Development of Surface Acoustic Wave Electronic Nose using Pattern Recognition System

The paper proposes an effective method to design and develop surface acoustic wave (SAW) sensor array-based electronic nose systems for specific target applications. The paper suggests that before undertaking full hardware development empirically through hit and trial for sensor selection, it is prudent to develop accurate sensor array simulator for generating synthetic data and optimising sensor array design and pattern recognition system. The latter aspects are most time-consuming and cost-intensive parts in the development of an electronic nose system. This is because most of the electronic sensor platforms, circuit components, and electromechanical parts are available commercially-off-the-shelve (COTS), whereas knowledge about specific polymers and data analysis software are often guarded due to commercial or strategic interests. In this study, an 11-element SAW sensor array is modelled to detect and identify trinitrotoluene (TNT) and dinitrotoluene (DNT) explosive vapours in the presence of toluene, benzene, dimethylmethylphosphonate (DMMP) and humidity as interferents. Additive noise sources and outliers were included in the model for data generation. The pattern recognition system consists of: (i) a preprocessor based on logarithmic data scaling, dimensional autoscaling, and singular value decomposition-based denoising, (ii) principal component analysis (PCA)-based feature extractor, and (iii) an artificial neural network (ANN) classifier. The efficacy of this approach is illustrated by presenting detailed PCA analysis and classification results under varied conditions of noise and outlier, and by analysing comparative performance of four classifiers (neural network, k-nearest neighbour, naOve Bayes, and support vector machine).

[1]  Stephen J. Martin,et al.  Dynamics and Response of Polymer-Coated Surface Acoustic Wave Devices: Effect of Viscoelastic Properties and Film Resonance , 1994 .

[2]  Gary S. Settles,et al.  Aerodynamic sampling for landmine trace detection , 2001, SPIE Defense + Commercial Sensing.

[3]  J. Yinon,et al.  Detection of explosives by electronic noses , 2003 .

[4]  William C. Trogler,et al.  Polymer sensors for nitroaromatic explosives detection , 2006 .

[5]  E. Zellers,et al.  Optimal coating selection for the analysis of organic vapor mixtures with polymer-coated surface acoustic wave sensor arrays. , 1995, Analytical chemistry.

[6]  Nathan S. Lewis,et al.  Cross-Reactive Chemical Sensor Arrays , 2000 .

[7]  Mamta Khaneja,et al.  Multifrequency characterization of viscoelastic polymers and vapor sensing based on SAW oscillators. , 2009, Ultrasonics.

[8]  R. D. S. Yadava Enhancing mass sensitivity of SAW delay line sensors by chirping transducers , 2006 .

[9]  R.D.S. Yadava,et al.  Preprocessing of SAW Sensor Array Data and Pattern Recognition , 2009, IEEE Sensors Journal.

[10]  Cheng-Hao Ko,et al.  A Novel Measurement Device for SAW Chemical Sensors with FT-IR Spectro-microscopic Analytical Capability , 2004 .

[11]  Ross J. Harper,et al.  Identification of dominant odor chemicals emanating from explosives for use in developing optimal training aid combinations and mimics for canine detection. , 2005, Talanta.

[12]  Sunil K Jha,et al.  Denoising by Singular Value Decomposition and Its Application to Electronic Nose Data Processing , 2011, IEEE Sensors Journal.

[13]  Shekar Viswanathan,et al.  Development of a Novel Odor Measurement System Using Gas Chromatography with Surface Acoustic Wave Sensor , 2008, Journal of the Air and Waste Management Association.

[14]  R Chung,et al.  Rational materials design of sorbent coatings for explosives: applications with chemical sensors. , 2001, Talanta.

[15]  Takahiro Hayashi,et al.  Feature extraction of multi-gas sensor responses using Genetic Algorithm , 2000 .

[16]  R. D. S. Yadava,et al.  Mass sensitivity analysis and designing of surface acoustic wave resonators for chemical sensors , 2009 .

[17]  L. M. Dorozhkin,et al.  Acoustic Wave Chemical Sensors for Gases , 2001 .

[18]  E. Zellers,et al.  Vapor recognition with small arrays of polymer-coated microsensors. A comprehensive analysis. , 1999, Analytical chemistry.

[19]  D. Moore Instrumentation for trace detection of high explosives , 2004 .

[20]  Taher Alizadeh,et al.  Electronic nose based on the polymer coated SAW sensors array for the warfare agent simulants classification , 2008 .

[21]  A. Hierlemann,et al.  Effective use of molecular recognition in gas sensing: results from acoustic wave and in situ FT-IR measurements. , 1999, Analytical chemistry.

[22]  Julian W. Gardner,et al.  Review of Conventional Electronic Noses and Their Possible Application to the Detection of Explosives , 2004 .

[23]  R. Chaudhary,et al.  Solvation, transduction and independent component analysis for pattern recognition in SAW electronic nose , 2006 .

[24]  Vamsee K. Pamula Detection of Explosives , 2004 .

[25]  D. Rounbehler,et al.  Vapor pressure of explosives , 1986 .

[26]  Ricardo Gutierrez-Osuna,et al.  A method for evaluating data-preprocessing techniques for odour classification with an array of gas sensors , 1999, IEEE Trans. Syst. Man Cybern. Part B.

[27]  Alphus D. Wilson,et al.  Applications and Advances in Electronic-Nose Technologies , 2009, Sensors.

[28]  P. Corcoran,et al.  The application of genetic algorithms to sensor parameter selection for multisensor array configuration , 1999 .

[29]  Philippe Robin,et al.  Surface acoustic wave detection of organophosphorus compounds with fluoropolyol coatings , 1997 .

[30]  Stewart Sherrit,et al.  BAW and SAW sensors for in situ analysis , 2003, SPIE Smart Structures and Materials + Nondestructive Evaluation and Health Monitoring.

[31]  William N. Venables,et al.  Modern Applied Statistics with S , 2010 .

[32]  Jay W. Grate,et al.  Acoustic Wave Microsensor Arrays for Vapor Sensing , 2000 .

[33]  Suman Singh,et al.  Sensors--an effective approach for the detection of explosives. , 2007, Journal of hazardous materials.

[34]  Evor L. Hines,et al.  Enhancing electronic nose performance by sensor selection using a new integer-based genetic algorithm approach , 2005 .

[35]  Christina Gloeckner,et al.  Modern Applied Statistics With S , 2003 .

[36]  K. S. Rawlinson,et al.  Development of a Surface Acoustic Wave Sensor for In-Situ Monitoring of Volatile Organic Compounds , 2003 .

[37]  Russell Chung,et al.  The design of functionalized silicone polymers for chemical sensor detection of nitroaromatic compounds , 2000 .

[38]  M. Rapp,et al.  In-Situ Soil Gas Analysis with a Robust Sawsensor System Integrated in Percussion Driven Penetration Cones , 2007, TRANSDUCERS 2007 - 2007 International Solid-State Sensors, Actuators and Microsystems Conference.

[39]  Zulfiqur Ali,et al.  Chemical Sensors for Electronic Nose Systems , 2005 .

[40]  T. Wessa,et al.  Gas analysis with SAW sensor systems , 2000 .

[41]  W. K. Schubert,et al.  Gas phase chemical detection with an integrated chemical analysis system , 1999, Proceedings of the 1999 Joint Meeting of the European Frequency and Time Forum and the IEEE International Frequency Control Symposium (Cat. No.99CH36313).

[42]  D.C. Malocha,et al.  Orthogonal frequency coded SAW sensors and RFID design principles , 2008, 2008 IEEE International Frequency Control Symposium.

[43]  George M. Murray,et al.  Sensors for chemical weapons detection , 2002 .

[44]  Franz L. Dickert,et al.  SAW devices : sensitivity enhancement in going from 80 MHz to 1 GHz , 1998 .