healing mechanism.

[1]  Anansa S. Ahmed,et al.  Morphing Soft Magnetic Composites , 2012, Advanced materials.

[2]  L. K. Lagorce,et al.  Magnetic and mechanical properties of micromachined strontium ferrite/polyimide composites , 1997 .

[3]  H. Colquhoun.  Self-repairing polymers: materials that heal themselves. , 2012, Nature chemistry.

[4]  P. Soroushian,et al.  Piezo-driven self-healing by electrochemical phenomena , 2013 .

[5]  A. Gu,et al.  Preparation of high thermal conductive aluminum nitride/cyanate ester nanocomposite using a new macromolecular coupling agent , 2012 .

[6]  K. Goodson,et al.  Thermal conductance enhancement of particle-filled thermal interface materials using carbon nanotube inclusions , 2004, The Ninth Intersociety Conference on Thermal and Thermomechanical Phenomena In Electronic Systems (IEEE Cat. No.04CH37543).

[7]  Ronald F. Gibson,et al.  A review of recent research on mechanics of multifunctional composite materials and structures , 2010 .

[8]  Haijun Zhang,et al.  Mechanical properties of silicone composites reinforced with micron- and nano-sized magnetic particles , 2013 .

[9]  Bodo Fiedler,et al.  Evaluation and identification of electrical and thermal conduction mechanisms in carbon nanotube/epoxy composites , 2006 .

[10]  Simon A. Hayes,et al.  A self-healing thermosetting composite material , 2007 .

[11]  Justin R. Kumpfer,et al.  Optically healable supramolecular polymers , 2011, Nature.

[12]  Kuo-Ning Chiang,et al.  Fabrication process simulation and reliability improvement of high-brightness LEDs , 2009, Microelectron. Reliab..

[13]  M. Urban,et al.  Self-Repairing Oxetane-Substituted Chitosan Polyurethane Networks , 2009, Science.

[14]  Ming Qiu Zhang,et al.  Self-Healing of Polymers via Synchronous Covalent Bond Fission/Radical Recombination , 2011 .

[15]  I. Kinloch,et al.  Ultra-low electrical percolation threshold in carbon-nanotube-epoxy composites , 2003 .

[16]  Robert J. Young,et al.  Crack propagation in a glass particle-filled epoxy resin , 1984 .

[17]  Xinling Wang,et al.  Synthesis and characterization of linear self-healing polyurethane based on thermally reversible Diels–Alder reaction , 2013 .

[18]  S. Alkoy,et al.  Piezoelectric Sensors and Sensor Materials , 1998 .

[19]  S. Blacher,et al.  Electrical and dielectric properties of carbon black filled co-continuous two-phase polymer blends , 1999 .

[20]  J. Lewis,et al.  Self-healing materials with microvascular networks. , 2007, Nature materials.

[21]  I. Bond,et al.  A hollow fibre reinforced polymer composite encompassing self-healing and enhanced damage visibility , 2005 .

[22]  M. Rong,et al.  Synthesis and characterization of epoxy with improved thermal remendability based on Diels-Alder reaction , 2010 .

[23]  S. Redner,et al.  Introduction To Percolation Theory , 2018 .

[24]  E. W. Meijer,et al.  Reversible polymers formed from self-complementary monomers using quadruple hydrogen bonding. , 1997, Science.

[25]  Thomas C Ward,et al.  Thermal characteristics of the self-healing response in poly(ethylene-co-methacrylic acid) copolymers , 2007, Journal of The Royal Society Interface.

[26]  Thomas C. Ward,et al.  Self-Healing of Poly(Ethylene-co-Methacrylic Acid) Copolymers Following Projectile Puncture , 2007 .

[27]  T. C. Bor,et al.  Review of current strategies to induce self-healing behaviour in fibre reinforced polymer based composites , 2014 .

[28]  Eric Vanlathem,et al.  Design of electrical conductive composites : key role of the morphology on the electrical properties of carbon black filled polymer blends , 1995 .

[29]  S. Zwaag,et al.  Development of a quasi-static test method to investigate the origin of self-healing in ionomers under ballistic conditions , 2008 .

[30]  M. Reboredo,et al.  Dielectric and magnetic response of Fe3O4/epoxy composites , 2009 .

[31]  W. Hayes,et al.  Design, synthesis and computational modelling of aromatic tweezer-molecules as models for chain-folding polymer blends , 2008 .

[32]  H. Manuspiya,et al.  Thermal conductivity and mechanical properties of BN-filled epoxy composite: effects of filler content, mixing conditions, and BN agglomerate size , 2011 .

[33]  Haiyang Yang,et al.  Thermal-responsive self-healing hydrogel based on hydrophobically modified chitosan and vesicle , 2013, Colloid and Polymer Science.

[34]  Leslie Eadie,et al.  Biomimicry in textiles: past, present and potential. An overview , 2011, Journal of The Royal Society Interface.

[35]  Constantinos Soutis,et al.  Fibre reinforced composites in aircraft construction , 2005 .

[36]  S. van der Zwaag,et al.  Self-healing thermally conductive adhesives , 2014 .

[37]  Y. Mai,et al.  Effects of particle size, particle/matrix interface adhesion and particle loading on mechanical properties of particulate–polymer composites , 2008 .

[38]  George P. Simon,et al.  Synthesis of a diamine cross-linker containing Diels–Alder adducts to produce self-healing thermosetting epoxy polymer from a widely used epoxy monomer , 2013 .

[39]  D. Leo,et al.  Softening and heating effects in ionic polymer transducers: An experimental investigation , 2013 .

[40]  W. Hayes,et al.  A novel self-healing supramolecular polymer system. , 2009, Faraday discussions.

[41]  T. Park,et al.  A highly stable quadruply hydrogen-bonded heterocomplex useful for supramolecular polymer blends. , 2005, Journal of the American Chemical Society.

[42]  N. Sottos,et al.  Autonomic healing of polymer composites , 2001, Nature.

[43]  Sybrand van der Zwaag,et al.  An Introduction to Material Design Principles: Damage Prevention versus Damage Management , 2007 .

[44]  Y. Bar-Cohen,et al.  Electroactive Polymer Actuators and Sensors , 2008 .

[45]  Patrick E. Phelan,et al.  Percolation theory applied to the analysis of thermal interface materials in flip-chip technology , 2000, ITHERM 2000. The Seventh Intersociety Conference on Thermal and Thermomechanical Phenomena in Electronic Systems (Cat. No.00CH37069).

[46]  M. Mahendran,et al.  Thermal and Magnetic studies of Ni–Mn–Ga/PU Polymer Composites , 2012 .

[47]  S. Zwaag,et al.  Autonomous damage initiated healing in a thermo‐responsive ionomer , 2010 .

[48]  Sybrand van der Zwaag,et al.  Increasing the reliability of solid state lighting systems via self-healing approaches: A review , 2012, Microelectron. Reliab..

[49]  Mohamad Amran Mohd Salleh,et al.  Effect of fibre coating and geometry on the tensile properties of hybrid carbon nanotube coated carbon fibre reinforced composite , 2014 .

[50]  Y. Seo,et al.  A large increase in the thermal conductivity of carbon nanotube/polymer composites produced by percolation phenomena , 2013 .

[51]  D. Heikens,et al.  The effect of interfacial adhesion on the tensile behavior of polystyrene–glass‐bead composites , 1983 .

[52]  Robert E Jensen,et al.  Reversibly cross-linked polymer gels as healing agents for epoxy-amine thermosets. , 2009, ACS applied materials & interfaces.

[53]  Ton Peijs,et al.  The extraordinary reinforcing efficiency of single-walled carbon nanotubes in oriented poly(vinyl alcohol) tapes , 2007 .

[54]  Bert Klumperman,et al.  Self-Healing Materials Based on Disulfide Links , 2011 .

[55]  S. Zwaag,et al.  Piezoelectric and mechanical properties of fatigue resistant, self-healing PZT–ionomer composites , 2014 .

[56]  Wenying Zhou.  Effect of coupling agents on the thermal conductivity of aluminum particle/epoxy resin composites , 2011 .

[57]  Nancy R. Sottos,et al.  Passive smart self-repair in polymer matrix composite materials , 1993, Smart Structures.

[58]  Yoseph Bar-Cohen,et al.  Electroactive polymers as artificial muscles: A review , 2002 .

[59]  Yoshifumi Amamoto,et al.  Thermal Reorganization and Molecular Weight Control of Dynamic Covalent Polymers Containing Alkoxyamines in Their Main Chains , 2007 .

[60]  N. Yoshie,et al.  Photoinduced mendable network polymer from poly(butylene adipate) end-functionalized with cinnamoyl groups , 2012 .

[61]  Yang Li,et al.  Polyelectrolyte Multilayers Impart Healability to Highly Electrically Conductive Films , 2012, Advanced materials.

[62]  Y. Tominaga,et al.  Anisotropic ionic conduction in composite polymer electrolytes filled with clays oriented by a strong magnetic field , 2013 .

[63]  Carolyn M. Dry,et al.  Procedures developed for self-repair of polymer matrix composite materials , 1996 .

[64]  Xiaoyong Zhang,et al.  A magnetic self-healing hydrogel. , 2012, Chemical communications.

[65]  K. Friedrich,et al.  Analysis of the interfacial interactions in polypropylene/silica nanocomposites , 2004 .

[66]  M. Iji,et al.  Factors affecting the magnitudes and anisotropies of the thermal and electrical conductivities of poly(l-lactic) acid composites with carbon fibers of various sizes , 2011 .

[67]  Sankha Banerjee,et al.  An investigation into the influence of electrically conductive particle size on electromechanical coupling and effective dielectric strain coefficients in three phase composite piezoelectric polymers , 2012 .

[68]  P. Cordier,et al.  Self-healing and thermoreversible rubber from supramolecular assembly , 2008, Nature.

[69]  P. Mather,et al.  A thermoplastic/thermoset blend exhibiting thermal mending and reversible adhesion. , 2009, ACS applied materials & interfaces.

[70]  Russell J. Varley,et al.  The effect of cluster plasticisation on the self healing behaviour of ionomers , 2010 .

[71]  Russell J. Varley,et al.  Towards an understanding of thermally activated self-healing of an ionomer system during ballistic penetration , 2008 .

[72]  K. Friedrich,et al.  Silica nanoparticles filled polypropylene: effects of particle surface treatment, matrix ductility and particle species on mechanical performance of the composites , 2005 .

[73]  P. Bandaru,et al.  Evidence of percolation related power law behavior in the thermal conductivity of nanotube/polymer composites , 2013 .

[74]  B. D. Agarwal,et al.  Analysis and Performance of Fiber Composites , 1980 .

[75]  Naoki Takano,et al.  Intelligent Material Systems Using Epoxy Particles to Repair Microcracks and Delamination Damage in GFRP , 1999 .

[76]  Thomas Speck,et al.  Restoration of tensile strength in bark samples of Ficus benjamina due to coagulation of latex during fast self-healing of fissures. , 2012, Annals of botany.

[77]  Y. Ohki,et al.  Development of epoxy/BN composites with high thermal conductivity and sufficient dielectric breakdown strength partI - sample preparations and thermal conductivity , 2011, IEEE Transactions on Dielectrics and Electrical Insulation.

[78]  Shing Chung Josh Wong,et al.  Electrical conductivity and dielectric properties of PMMA/expanded graphite composites , 2003 .

[79]  Aleksandra M. Vinogradov,et al.  Accomplishments and future trends in the field of electroactive polymers , 2008, SPIE Smart Structures and Materials + Nondestructive Evaluation and Health Monitoring.

[80]  U. Lafont,et al.  Influence of cross-linkers on the cohesive and adhesive self-healing ability of polysulfide-based thermosets. , 2012, ACS applied materials & interfaces.

[81]  M. Rong,et al.  Intrinsic self-healing of covalent polymers through bond reconnection towards strength restoration , 2013 .

[82]  Shaohua Yang,et al.  Analysis on failure modes and mechanisms of LED , 2009, 2009 8th International Conference on Reliability, Maintainability and Safety.

[83]  K. Char,et al.  Synthesis, self-assembly and reversible healing of supramolecular perfluoropolyethers , 2013 .

[84]  J. Thomason.  The influence of fibre length, diameter and concentration on the modulus of glass fibre reinforced polyamide 6,6 , 2008 .

[85]  L. Ye,et al.  Mechanical properties and toughening mechanisms of polypropylene/barium sulfate composites , 2003 .

[86]  Ying‐Ling Liu,et al.  Electrically driven self‐healing polymers based on reversible guest–host complexation of β‐cyclodextrin and ferrocene , 2013 .

[87]  Youchun Zhang,et al.  Thermally Self-Healing Polymeric Materials : The Next Step to Recycling Thermoset Polymers? , 2009 .

[88]  Ron Pelrine,et al.  High-Strain Actuator Materials Based on Dielectric Elastomers , 2000 .

[89]  Pingan Song,et al.  Effects of carbon nanotubes and its functionalization on the thermal and flammability properties of polypropylene/wood flour composites , 2010 .

[90]  M. C. Rezende,et al.  Effect of the interfacial adhesion on the tensile and impact properties of carbon fiber reinforced polypropylene matrices , 2005 .

[91]  Yaling Lin,et al.  Self‐healing supramolecular elastomers based on the multi‐hydrogen bonding of low‐molecular polydimethylsiloxanes: Synthesis and characterization , 2013 .

[92]  M. Yamaguchi,et al.  Effects of particle size on mechanical and impact properties of epoxy resin filled with spherical silica , 1992 .

[93]  Dilhan M. Kalyon,et al.  Electric and magnetic properties of a thermoplastic elastomer incorporated with ferromagnetic powders , 1993 .

[94]  Rashi Tiwari,et al.  The state of understanding of ionic polymer metal composite architecture: a review , 2011 .

[95]  G. Jorge,et al.  Magnetic and Conducting Properties of Composites of Conducting Polymers and Ferrite Nanoparticles , 2013, IEEE Transactions on Magnetics.

[96]  Q. Pei,et al.  High-speed electrically actuated elastomers with strain greater than 100% , 2000, Science.

[97]  M. Taya,et al.  Electrical and thermal conductivities of a silver flake/thermosetting polymer matrix composite , 2009 .

[98]  Hao Wang,et al.  A review on the tensile properties of natural fiber reinforced polymer composites , 2011 .

[99]  I. Chung,et al.  The effect of coupling agent on electrical and mechanical properties of carbon fiber/phenolic resin composites , 2000 .

[100]  Ming Qiu Zhang,et al.  Coumarin imparts repeated photochemical remendability to polyurethane , 2011 .

[101]  Kankanhalli N. Seetharamu,et al.  Thermal characterization of Al2O3 and ZnO reinforced silicone rubber as thermal pads for heat dissipation purposes , 2005 .

[102]  Pengchong Li,et al.  Facile fabrication method of hydrophobic-associating cross-linking hydrogel with outstanding mechanical performance and self-healing property in the absence of surfactants , 2013 .

[103]  Krzysztof Matyjaszewski,et al.  Self‐Healing of Covalently Cross‐Linked Polymers by Reshuffling Thiuram Disulfide Moieties in Air under Visible Light , 2012, Advanced materials.

[104]  Stijn Billiet,et al.  Chemistry of crosslinking processes for self-healing polymers. , 2013, Macromolecular rapid communications.

[105]  Geoffrey M. Spinks,et al.  Conducting Polmers as a Basis for Responsive Materials Systems , 1998 .

[106]  Ming Qiu Zhang,et al.  Photo-stimulated self-healing polyurethane containing dihydroxyl coumarin derivatives , 2012 .

[107]  T. Guo,et al.  Synthesis and evaluation of a moisture-promoted healing copolymer , 2012 .

[108]  R. M. Simon.  Emi Shielding Through Conductive Plastics , 1981 .

[109]  F. Tournilhac,et al.  Epoxy‐based networks combining chemical and supramolecular hydrogen‐bonding crosslinks , 2010 .

[110]  N. K. Singha,et al.  "Click chemistry" in tailor-made polymethacrylates bearing reactive furfuryl functionality: a new class of self-healing polymeric material. , 2009, ACS applied materials & interfaces.

[111]  H. Minami,et al.  Preparation and characterization of conducting polyaniline layered magnetic nano composite polymer particles , 2013 .

[112]  Jonathan Seppala,et al.  A healable supramolecular polymer blend based on aromatic pi-pi stacking and hydrogen-bonding interactions. , 2010, Journal of the American Chemical Society.

[113]  Akira Harada,et al.  Preorganized Hydrogel: Self‐Healing Properties of Supramolecular Hydrogels Formed by Polymerization of Host–Guest‐Monomers that Contain Cyclodextrins and Hydrophobic Guest Groups , 2013, Advanced materials.

[114]  R. Spontak,et al.  Bridged double percolation in conductive polymer composites: an electrical conductivity, morphology and mechanical property study , 2002 .

[115]  Benjamin C. K. Tee,et al.  An electrically and mechanically self-healing composite with pressure- and flexion-sensitive properties for electronic skin applications. , 2012, Nature nanotechnology.

[116]  Mpf Mark Pepels,et al.  Self-healing systems based on disulfide–thiol exchange reactions , 2013 .

[117]  Santiago J. Garcia,et al.  Effect of polymer architecture on the intrinsic self-healing character of polymers , 2014 .

[118]  Qiang Fu,et al.  Controlling the dynamic percolation of carbon nanotube based conductive polymer composites by addition of secondary nanofillers: The effect on electrical conductivity and tuneable sensing behaviour , 2013 .

[119]  Raju V. Ramanujan,et al.  Novel Coiling Behavior in Magnet‐Polymer Composites , 2010 .

[120]  C. Jegat,et al.  Thermally reversible crosslinked polyethylene using Diels–Alder reaction in molten state , 2010 .

[121]  N. Sottos,et al.  Restoration of Large Damage Volumes in Polymers , 2014, Science.

[122]  P. Ren,et al.  Thermal, Mechanical and Electrical Properties of Linear Low-Density Polyethylene Composites Filled with Different Dimensional SiC Particles , 2011 .

[123]  Michael D. Dickey,et al.  Self‐Healing Stretchable Wires for Reconfigurable Circuit Wiring and 3D Microfluidics , 2013, Advanced materials.

[124]  A. Bhowmick,et al.  A review on the mechanical and electrical properties of graphite and modified graphite reinforced polymer composites , 2011 .

[125]  Krzysztof Matyjaszewski,et al.  Repeatable photoinduced self-healing of covalently cross-linked polymers through reshuffling of trithiocarbonate units. , 2011, Angewandte Chemie.

[126]  Yves Grohens,et al.  Conductive polymer composites: comparative study of poly(ester)-short carbon fibres and poly(epoxy)-short carbon fibres mechanical and electrical properties , 2002 .

[127]  Junhong Lin,et al.  Enhanced Electromechanical Response of Ionic Polymer Actuators by Improving Mechanical Coupling between Ions and Polymer Matrix , 2012 .

[128]  J. Lee,et al.  PROGRESS IN PREPARATION, PROCESSING AND APPLICATIONS OF POLYANILINE , 2009 .

[129]  M. P. Stevens,et al.  Thermally reversible crosslinking of polystyrene via the furan-maleimide diels-alder reaction , 1992 .

[130]  Ying‐Ling Liu,et al.  Thermally reversible cross-linked polyamides and thermo-responsive gels by means of Diels–Alder reaction , 2006 .

[131]  Zhenan Bao,et al.  Self-healing chemistry enables the stable operation of silicon microparticle anodes for high-energy lithium-ion batteries. , 2013, Nature chemistry.

[132]  Atsushi Takahara,et al.  A Thermodynamic Polymer Cross-Linking System Based on Radically Exchangeable Covalent Bonds , 2006 .

[133]  Amy M. Peterson,et al.  Thermoreversible and remendable glass–polymer interface for fiber-reinforced composites , 2011 .

[134]  J. Hao,et al.  Remarkable improvements in the stability and thermal conductivity of graphite/ethylene glycol nanofluids caused by a graphene oxide percolation structure. , 2013, Dalton transactions.

[135]  Jie Yin,et al.  Preparation and properties of Organosoluble polyimide/ silica hybrid materials by sol-gel process , 1999 .

[136]  Shunsuke Saito,et al.  A thermally-stable self-mending polymer networked by Diels–Alder cycloaddition , 2011 .

[137]  Shunhong Liu,et al.  Analysis of delamination and darkening in high power LED packaging , 2009, 2009 16th IEEE International Symposium on the Physical and Failure Analysis of Integrated Circuits.

[138]  Elliot P. Douglas,et al.  Bone structure and formation: A new perspective , 2007 .

[139]  D. Leo,et al.  Correlation of capacitance and actuation in ionomeric polymer transducers , 2005 .

[140]  S. Sonawane,et al.  Studies on characterization of nano CaCO3 prepared by the in situ deposition technique and its application in PP‐nano CaCO3 composites , 2005 .

[141]  Amy M. Peterson,et al.  The role of maleimide structure in the healing of furan-functionalized epoxy–amine thermosets , 2013 .

[142]  Rishi Raj,et al.  The effect of particle size on the thermal conductivity of ZnS/diamond composites , 1992 .

[143]  Sung-Youl Cho,et al.  Crack Healing in Polymeric Materials via Photochemical [2+2] Cycloaddition , 2004 .

[144]  A. C. Lopes,et al.  Electroactive phases of poly(vinylidene fluoride) : determination, processing and applications , 2014 .