Emerging Non-Aqueous Potassium-Ion Batteries: Challenges and Opportunities

The ever-increasing demand for storing renewable energy sources calls for novel battery technologies that are of sustainably low levelized energy cost. Research into battery chemistry has evolved to a stage where a plethora of choices based on earth-abundant elements can be compared during their development. One of the emerging candidates is the nonaqueous potassium-ion battery. K-ion’s unique properties as a charge carrier have aroused intense interest in exploring high-performing cathode and anode materials for this battery. Rapid progress has been made, where leading candidates of electrodes have been proposed, i.e., hard carbon as anode and Prussian white analogues as cathode. In this new battery technology’s infancy, it is our opinion that the focus should be given to potentially scalable, inexpensive electrode materials and the understanding of their cycle-life-property correlations. It may be the ultralong cycle life that differentiates potassium-ion batteries from sodium-ion batteries in the futur...

[1]  Meng Huang,et al.  Earth Abundant Fe/Mn-Based Layered Oxide Interconnected Nanowires for Advanced K-Ion Full Batteries. , 2017, Nano letters.

[2]  Xiulei Ji,et al.  Potassium Secondary Batteries. , 2017, ACS applied materials & interfaces.

[3]  Liquan Chen,et al.  Room-temperature stationary sodium-ion batteries for large-scale electric energy storage , 2013 .

[4]  Jean-Marie Tarascon,et al.  In search of an optimized electrolyte for Na-ion batteries , 2012 .

[5]  Linda F. Nazar,et al.  Crystallite Size Control of Prussian White Analogues for Nonaqueous Potassium-Ion Batteries , 2017 .

[6]  A. Glushenkov,et al.  K-ion and Na-ion storage performances of Co3O4-Fe2O3 nanoparticle-decorated super P carbon black prepared by a ball milling process. , 2017, Nanoscale.

[7]  J. Tarascon,et al.  Preparation and Characterization of a Stable FeSO4F-Based Framework for Alkali Ion Insertion Electrodes , 2012 .

[8]  Xiulei Ji,et al.  Polynanocrystalline Graphite: A New Carbon Anode with Superior Cycling Performance for K-Ion Batteries. , 2017, ACS applied materials & interfaces.

[9]  Clement Bommier,et al.  Electrochemically Expandable Soft Carbon as Anodes for Na-Ion Batteries , 2015, ACS central science.

[10]  Z. Fu,et al.  Long life and high-rate Berlin green FeFe(CN)6 cathode material for a non-aqueous potassium-ion battery , 2017 .

[11]  Yuki Yamada,et al.  Na2FeP2O7: A Safe Cathode for Rechargeable Sodium-ion Batteries , 2013 .

[12]  T. Sasaki,et al.  Synthesis and soft-chemical reactivity of layered potassium cobalt oxide , 2005 .

[13]  Liang Zhou,et al.  Novel K3V2(PO4)3/C Bundled Nanowires as Superior Sodium‐Ion Battery Electrode with Ultrahigh Cycling Stability , 2015 .

[14]  Haoshen Zhou,et al.  Bimetallic cyanide-bridged coordination polymers as lithium ion cathode materials: core@shell nanoparticles with enhanced cyclability. , 2013, Journal of the American Chemical Society.

[15]  J. Tarascon,et al.  Na Reactivity toward Carbonate-Based Electrolytes: The Effect of FEC as Additive , 2016 .

[16]  A. Madram,et al.  Effect of Na+ and K+ co-doping on the structure and electrochemical behaviors of LiFePO4/C cathode material for lithium-ion batteries , 2016 .

[17]  O. Bondarchuk,et al.  Higher voltage plateau cubic Prussian White for Na-ion batteries , 2016 .

[18]  Yi Cui,et al.  Copper hexacyanoferrate battery electrodes with long cycle life and high power. , 2011, Nature communications.

[19]  Yuliang Cao,et al.  Antimony Nanocrystals Encapsulated in Carbon Microspheres Synthesized by a Facile Self-Catalyzing Solvothermal Method for High-Performance Sodium-Ion Battery Anodes. , 2016, ACS applied materials & interfaces.

[20]  M. Armand,et al.  Building better batteries , 2008, Nature.

[21]  A. Glushenkov,et al.  Tin-based composite anodes for potassium-ion batteries. , 2016, Chemical communications.

[22]  Jun Chen,et al.  High K-storage performance based on the synergy of dipotassium terephthalate and ether-based electrolytes , 2017 .

[23]  N. Munichandraiah,et al.  K2Ti4O9: A Promising Anode Material for Potassium Ion Batteries , 2016 .

[24]  T. Abe,et al.  Graphite intercalation compounds prepared in solutions of alkali metals in 2-methyltetrahydrofuran and 2,5-dimethyltetrahydrofuran , 1997 .

[25]  Wenwen Deng,et al.  Single-crystal FeFe(CN)6 nanoparticles: a high capacity and high rate cathode for Na-ion batteries , 2013 .

[26]  E. Levi,et al.  Prototype systems for rechargeable magnesium batteries , 2000, Nature.

[27]  Xiaodi Ren,et al.  MoS2 as a long-life host material for potassium ion intercalation , 2017, Nano Research.

[28]  A. L. Crumbliss,et al.  Alkali Metal Cation Effects in a Prussian Blue Surface Modified Electrode , 1984 .

[29]  Haoshen Zhou,et al.  The design of a LiFePO4/carbon nanocomposite with a core-shell structure and its synthesis by an in situ polymerization restriction method. , 2008, Angewandte Chemie.

[30]  Chun-hua Chen,et al.  The role of potassium ions in iron hexacyanoferrate as a cathode material for hybrid ion batteries , 2016 .

[31]  Shinichi Komaba,et al.  P2-type Na(x)[Fe(1/2)Mn(1/2)]O2 made from earth-abundant elements for rechargeable Na batteries. , 2012, Nature materials.

[32]  Y. Marcus Thermodynamic functions of transfer of single ions from water to nonaqueous and mixed solvents: Part 3 - Standard potentials of selected electrodes , 1985 .

[33]  Yi Cui,et al.  Highly reversible open framework nanoscale electrodes for divalent ion batteries. , 2013, Nano letters.

[34]  Kyusung Park,et al.  Liquid K–Na Alloy Anode Enables Dendrite‐Free Potassium Batteries , 2016, Advanced materials.

[35]  Bing-Joe Hwang,et al.  An ultrafast rechargeable aluminium-ion battery , 2015, Nature.

[36]  Jin Han,et al.  Nanocubic KTi2(PO4)3 electrodes for potassium-ion batteries. , 2016, Chemical communications.

[37]  John B. Goodenough,et al.  LixCoO2 (0, 1980 .

[38]  S. Fedotov,et al.  Transport and Kinetic Aspects of Alkali Metal Ions Intercalation into AVPO4F Framework , 2017 .

[39]  Xiaodi Ren,et al.  Potassium-Ion Oxygen Battery Based on a High Capacity Antimony Anode. , 2015, ACS applied materials & interfaces.

[40]  K. Kubota,et al.  P2- and P3-KxCoO2 as an electrochemical potassium intercalation host. , 2017, Chemical communications.

[41]  A. Eftekhari Potassium secondary cell based on Prussian blue cathode , 2004 .

[42]  H. Sakaebe,et al.  Lithium intercalation behavior of iron cyanometallates , 1999 .

[43]  B. Dunn,et al.  Electrical Energy Storage for the Grid: A Battery of Choices , 2011, Science.

[44]  Y. Liu,et al.  In situ transmission electron microscopy study of electrochemical sodiation and potassiation of carbon nanofibers. , 2014, Nano letters.

[45]  Wangxing Li,et al.  Electrochemical intercalation of potassium into graphite in KF melt , 2010 .

[46]  Kangsheng Huang,et al.  Phosphorus and oxygen dual-doped graphene as superior anode material for room-temperature potassium-ion batteries , 2017 .

[47]  Liquan Chen,et al.  Prussian blues as a cathode material for lithium ion batteries. , 2014, Chemistry.

[48]  D. Aurbach,et al.  Investigation of the electrochemical windows of aprotic alkali metal (Li, Na, K) salt solutions , 2001 .

[49]  Jiulin Wang,et al.  Highly Crystallized Na₂CoFe(CN)₆ with Suppressed Lattice Defects as Superior Cathode Material for Sodium-Ion Batteries. , 2016, ACS applied materials & interfaces.

[50]  Fan Zhang,et al.  A Novel Potassium‐Ion‐Based Dual‐Ion Battery , 2017, Advanced materials.

[51]  Jinbao Zhang,et al.  Synthesis and electrochemical properties of K-doped LiFePO4/C composite as cathode material for lithium-ion batteries , 2012, Journal of Solid State Electrochemistry.

[52]  Limin Zhu,et al.  Fe(CN)6−4-doped polypyrrole: a high-capacity and high-rate cathode material for sodium-ion batteries , 2012 .

[53]  C. Ling,et al.  First-Principles Study of Alkali and Alkaline Earth Ion Intercalation in Iron Hexacyanoferrate: The Important Role of Ionic Radius , 2013 .

[54]  Yang Xu,et al.  Potassium Prussian Blue Nanoparticles: A Low‐Cost Cathode Material for Potassium‐Ion Batteries , 2017 .

[55]  Liangbing Hu,et al.  A perylene anhydride crystal as a reversible electrode for K-ion batteries , 2016 .

[56]  Shinichi Komaba,et al.  Potassium intercalation into graphite to realize high-voltage/high-power potassium-ion batteries and potassium-ion capacitors , 2015 .

[57]  Haoshen Zhou,et al.  Fabrication of a Cyanide-Bridged Coordination Polymer Electrode for Enhanced Electrochemical Ion Storage Ability , 2012 .

[58]  T. Abe,et al.  Creation of nanospaces by intercalation of alkali metals into graphite in organic solutions , 2001 .

[59]  N. Matsuura,et al.  Standard Potentials of Alkali Metals, Silver, and Thallium Metal/Ion Couples in N,N′-Dimethylformamide, Dimethyl Sulfoxide, and Propylene Carbonate , 1974 .

[60]  John B Goodenough,et al.  A superior low-cost cathode for a Na-ion battery. , 2013, Angewandte Chemie.

[61]  R. Franklin Crystallite growth in graphitizing and non-graphitizing carbons , 1951, Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences.

[62]  Jin Han,et al.  Exploration of K2Ti8O17 as an anode material for potassium-ion batteries. , 2016, Chemical communications.

[63]  W. Luo,et al.  Potassium Ion Batteries with Graphitic Materials. , 2015, Nano letters.

[64]  John B Goodenough,et al.  Prussian blue: a new framework of electrode materials for sodium batteries. , 2012, Chemical communications.

[65]  Huilin Pan,et al.  Carbon coated Na3V2(PO4)3 as novel electrode material for sodium ion batteries , 2012 .

[66]  Zhixin Chen,et al.  Phosphorus-Based Alloy Materials for Advanced Potassium-Ion Battery Anode. , 2017, Journal of the American Chemical Society.

[67]  Seung M. Oh,et al.  Sodium Terephthalate as an Organic Anode Material for Sodium Ion Batteries , 2012, Advanced materials.

[68]  Joseph Paul Baboo,et al.  Amorphous iron phosphate: potential host for various charge carrier ions , 2014 .

[69]  Wataru Murata,et al.  Fluorinated ethylene carbonate as electrolyte additive for rechargeable Na batteries. , 2011, ACS applied materials & interfaces.

[70]  Linda F Nazar,et al.  The emerging chemistry of sodium ion batteries for electrochemical energy storage. , 2015, Angewandte Chemie.

[71]  Yi Cui,et al.  The Effect of Insertion Species on Nanostructured Open Framework Hexacyanoferrate Battery Electrodes , 2011 .

[72]  Yan Yao,et al.  Poly(anthraquinonyl sulfide) cathode for potassium-ion batteries , 2016 .

[73]  Young Gyu Kim,et al.  Corrosion/passivation of aluminum current collector in bis(fluorosulfonyl)imide-based ionic liquid for lithium-ion batteries , 2012 .

[74]  Palani Balaya,et al.  The First Report on Excellent Cycling Stability and Superior Rate Capability of Na3V2(PO4)3 for Sodium Ion Batteries , 2013 .

[75]  Yuki Yamada,et al.  Theoretical Analysis of Interactions between Potassium Ions and Organic Electrolyte Solvents: A Comparison with Lithium, Sodium, and Magnesium Ions , 2017 .

[76]  Yi Cui,et al.  Nickel hexacyanoferrate nanoparticle electrodes for aqueous sodium and potassium ion batteries. , 2011, Nano letters.

[77]  P. Bruce,et al.  Macroporous Li(Ni1/3Co1/3Mn1/3)O2: A High‐Power and High‐Energy Cathode for Rechargeable Lithium Batteries , 2006 .

[78]  Philipp Adelhelm,et al.  Use of graphite as a highly reversible electrode with superior cycle life for sodium-ion batteries by making use of co-intercalation phenomena. , 2014, Angewandte Chemie.

[79]  K. Kubota,et al.  A novel K-ion battery: hexacyanoferrate(II)/graphite cell , 2017 .

[80]  Motoaki Nishijima,et al.  Rhombohedral prussian white as cathode for rechargeable sodium-ion batteries. , 2015, Journal of the American Chemical Society.

[81]  Xiaogang Han,et al.  Porous amorphous FePO4 nanoparticles connected by single-wall carbon nanotubes for sodium ion battery cathodes. , 2012, Nano letters.

[82]  Xiulei Ji,et al.  Carbon Electrodes for K-Ion Batteries. , 2015, Journal of the American Chemical Society.

[83]  M. Ávila,et al.  Cation mobility and structural changes on the water removal in zeolite-like zinc hexacyanometallates (II) , 2011 .

[84]  Kai He,et al.  Expanded graphite as superior anode for sodium-ion batteries , 2014, Nature Communications.

[85]  S. Passerini,et al.  Non-Aqueous K-Ion Battery Based on Layered K0.3MnO2 and Hard Carbon/Carbon Black , 2016 .

[86]  Xinping Ai,et al.  Hierarchical Carbon Framework Wrapped Na3V2(PO4)3 as a Superior High‐Rate and Extended Lifespan Cathode for Sodium‐Ion Batteries , 2015, Advanced materials.

[87]  R. D. Shannon Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides , 1976 .

[88]  Jun Liu,et al.  Sodium ion insertion in hollow carbon nanowires for battery applications. , 2012, Nano letters.

[89]  Xinping Ai,et al.  High capacity Na-storage and superior cyclability of nanocomposite Sb/C anode for Na-ion batteries. , 2012, Chemical communications.

[90]  Christian Masquelier,et al.  Polyanionic (phosphates, silicates, sulfates) frameworks as electrode materials for rechargeable Li (or Na) batteries. , 2013, Chemical reviews.

[91]  Jun Liu,et al.  Electrochemical energy storage for green grid. , 2011, Chemical reviews.

[92]  Zelang Jian,et al.  Prussian white analogues as promising cathode for non-aqueous potassium-ion batteries , 2017 .

[93]  Clement Bommier,et al.  Hard Carbon Microspheres: Potassium‐Ion Anode Versus Sodium‐Ion Anode , 2016 .

[94]  C. Li,et al.  Potassium salts of para-aromatic dicarboxylates as the highly efficient organic anodes for low-cost K-ion batteries , 2017 .

[95]  Xiulei Ji,et al.  Hard carbon anodes of sodium-ion batteries: undervalued rate capability. , 2017, Chemical communications.

[96]  Kingo Itaya,et al.  Spectroelectrochemistry and electrochemical preparation method of Prussian blue modified electrodes , 1982 .

[97]  D. Stevens,et al.  High Capacity Anode Materials for Rechargeable Sodium‐Ion Batteries , 2000 .

[98]  Steven D. Lacey,et al.  Organic electrode for non-aqueous potassium-ion batteries , 2015 .

[99]  Keith Share,et al.  Role of Nitrogen-Doped Graphene for Improved High-Capacity Potassium Ion Battery Anodes. , 2016, ACS nano.

[100]  Yu-Guo Guo,et al.  High-quality Prussian blue crystals as superior cathode materials for room-temperature sodium-ion batteries , 2014 .

[101]  J. Tarascon,et al.  Synthesis, Structure, and Electrochemical Properties of K-Based Sulfates K2M2(SO4)3 with M = Fe and Cu. , 2017, Inorganic chemistry.

[102]  A. Manthiram,et al.  Low-Cost High-Energy Potassium Cathode. , 2017, Journal of the American Chemical Society.

[103]  D. Su,et al.  Hard–Soft Composite Carbon as a Long‐Cycling and High‐Rate Anode for Potassium‐Ion Batteries , 2017 .

[104]  F. Liu,et al.  Investigation of K3V2(PO4)3/C nanocomposites as high-potential cathode materials for potassium-ion batteries. , 2017, Chemical communications.

[105]  P. Hagenmuller,et al.  Les bronzes de cobalt KxCoO2 (x < 1). L'oxyde KCoO2 , 1975 .