Structural ordering and magnetic properties of arc-melted FeGa alloys

Abstract X-ray diffraction, Mossbauer spectrometry and magnetic properties have been performed on FeGa arc-melted binary alloys in order to study the compositional dependence of the structural ordering and magnetic properties of these alloys. The average magnetic hyperfine field at 300 K decreases with increasing Ga content as does the average magnetic moment per Fe atom, and a linear dependence between both quantities is found for Ga content up to 20 at%. The substitution of Fe by Ga atoms increases the lattice parameter and causes a change in the order of the crystal structure that has been modelled using a binomial distribution method. The effect of Ga atoms as near neighbours of Fe on the average magnetic hyperfine field is evaluated.

[1]  Marilyn Wun-Fogle,et al.  Strong, ductile, and low-field-magnetostrictive alloys based on Fe-Ga , 2000 .

[2]  M. Stoica,et al.  Crystallization behavior and magnetic properties of Cu-containing Fe- Cr- Mo- Ga- P- C- B alloys , 2006 .

[3]  Sivaraman Guruswamy,et al.  Large magnetostriction in directionally solidified FeGa and FeGaAl alloys , 2001 .

[4]  D. Schmool,et al.  Magnetic properties of the Fe-rich FexAl1−x alloy system , 2004 .

[5]  T. Lograsso,et al.  Effect of quenching on the magnetostriction on Fe/sub 1-x/Ga/sub x/ (0.13x<0.21) , 2001 .

[6]  R. S. Turtelli,et al.  Volume magnetostriction and structure of copper mold-cast polycrystalline Fe-Ga alloys , 2005 .

[7]  R. Brand,et al.  The evaluation of hyperfine field distributions in overlapping and asymmetric Mossbauer spectra: a study of the amorphous alloy Pd77.5-xCu6Si16.5Fex , 1983 .

[8]  Ikuo Ohnuma,et al.  Phase equilibria and stability of ordered b.c.c. phases in the Fe-rich portion of the Fe–Ga system , 2002 .

[9]  Marilyn Wun-Fogle,et al.  Extraordinary magnetoelasticity and lattice softening in bcc Fe-Ga alloys , 2003 .

[10]  J. Restrepo,et al.  Hyperfine Magnetic Field Distributions of Fe0.8—qMnqAl0.2 Disordered Alloys: Interpretation in a Local Model , 2000 .

[11]  M. Stearns INTERNAL MAGNETIC FIELDS, ISOMER SHIFTS, AND RELATIVE ABUNDANCES OF THE VARIOUS Fe SITES IN FeSi ALLOYS , 1963 .

[12]  I. Vincze Evaluation of complex Mössbauer spectra in amorphous and crystalline ferromagnets , 1978 .

[13]  Marilyn Wun-Fogle,et al.  Magnetostrictive properties of body-centered cubic Fe-Ga and Fe-Ga-Al alloys , 2000 .

[14]  T. Lograsso,et al.  Structural transformations in quenched Fe-Ga alloys , 2003 .

[15]  S. Guruswamy,et al.  Influence of ordering on the magnetostriction of Fe–27.5 at. % Ga alloys , 2002 .