LER evaluation of molecular resist for EUV lithography

We have designed and synthesized a molecular resist material, which has no distribution of the protecting groups and have evaluated its performance as a molecular resist with EB and EUV exposure tool. The molecular resist attained a resolution of sub-45nm patterning at an exposure dose of 12mJ/cm^2. It was found that controlling the distribution of the protecting groups in a molecular resist material has a great impact on improving line edge roughness (LER). Low LER values of 3.1nm (inspection length: L=620nm) and 3.6nm (L=2000nm) were achieved with this molecular resist using Extreme UltraViolet (EUV) lithography tool.

[1]  Atsuko Yamaguchi,et al.  Depth Profile and Line-Edge Roughness of Low-Molecular-Weight Amorphous Electron Beam Resists , 2005 .

[2]  Shinji Okazaki,et al.  Correlation of Nano Edge Roughness in Resist Patterns with Base Polymers , 1993 .

[3]  Iwao Nishiyama,et al.  Lithographic performance of high-numerical-aperture (NA=0.3) EUV small-field exposure tool (HINA) , 2005, SPIE Advanced Lithography.

[4]  Shiying Xiong,et al.  Gate line-edge roughness effects in 50-nm bulk MOSFET devices , 2002, SPIE Advanced Lithography.

[5]  D. Shiono,et al.  Molecular resists based on cholate derivatives for electron-beam lithography , 2005, Digest of Papers Microprocesses and Nanotechnology 2005.

[6]  Taku Hirayama,et al.  New Photoresist Based on Amorphous Low Molecular Weight Polyphenols , 2004 .

[7]  H. Fukuda Analysis of line edge roughness using probability process model for chemically amplified resists , 2002, 2002 International Microprocesses and Nanotechnology Conference, 2002. Digest of Papers..

[8]  Atsuko Yamaguchi,et al.  Analysis of Line-edge Roughness in Resist Patterns and Its Transferability as Origins of Device Performance Degradation and Variation , 2003 .

[9]  C.H. Diaz,et al.  An experimentally validated analytical model for gate line-edge roughness (LER) effects on technology scaling , 2001, IEEE Electron Device Letters.

[10]  Laurent Ithier,et al.  Amplitude and spatial frequency characterization of line-edge roughness using CD-SEM , 2002, SPIE Advanced Lithography.

[11]  Masahiko Ishida,et al.  Sub-10-nm-Scale Lithography Using p-chloromethyl-methoxy-calix[4]arene Resist , 2003 .

[12]  Kenji Gamo,et al.  Novel class of low molecular‐weight organic resists for nanometer lithography , 1996 .

[13]  Jean M. J. Fréchet,et al.  Dendrimers with Thermally Labile End Groups: An Alternative Approach to Chemically Amplified Resist Materials Designed for Sub‐100 nm Lithography , 2000 .

[14]  Yuusuke Tanaka,et al.  Evaluation of resolution and LER in the resist patterns replicated by EUV microexposure tools , 2006, SPIE Advanced Lithography.

[15]  Hyo-Jin Yun,et al.  Novel molecular resist based on derivative of cholic acid , 2002 .