The Infrared Spectrum of 13C2D2: The Bending States up to v4+v5=2

Abstract The vibration–rotation spectrum of 13 C 2 D 2 has been recorded in the infrared region between 420 and 1100 cm −1 with an effective resolution ranging from 0.004 to 0.006 cm −1 , and in the millimeter-wave region between 68 and 518 GHz. A total of about 1400 rovibrational transitions (66 of which have been measured in the millimeter-wave region) have been assigned to 8 bands with 15 l -vibrational components involving the bending states up to v t = v 4 + v 5 =2. The ground state and nine vibrationally excited states have been characterized. All the measured transitions have been analyzed simultaneously by adopting a model Hamiltonian which takes into account the usual vibration and rotation l -type resonances, together with the Darling–Dennison coupling between the v 4 =2 and v 5 =2 bending states. The derived spectroscopic parameters reproduce the transition wavenumbers with a standard deviation of the fit of the order of the experimental uncertainty.

[1]  M. Herman,et al.  THE VIBRATIONAL ENERGY PATTERN IN ACETYLENE (IV) : UPDATED GLOBAL VIBRATION CONSTANTS FOR 12C2H2 , 1999 .

[2]  Robert A. Toth,et al.  nu-2 band of H2 O-16 - Line strengths and transition frequencies , 1991 .

[3]  L. Dore,et al.  Lineshape measurements of rotational lines in the millimeter-wave region by second harmonic detection , 1990 .

[4]  G. Guelachvili Handbook of infrared standards , 1986 .

[5]  S. Ridgway Jupiter: Identification of ethane and acetylene , 1974 .

[6]  S. Ridgway,et al.  Polyatomic species contributing to the carbon-star 3 micron band. , 1978 .

[7]  A. G. Maki,et al.  Wavenumber calibration tables from heterodyne frequency measurements , 1991 .

[8]  Robert A. Toth,et al.  ν 1 −ν 2 , ν 3 −ν 2 , ν 1 , and ν 3 bands of H 2 16 O: line positions and strengths , 1993 .

[9]  J. W. C. Johns,et al.  The bending energy levels of C2H2 , 1991 .

[10]  M. Birk,et al.  High resolution wavenumber standards for the infrared (Technical Report) , 1996 .

[11]  M. Birk,et al.  High resolution wavenumber standards for the infrared , 1996 .

[12]  N. Evans,et al.  Discovery of interstellar acetylene , 1989 .

[13]  I. Mills,et al.  Quartic anharmonic resonances in acetylenes and haloacetylenes , 1995 .

[14]  E. Venuti,et al.  The vibrational energy pattern in acetylene. V. 13C2H2 , 1999 .

[15]  J. Plíva Molecular constants for the bending modes of acetylene 12C2H2 , 1972 .

[16]  D. Bermejo,et al.  High-Resolution Raman Spectra of ν2 and Associated Hot Bands of 12C2D2 , 2001 .

[17]  A. Pisarchik,et al.  The Vibrational Energy Levels in Acetylene (III): 12C2D2 , 1998 .

[18]  M. Herman,et al.  The bending vibrational levels in C2D2 (X̃ 1Σ+g) , 1991 .

[19]  R. Toth 2ν 2 –ν 2 and 2ν 2 bands of H 2 16 O, H 2 17 O, and H 2 18 O: line positions and strengths , 1993 .

[20]  J. V. Auwera,et al.  L-type resonances in C2H2 , 1991 .

[21]  T. Encrenaz,et al.  Enhanced acetylene emission near the north pole of jupiter , 1986 .

[22]  E. Venuti,et al.  Vibration-Rotation Spectra of 13C Containing Acetylene , 1993 .