A Novel Solid State Non-Dispersive Infrared CO2 Gas Sensor Compatible with Wireless and Portable Deployment

This paper describes development of a novel mid-infrared light emitting diode (LED) and photodiode (PD) light source/detector combination and use within a non-dispersive infrared (NDIR) carbon dioxide gas sensor. The LED/PD based NDIR sensor provides fast stabilisation time (time required to turn on the sensor from cold, warm up, take and report a measurement, and power down again ≈1 second), longevity (>15 years), low power consumption and low cost. Described performance is compatible with “fit and forget” wireless deployed sensors in applications such as indoor air quality monitoring/control & energy conservation in buildings, transport systems, horticultural greenhouses and portable deployment for safety, industrial and medical applications. Fast stabilisation time, low intrinsic power consumption and cycled operation offer typical energy consumption per measurement of mJ's, providing extended operation using battery and/or energy harvesting strategies (measurement interval of ≈ 2 minutes provides >10 years operation from one AA battery). Specific performance data is provided in relation to measurement accuracy and noise, temperature performance, cross sensitivity, measurement range (two pathlength variants are described covering ambient through to 100% gas concentration), comparison with NDIR utilizing thermal source/pyroelectric light source/detector combination and compatibility with energy harvesting. Semiconductor based LED/PD processing together with injection moulded reflective optics and simple assembly provide a route to low cost high volume manufacturing.

[1]  A. Krier Mid-infrared Semiconductor Optoelectronics , 2006 .

[2]  P. J. Batty,et al.  The development of room temperature LEDs and lasers for the mid‐infrared spectral range , 2008 .

[3]  T. Sashida,et al.  Development of a carbon dioxide concentration meter using a solid electrolyte sensor , 2002, Proceedings of the 41st SICE Annual Conference. SICE 2002..

[4]  H. S. Wolff,et al.  iRun: Horizontal and Vertical Shape of a Region-Based Graph Compression , 2022, Sensors.

[5]  문성욱,et al.  NDIR Gas Sensor , 2009 .

[6]  Shiaw-Fen Ferng,et al.  Indoor air quality assessment of daycare facilities with carbon dioxide, temperature, and humidity as indicators. , 2002, Journal of environmental health.

[7]  The prospects of LEDs, diode detectors and negative luminescence in infrared sensing of gases and spectroscopy , 2001, Philosophical Transactions of the Royal Society of London. Series A: Mathematical, Physical and Engineering Sciences.

[8]  T. Tille,et al.  A High-Precision NDIR $\hbox{CO}_{2}$ Gas Sensor for Automotive Applications , 2006, IEEE Sensors Journal.

[9]  N. Stafford Future crops: The other greenhouse effect , 2007, Nature.

[10]  Mukesh Khare,et al.  Sick building syndrome—A case study in a multistory centrally air-conditioned building in the Delhi City , 2007 .

[11]  Harvey R. Hardaway,et al.  Optimizing indium aluminum antimonide LEDs and photodiodes for gas sensing applications , 2004, SPIE Optics + Photonics.

[12]  Judy Sparer,et al.  Sick-building syndrome , 1997, The Lancet.

[13]  H. Beerman The pyroelectric detector of infrared radiation , 1969 .

[14]  Erika Check Abbott's AIDS fight-back , 2007, Nature.

[15]  Hendrik Poorter Interspecific variation in the growth response of plants to an elevated ambient CO2 concentration , 2004, Vegetatio.

[16]  A. Krier,et al.  Mid-infrared electroluminescence at room temperature from InAsSb multi- quantum-well light-emitting diodes , 2006 .

[17]  J. Rinehart U . S . Patent , 2006 .

[18]  P. K. Dixon,et al.  Broadband digital lock-in amplifier techniques , 1989 .

[19]  M. Razeghi,et al.  Handbook of Infrared Detection Technologies , 2002 .

[20]  C. Lauer,et al.  Room-temperature operation of 3.26μm GaSb-based type-I lasers with quinternary AlGaInAsSb barriers , 2005 .

[21]  Stanley D. Smith,et al.  Comparison of IR LED gas sensors with thermal source products , 1997 .

[22]  W. M. Haynes CRC Handbook of Chemistry and Physics , 1990 .

[23]  Martin A. Green,et al.  Clean electricity from photovoltaics , 2001 .

[24]  M. Grätzel,et al.  A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films , 1991, Nature.

[25]  M G Apte,et al.  Indoor air quality, ventilation and health symptoms in schools: an analysis of existing information. , 2003, Indoor air.

[26]  Weiling Guo,et al.  The reliability of tunnel junction regenerated light emitting diodes , 2005, SPIE/OSA/IEEE Asia Communications and Photonics.

[27]  John Lester Miller,et al.  Principles Of Infrared Technology: A Practical Guide to the State of the Art , 1994 .

[28]  A. Rogalski,et al.  PERFORMANCE LIMITATIONS OF PHOTON AND THERMAL INFRARED DETECTORS , 1997 .

[29]  J. Scofield Frequency‐domain description of a lock‐in amplifier , 1994 .

[30]  T. Ashley,et al.  Mid-infrared AlxIn1−xSb light-emitting diodes , 2007 .

[31]  O. Horacsek,et al.  Properties and failure modes of incandescent tungsten filaments , 1980 .