Optimization of curing cycle in carbon fiber-reinforced laminates: Void distribution and mechanical properties

Abstract A strategy is presented to optimize out-of-autoclave processing of quasi-isotropic carbon fiber-reinforced laminates. Square panels of 4.6 mm nominal thickness with very low porosity ( ⩽ 0.2 % ) were manufactured by compression molding at low pressure (0.2 MPa) by careful design of the temperature cycle to maximize the processing window. The mechanisms of void migration during processing were ascertained by means of X-ray microtomography and the effect of ply clustering on porosity and on void shape was explained. Finally, the effect of porosity and ply clustering on the compressive strength before and after impact was studied.

[1]  Leon W. Davies,et al.  Effect of cure cycle heat transfer rates on the physical and mechanical properties of an epoxy matrix composite , 2007 .

[2]  J. Llorca,et al.  X-ray microtomography analysis of the damage micromechanisms in 3 D woven composites under low-velocity impact , 2014 .

[3]  K. Terzaghi Theoretical Soil Mechanics , 1943 .

[4]  Kenneth J. Bowles,et al.  Void Effects on the Interlaminar Shear Strength of Unidirectional Graphite-Fiber-Reinforced Composites , 1992 .

[5]  L. Michel,et al.  Coupled visco-mechanical and diffusion void growth modelling during composite curing , 2010 .

[6]  J. Llorca,et al.  X-ray microtomography analysis of the damage micromechanisms in 3D woven composites under low-velocity impact , 2013 .

[7]  Effects of Cure Pressure Induced Voids on the Mechanical Strength of Carbon/Epoxy Laminates , 2009 .

[8]  Hong Zhang,et al.  A multistage adaptive thresholding method , 2005, Pattern Recognit. Lett..

[9]  George S. Springer,et al.  Effects of Cure Pressure on Resin Flow, Voids, and Mechanical Properties , 1987 .

[10]  Pedro P. Camanho,et al.  Effects of ply clustering in laminated composite plates under low-velocity impact loading , 2011 .

[11]  S. Nutt,et al.  Void formation in composite prepregs – Effect of dissolved moisture , 2010 .

[12]  George S. Springer,et al.  Heat of Reaction, Degree of Cure, and Viscosity of Hercules 3501-6 Resin , 1982 .

[13]  Michael R Wisnom,et al.  Scaling Effects in Notched Composites , 2010 .

[14]  R. Day,et al.  Flexural and interlaminar shear strength properties of carbon fibre/epoxy composites cured thermally and with microwave radiation , 2002 .

[15]  S. Agius,et al.  Cure behaviour and void development within rapidly cured out-of-autoclave composites , 2013 .

[16]  F. Sket,et al.  Effect of curing cycle on void distribution and interlaminar shear strength in polymer-matrix composites , 2011 .

[17]  J. L. Kardos,et al.  Void growth and resin transport during processing of thermosetting — Matrix composites , 1986 .

[18]  Boming Zhang,et al.  Effects of cure cycles on void content and mechanical properties of composite laminates , 2006 .

[19]  Constantinos Soutis,et al.  A study on the compressive strength of thick carbon fibre-epoxy laminates , 2007 .

[20]  H. Henning Winter,et al.  Analysis of Linear Viscoelasticity of a Crosslinking Polymer at the Gel Point , 1986 .

[21]  G. Springer,et al.  Curing of Epoxy Matrix Composites , 1983 .