Mueilha rare metals granite, Eastern Desert of Egypt: An example of a magmatic-hydrothermal system in the Arabian-Nubian Shield

Abstract The Mueilha granite pluton is one of the rare-metals bearing peraluminous granitic plutons in the Arabian-Nubian Shield. It represents the apical part of a highly evolved magma chamber emplaced at a shallow level subsequent to the post Pan-African orogeny. The pluton can be seen as a highly leucocratic medium-grained albite/oligoclase framework infilled with quartz, K-feldspar and muscovite that are variably overgrown by K-feldspar, muscovite, quartz and topaz megacrysts. The increasing number and size of the K-feldspar megacrysts at the expense of the whitened albite/oligoclase framework imparts variably red color to the Mueilha granite. Contacts between the milky white and red granites are usually gradational, but may be locally sharp or may form narrow transition zones resulting from abrupt variations in texture and lithology. Textural relations indicate an initial stage of hydrothermal albitization of magmatic plagioclase and crystallization of topaz megacrysts resulting from infiltration of Na-rich fluorine bearing fluids. A subsequent stage of metasomatic enrichment is characterized by extensive growth of large K-feldspar, quartz and muscovite megacrysts at the expense of the albite/oligoclase crystals as a result of infiltration of K-Si rich hydrous fluids. Post-magmatic infiltration of hydrous fluids along the fault planes is shown by the intense replacement of alkali feldspar megacrysts by quartz, development of myrmekitic intergrowth pockets along the K-feldspar megacrysts and sealing of the micro-fractures by cryptocrystalline mixtures of clay minerals, iron oxides, sericite and chlorite. Compositionally, the red granitic rocks have higher SiO 2 , Fe 2 O 3total , K 2 O/Na 2 O, Σ REE, Y, Th, U, Zr and Zn and lower Al 2 O 3 , Ga, Ta, Nb and Mo compared to the milky white granites. LILE and Sn do not show clear variation trends throughout the Mueilha granite pluton, suggesting their immobility during hydrothermal alteration. Microthermometric measurements indicate that the interactions with the hydrothermal fluids started at a minimum temperature > 400°C, most likely during the late-stage crystallization of the Mueilha granite and continued after their complete solidification (i.e. subsolidus conditions) at a temperature as low as 120 °C. The high fertility of Mueilha granite is most plausibly the result of partial melting within the undepleted juvenile crust of the Arabian–Nubian Shield that has formed during the Pan-African orogeny.

[1]  J. G. Shellnutt,et al.  Cretaceous ongonites (topaz-bearing albite-rich microleucogranites) from Ongon Khairkhan, Central Mongolia: Products of extreme magmatic fractionation and pervasive metasomatic fluid: Rock interaction , 2015 .

[2]  K. Bateman,et al.  An experimental evaluation of the reaction of granite with streamwater, seawater and NaCl solutions at 200°C , 1993 .

[3]  L. Gu,et al.  A topaz- and amazonite-bearing leucogranite pluton in eastern Xinjiang, NW China and its zoning , 2011 .

[4]  G. Eby The A-type granitoids: A review of their occurrence and chemical characteristics and speculations on their petrogenesis , 1990 .

[5]  K. Grossenbacher,et al.  Conductive cooling of lava: columnar joint diameter and stria width as functions of cooling rate and thermal gradient , 1995 .

[6]  O. F. Tuttle,et al.  ORIGIN OF GRANITE IN THE LIGHT OF EXPERIMENTAL STUDIES IN THE SYSTEM NaAlSi3O8–KAlSi3O8–SiO2–H2O , 1958 .

[7]  A. Sbrana,et al.  Rare-earth element (REE) behaviour in the alteration facies of the active magmatic–hydrothermal system of Vulcano (Aeolian Islands, Italy) , 1999 .

[8]  B. Bonin A-type granites and related rocks: Evolution of a concept, problems and prospects , 2007 .

[9]  B. Chappell,et al.  I- and S-type granites in the Lachlan Fold Belt , 1992, Earth and Environmental Science Transactions of the Royal Society of Edinburgh.

[10]  C. Manning,et al.  Experimental determination of CePO4 and YPO4 solubilities in H2O-NaF at 800°C and 1 GPa: Implications for rare earth element transport in high-grade metamorphic fluids , 2013 .

[11]  F. Corfu,et al.  U–Pb TIMS age constraints on the evolution of the Neoproterozoic Meatiq Gneiss Dome, Eastern Desert, Egypt , 2009 .

[12]  I. Haapala Metallogeny of the Rapakivi granites , 1995 .

[13]  C. Pin,et al.  Deciphering the petrogenesis of deeply buried granites: whole-rock geochemical constraints on the origin of largely undepleted felsic granulites from the Moldanubian Zone of the Bohemian Massif , 2004, Earth and Environmental Science Transactions of the Royal Society of Edinburgh.

[14]  S. O. Khalil,et al.  Geochemical and petrographic studies of Ta mineralization in the Nuweibi albite granite complex, Eastern Desert, Egypt , 1997 .

[15]  J. Blundy,et al.  Ascent-driven crystallisation of dacite magmas at Mount St Helens, 1980–1986 , 2001, Contributions to Mineralogy and Petrology.

[16]  V. I. Kovalenko,et al.  Problems of the origin, ore-bearing and evolution of rare-metal granitoids , 1984 .

[17]  M. Cuney,et al.  The Beauvoir topaz-lepidolite albite granite (Massif Central, France); the disseminated magmatic Sn-Li-Ta-Nb-Be mineralization , 1992 .

[18]  A. Michard Rare earth element systematics in hydrothermal fluids , 1989 .

[19]  R. Bodnar Revised equation and table for determining the freezing point depression of H2O-Nacl solutions , 1993 .

[20]  K. Sugitani Anomalously low Al2O3/TiO2 values for Archean cherts from the Pilbara Block, Western Australia—possible evidence for extensive chemical weathering on the early earth , 1996 .

[21]  P. E. Brown FLINCOR; a microcomputer program for the reduction and investigation of fluid-inclusion data , 1989 .

[22]  R. Seltmann,et al.  Experimental testing of line rocks in Li-F granites: evidence from superliquidus experiments with F and P added , 2002 .

[23]  D. Küster Granitoid-hosted Ta mineralization in the Arabian–Nubian Shield: Ore deposit types, tectono-metallogenetic setting and petrogenetic framework , 2009 .

[24]  G. Eby Chemical subdivision of the A-type granitoids:Petrogenetic and tectonic implications , 1992 .

[25]  I. Veksler,et al.  Magmatic evolution of Li–F, rare-metal granites: a case study of melt inclusions in the Khangilay complex, Eastern Transbaikalia (Russia) , 2004 .

[26]  J. Dostal,et al.  Origin of topaz-bearing and related peraluminous granites of the Late Devonian Davis Lake pluton, Nova Scotia, Canada: crystal versus fluid fractionation , 1995 .

[27]  C. Stern,et al.  Magmatic Evolution of the Giant El Teniente Cu–Mo Deposit, Central Chile , 2011 .

[28]  Yixian Wang,et al.  Highly evolved juvenile granites with tetrad REE patterns: the Woduhe and Baerzhe granites from the Great Xing'an Mountains in NE China , 2001 .

[29]  J. Price,et al.  Rapakivi Texture in the Mount Scott Granite, Wichita Mountains, Oklahoma , 1996 .

[30]  N. Sturchio,et al.  The rare earth element geochemistry of acid-sulphate and acid-sulphate-chloride geothermal systems from Yellowstone National Park, Wyoming, USA , 1997 .

[31]  P. Sylvester Post-Collisional Alkaline Granites , 1989, The Journal of Geology.

[32]  J. Webster Exsolution of magmatic volatile phases from Cl-enriched mineralizing granitic magmas and implications for ore metal transport , 1997 .

[33]  Hussein M. Harbi,et al.  Geochemistry of the Late Neoproterozoic Hadb adh Dayheen ring complex, Central Arabian Shield: Implications for the origin of rare-metal-bearing post-orogenic A-type granites , 2011 .

[34]  D. Baker,et al.  Liquidus Equilibria in the System K2O–Na2O–Al2O3–SiO2–F2O−1–H2O to 100 MPa: II. Differentiation Paths of Fluorosilicic Magmas in Hydrous Systems , 2007 .

[35]  H. Nekvasil Tertiary feldspar crystallization in high-temperature felsic magmas , 1992 .

[36]  T. Dewers,et al.  Solubility of excess alumina in hydrous granitic melts in equilibrium with peraluminous minerals at 700–800 °C and 200 MPa, and applications of the aluminum saturation index , 2003 .

[37]  D. Manning,et al.  Petrogenesis of tourmaline granites and topaz granites ; the contribution of experimental data , 1984 .

[38]  J. Liégeois,et al.  Alkaline magmatism subsequent to collision in the Pan-African belt of the Adrar des Iforas (Mali) , 1987, Geological Society, London, Special Publications.

[39]  A. Khudeir,et al.  Sr–Nd isotopes and geochemistry of the infrastructural rocks in the Meatiq and Hafafit core complexes, Eastern Desert, Egypt: Evidence for involvement of pre‐Neoproterozoic crust in the growth of Arabian–Nubian Shield , 2007 .

[40]  J. Leroy,et al.  Un nouvel appareil pour la mesure des températures sous le microscope : l'installation de microthermométrie Chaixmeca , 1976 .

[41]  C. Douch,et al.  Rare element mineralization related to Precambrian alkali granites in the Arabian Shield , 1984 .

[42]  W. McDonough,et al.  Chemical and isotopic systematics of oceanic basalts: implications for mantle composition and processes , 1989, Geological Society, London, Special Publications.

[43]  M. Solomon,et al.  The genesis of the Blue Tier Batholith, northeastern Tasmania, Australia , 1985 .

[44]  J. Whalen,et al.  A-type granites: geochemical characteristics, discrimination and petrogenesis , 1987 .

[45]  I. S. Peretyazhko,et al.  Tetrad effects in the rare earth element patterns of granitoid rocks as an indicator of fluoride-silicate liquid immiscibility in magmatic systems , 2010 .

[46]  N. Jackson Petrogenesis and evolution of Arabian felsic plutonic rocks , 1986 .

[47]  Shen-su Sun,et al.  Origin of alkali-feldspar granites: An example from the Poimena Granite, northeastern Tasmania, Australia , 1988 .

[48]  C. Baes,et al.  The hydrolysis of cations , 1986 .

[49]  P. Piccoli,et al.  Tectonic discrimination of granitoids , 1989 .

[50]  A. Boyce,et al.  Deep hydrothermal circulation in a granite intrusion beneath Larderello geothermal area (Italy): constraints from mineralogy, fluid inclusions and stable isotopes , 2003 .

[51]  R. Stern,et al.  Geochronologic and isotopic constraints on late Precambrian crustal evolution in the Eastern Desert of Egypt , 1985 .

[52]  J. Lowenstern Carbon dioxide in magmas and implications for hydrothermal systems , 2001 .

[53]  M. Hassan,et al.  Precambrian of Egypt , 2017 .

[54]  D. Baker,et al.  Liquidus Equilibria in the System K2O–Na2O–Al2O3–SiO2–F2O−1–H2O to 100 MPa: I. Silicate–Fluoride Liquid Immiscibility in Anhydrous Systems , 2007 .

[55]  W. Griffin,et al.  Apatite as an indicator mineral for mineral exploration: trace-element compositions and their relationship to host rock type , 2002 .

[56]  P. Cˇerný Geochemical and petrogenetic features of mineralization in rare-element granitic pegmatites in the light of current research , 1992 .

[57]  D. London,et al.  Internal Evolution of Miarolitic Granitic Pegmatites at the Little Three Mine, Ramona, California, USA , 2012 .

[58]  S. Nishimoto,et al.  Hydrothermal alteration of deep fractured granite: Effects of dissolution and precipitation , 2010 .

[59]  J. Leterrier,et al.  A classification of volcanic and plutonic rocks using R1R2-diagram and major-element analyses — Its relationships with current nomenclature , 1980 .

[60]  A. J. Anderson,et al.  Extreme fractionation in rare-element granitic pegmatites; selected examples of data and mechanisms , 1985 .

[61]  C. Douch,et al.  Jabal Hamra REE-mineralized silexite, Hijaz region, Kingdom of Saudi Arabia , 1986 .

[62]  Everett L. Shock,et al.  Rare earth elements in hydrothermal systems: Estimates of standard partial molal thermodynamic properties of aqueous complexes of the rare earth elements at high pressures and temperatures , 1995 .

[63]  D. Manning The effect of fluorine on liquidus phase relationships in the system Qz-Ab-Or with excess water at 1 kb , 1981 .

[64]  Jeff R. Taylor,et al.  The behavior of tin in granitoid magmas , 1992 .

[65]  W. Irber Quantification of the lanthanide tetrad effect and its correlation with K/Rb, Eu/Eu*, Sr/Eu, Y/Ho, and Zr/Hf of evolving peraluminous granite suites , 1999 .

[66]  J. Richardson,et al.  Quartz-tourmaline orbicules in the Seagull Batholith, Yukon Territory , 1992 .

[67]  R. Tartèse,et al.  Nb-Ta fractionation in peraluminous granites: A marker of the magmatic-hydrothermal transition , 2016 .

[68]  C. Douch,et al.  NbThZr mineralization in microgranite—microsyenite at Jabal Tawlah, Midyan region, Kingdom of Saudi Arabia , 1986 .

[69]  A. Sokkary,et al.  The relation between Rb, Ba and Sr in granitic rocks , 1975 .

[70]  J. Joron,et al.  Element mobility during metasomatism of granitic rocks in the Saint-Chély d'Apcher area (Lozère, France). , 2002, Environment International.

[71]  I. Haapala Magmatic and Postmagmatic Processes in Tin-mineralized Granites: Topaz-bearing Leucogranite in the Eurajoki Rapakivi Granite Stock, Finland , 1997 .

[72]  C. R. Ramsay Specialized felsic plutonic rocks of the Arabian Shield and their precursors , 1986 .

[73]  M. Bau Controls on the fractionation of isovalent trace elements in magmatic and aqueous systems: evidence from Y/Ho, Zr/Hf, and lanthanide tetrad effect , 1996 .

[74]  B. Jahn,et al.  Origin and evolution of post-collisional magmatism: Coeval Neoproterozoic calc-alkaline and alkaline suites of the Sinai Peninsula , 2010 .

[75]  E. Phillips Myrmekite and Muscovite Developed by Retrograde Metamorphism at Broken Hill, New South Wales , 1972 .

[76]  A. Whittington,et al.  The role of H2O in rapid emplacement and crystallization of granite pegmatites: resolving the paradox of large crystals in highly undercooled melts , 2010 .

[77]  D. Lescinsky,et al.  Anisotropic stress accumulation in cooling lava flows and resulting fracture patterns: Insights from starch-water desiccation experiments , 2009 .

[78]  G. M. Young,et al.  Behavior of major and trace elements (including REE) during Paleoproterozoic pedogenesis and diagenetic alteration of an Archean granite near Ville Marie, Québec, Canada , 2000 .

[79]  A. Parsapoor,et al.  The behaviour of trace and rare earth elements (REE) during hydrothermal alteration in the Rangan area (Central Iran) , 2009 .

[80]  O. Joensuu,et al.  Macusanite Occurrence, Age, and Composition, Macusani, Peru , 1970 .

[81]  P. Davidson,et al.  The missing link between granites and granitic pegmatites , 2013 .

[82]  Samir El Gaby,et al.  The basement complex of the Eastern Desert and Sinai , 2017 .

[83]  S. Klemme,et al.  Effect of melt composition on the partitioning of trace elements between titanite and silicate melt , 2003 .

[84]  Robert F. Martin,et al.  Phase equilibria of a fluorine-rich leucogranite from the St. Austell pluton, Cornwall , 1987 .

[85]  H. Gahlan,et al.  Cold plutonism in the Arabian–Nubian Shield: evidence from the Abu Diab garnet-bearing leucogranite, central Eastern Desert, Egypt , 2017, Journal of the Geological Society.

[86]  T. Kusky,et al.  Late Cryogenian-Ediacaran history of the Arabian-Nubian Shield: A review of depositional, plutonic, structural, and tectonic events in the closing stages of the northern East African Orogen , 2011 .

[87]  N. Jackson Mineralization associated with felsic plutonic rocks in the Arabian Shield , 1986 .

[88]  L. Diamond Stability of CO2 clathrate hydrate + CO2 liquid + CO2 vapour + aqueous KCl-NaCl solutions: Experimental determination and application to salinity estimates of fluid inclusions ∗ , 1992 .

[89]  P. Nurmi,et al.  The Proterozoic granitoids of Finland: Granite types, metallogeny and relation to crustal evolution , 1986 .

[90]  P. Barbey,et al.  Rheological Transitions During Partial Melting and Crystallization with Application to Felsic Magma Segregation and Transfer , 1996 .

[91]  H. Keppler Influence of fluorine on the enrichment of high field strength trace elements in granitic rocks , 1993 .

[92]  D. London Internal differentiation of rare-element pegmatites: Effects of boron, phosphorus, and fluorine , 1987 .

[93]  A. M. Aksyuk,et al.  The Zr/Hf ratio as a fractionation indicator of rare-metal granites , 2009 .

[94]  J. Schott,et al.  An experimental and computational study of sodium-aluminum complexing in crustal fluids , 1996 .

[95]  F. López-Moro,et al.  Ta and Sn concentration by muscovite fractionation and degassing in a lens-like granite body: The case study of the Penouta rare-metal albite granite (NW Spain) , 2017 .

[96]  M. A. MacDonald,et al.  Leucogranites from the Eastern Part of the South Mountain Batholith, Nova Scotia , 1993 .

[97]  G. Mahood,et al.  Evidence for ascent of differentiated liquids in a silicic magma chamber found in a granitic pluton , 1992, Earth and Environmental Science Transactions of the Royal Society of Edinburgh.

[98]  K. Zhao,et al.  Rare earth element and yttrium analyses of sulfides from the Dachang Sn-polymetallic ore field, Guangxi Province, China : Implication for ore genesis , 2007 .

[99]  M. Ackerson Trace element partitioning between titanite and groundmass in silicic volcanic systems , 2011 .

[100]  N. Pearson,et al.  An experimental study of Nb and Ta partitioning between Ti-rich minerals and silicate liquids at high pressure and temperature , 1987 .