Two Dimensional Materials for Military Applications

This paper particularly focuses on 2D materials and their utilization in military applications. 2D and heterostructured 2D materials have great potential for military applications in developing energy storage devices, sensors, electronic devices, and weapon systems. Advanced 2D material-based sensors and detectors provide high awareness and significant opportunities to attain correct data required for planning, optimization, and decision-making, which are the main factors in the command and control processes in the military operations. High capacity sensors and detectors or energy storage can be developed not only by using 2D materials such as graphene, hexagonal boron nitride (hBN), MoS2, MoSe2, MXenes; but also by combining 2D materials to obtain heterostructures. Phototransistors, flexible thin-film transistors, IR detectors, electrodes for batteries, organic photovoltaic cells, and organic light-emitting diodes have been being developed from the 2D materials for devices that are used in weapon systems, chemicalbiological warfare sensors, and detection systems. Therefore, the utilization of 2D materials is the key factor and the future of advanced sensors, weapon systems, and energy storage devices for military applications.

[1]  K. Brendley,et al.  Military Applications of Microelectromechanical Systems , 1993 .

[2]  Hee Cheul Choi,et al.  Direct growth of graphene pad on exfoliated hexagonal boron nitride surface. , 2011, Nanoscale.

[3]  N. Chopra,et al.  Progress in Large-Scale Production of Graphene. Part 2: Vapor Methods , 2015 .

[4]  XPS evidence for molecular charge-transfer doping of graphene , 2010, 1202.4323.

[5]  Jeongho Park,et al.  Epitaxial Graphene Growth by Carbon Molecular Beam Epitaxy (CMBE) , 2010, Advanced materials.

[6]  D. Broido,et al.  Enhanced thermal conductivity and isotope effect in single-layer hexagonal boron nitride , 2011 .

[7]  F. Wang,et al.  Two dimensional hexagonal boron nitride (2D-hBN): synthesis, properties and applications , 2017 .

[8]  Yong Wang,et al.  Recent advance in MXenes: A promising 2D material for catalysis, sensor and chemical adsorption , 2017 .

[9]  Brajesh Kumar Kaushik,et al.  Performance Improvement of Electro Optic Search and Track System for Maritime Surveillance , 2020 .

[10]  Qunyang Li,et al.  Tribology of two-dimensional materials: From mechanisms to modulating strategies , 2019, Materials Today.

[11]  P. Schwaller,et al.  Two-dimensional materials from high-throughput computational exfoliation of experimentally known compounds , 2016, Nature Nanotechnology.

[12]  B. Hong,et al.  Materials for Flexible, Stretchable Electronics: Graphene and 2D Materials , 2015 .

[13]  M. Ali,et al.  Improving the tribological behavior of internal combustion engines via the addition of nanoparticles to engine oils , 2015 .

[14]  T. O’Regan,et al.  Vertical 2D/3D Semiconductor Heterostructures Based on Epitaxial Molybdenum Disulfide and Gallium Nitride. , 2016, ACS nano.

[15]  Ashavani Kumar,et al.  Effect of Nanographite on Electrical Mechanical and Wear Characteristics of Graphite Epoxy Composites , 2020 .

[16]  Milos B. Djukic,et al.  Theoretical investigation of structural, mechanical, elastic and vibrational properties of advanced materials under extreme conditions , 2018 .

[17]  A. Mohamed,et al.  Mechanisms of graphene growth by chemical vapour deposition on transition metals , 2014 .

[18]  Bing Sun,et al.  Highly efficient and large-scale synthesis of graphene by electrolytic exfoliation , 2009 .

[19]  Andreas Hirsch,et al.  Soluble Graphene: Generation of Aqueous Graphene Solutions Aided by a Perylenebisimide‐Based Bolaamphiphile , 2009 .

[20]  A. Rogalski Infrared detectors: an overview , 2002 .

[21]  Y. Gogotsi,et al.  Saturable Absorption in 2D Ti3C2 MXene Thin Films for Passive Photonic Diodes , 2018, Advanced materials.

[22]  Young Soo Yoon,et al.  Room Temperature Gas Sensing of Two-Dimensional Titanium Carbide (MXene). , 2017, ACS applied materials & interfaces.

[23]  J. Shan,et al.  Atomically thin MoS₂: a new direct-gap semiconductor. , 2010, Physical review letters.

[24]  Jiecai Han,et al.  Infrared-transparent films based on conductive graphene network fabrics for electromagnetic shielding , 2015 .

[25]  S. Holmes,et al.  2D materials graphene and hBN boost DMFC performance , 2017 .

[26]  L. Qu,et al.  Graphene-quantum-dot assembled nanotubes: a new platform for efficient Raman enhancement. , 2012, ACS nano.

[27]  Paras N. Prasad,et al.  Two-dimensional MXenes: From morphological to optical, electric, and magnetic properties and applications , 2020, Physics Reports.

[28]  Lori A. Wilson,et al.  Frontiers of Materials Research: A Decadal Survey , 2017 .

[29]  Steven W. Cranford,et al.  Packing efficiency and accessible surface area of crumpled graphene , 2011 .

[30]  Xianlong Wei,et al.  Mechanical Properties of 2D Materials Studied by In Situ Microscopy Techniques , 2018 .

[31]  Mark C. Hersam,et al.  Synthesis and chemistry of elemental 2D materials , 2017 .

[32]  M. Kafesaki,et al.  A comparison of graphene, superconductors and metals as conductors for metamaterials and plasmonics , 2012, 1210.0640.

[33]  P. Hodgson,et al.  High-Efficient Production of Boron Nitride Nanosheets via an Optimized Ball Milling Process for Lubrication in Oil , 2014, Scientific Reports.

[34]  Xiaoping Shen,et al.  Graphene nanosheets for enhanced lithium storage in lithium ion batteries , 2009 .

[35]  Xiaolong Jia,et al.  Hierarchical structure graphitic-like/MoS2 film as superlubricity material , 2017 .

[36]  K. Bolotin,et al.  Graphene: corrosion-inhibiting coating. , 2012, ACS nano.

[37]  Chenhui Zhang,et al.  The synthesis of two-dimensional MoS2 nanosheets with enhanced tribological properties as oil additives , 2018, RSC advances.

[38]  N. Lee,et al.  Gas sensing with heterostructures based on two-dimensional nanostructured materials: a review , 2019, Journal of Materials Chemistry C.

[39]  Fuming Chen,et al.  Free-standing graphene paper for energy application: Progress and future scenarios , 2019, Carbon.

[40]  Philip Perconti,et al.  2D electronic materials for army applications , 2015, Defense + Security Symposium.

[41]  F. Guinea,et al.  The electronic properties of graphene , 2007, Reviews of Modern Physics.

[42]  Sungwon Lee,et al.  Functionalization of graphene layers and advancements in device applications , 2019, Carbon.

[43]  C. Coletti,et al.  Superlubricity of epitaxial monolayer WS2 on graphene , 2018, Nano Research.

[44]  D. A. Brownson,et al.  A decade of graphene research: Production, applications and outlook , 2014 .

[45]  Oriol López Sánchez,et al.  Large-Area Epitaxial Monolayer MoS2 , 2015, ACS nano.

[46]  Layer thickness-dependent phonon properties and thermal conductivity of MoS2 , 2016, 1601.00227.

[47]  T. Fisher,et al.  Graphene: An effective oxidation barrier coating for liquid and two-phase cooling systems , 2013 .

[48]  H. Ago,et al.  Synthesis, structure and applications of graphene-based 2D heterostructures. , 2017, Chemical Society reviews.

[49]  Edwin L. Thomas,et al.  Opportunities in Protection Materials Science and Technology for Future Army Applications , 2012 .

[50]  Moon J. Kim,et al.  Toward the controlled synthesis of hexagonal boron nitride films. , 2012, ACS nano.

[51]  A. Reina,et al.  Large area, few-layer graphene films on arbitrary substrates by chemical vapor deposition. , 2009, Nano letters.

[52]  Giuseppe Iannaccone,et al.  Quantum engineering of transistors based on 2D materials heterostructures , 2018, Nature Nanotechnology.

[53]  David A. Strubbe,et al.  Solid Lubrication with MoS$_2$: A Review , 2019, 1906.05854.

[54]  David A. Strubbe,et al.  Solid Lubrication with MoS2: A Review , 2019, Lubricants.

[55]  A. Agarwal,et al.  Effect of 2D Boron Nitride Nanoplate Additive on Tribological Properties of Natural Oils , 2016, Tribology Letters.

[56]  D. Englund,et al.  Heterogeneous Integration of 2D Materials and Devices on a Si Platform , 2018, Beyond-CMOS Technologies for Next Generation Computer Design.

[57]  P. Ajayan,et al.  Ultrathin high-temperature oxidation-resistant coatings of hexagonal boron nitride , 2013, Nature Communications.

[58]  A. Ouerghi,et al.  Strong interlayer hybridization in the aligned SnS2/WSe2 hetero-bilayer structure , 2019, npj 2D Materials and Applications.

[59]  H. Shao,et al.  Low lattice thermal conductivity of stanene , 2015, Scientific Reports.

[60]  W. Choi,et al.  Synthesis of Graphene and Its Applications: A Review , 2010 .

[61]  L. Besra,et al.  Graphene Coating on Copper by Electrophoretic Deposition for Corrosion Prevention , 2017 .

[62]  J. Kysar,et al.  Measurement of the Elastic Properties and Intrinsic Strength of Monolayer Graphene , 2008, Science.

[63]  Zhen Zhou,et al.  MXene-based materials for electrochemical energy storage , 2018 .

[64]  A. Wee,et al.  Van der Waals stacked 2D layered materials for optoelectronics , 2016 .

[65]  Li Gao Flexible Device Applications of 2D Semiconductors. , 2017, Small.

[66]  Gaohua Zhu,et al.  Tuning thermal conductivity in molybdenum disulfide by electrochemical intercalation , 2016, Nature Communications.

[67]  Andre K. Geim,et al.  The rise of graphene. , 2007, Nature materials.

[68]  K. S. Coleman,et al.  Graphene Synthesis. Relationship to Applications , 2013 .

[69]  S. Tawfick,et al.  Tailoring the mechanical properties of 2D materials and heterostructures , 2018, 2D Materials.

[70]  Ben Wang,et al.  Nanotechnology Commercialization: Manufacturing Processes and Products , 2017 .

[71]  C. Zhi,et al.  Large‐Scale Fabrication of Boron Nitride Nanosheets and Their Utilization in Polymeric Composites with Improved Thermal and Mechanical Properties , 2009 .

[72]  Byoung Hun Lee,et al.  Chemical Sensing of 2D Graphene/MoS2 Heterostructure device. , 2015, ACS applied materials & interfaces.

[73]  Y. Chen,et al.  Atomically Thin Boron Nitride: Unique Properties and Applications , 2016, 1605.01136.

[74]  Yihong Wu,et al.  Graphene thickness determination using reflection and contrast spectroscopy. , 2007, Nano letters.

[75]  Fang Liu,et al.  Strongly green-photoluminescent graphene quantum dots for bioimaging applications. , 2011, Chemical communications.

[76]  Lili Zhang,et al.  Large area CVD growth of graphene , 2015 .

[77]  Hugen Yan,et al.  Anomalous lattice vibrations of single- and few-layer MoS2. , 2010, ACS nano.

[78]  Y. Gogotsi,et al.  Cold Sintered Ceramic Nanocomposites of 2D MXene and Zinc Oxide , 2018, Advanced materials.

[79]  Y. Gogotsi,et al.  An Update from Flatland. , 2016, ACS nano.

[80]  Huaihe Song,et al.  Graphene nanosheets as electrode material for electric double-layer capacitors , 2010 .

[81]  Anirudha V. Sumant,et al.  Graphene: a new emerging lubricant ☆ , 2014 .

[82]  Jae Hwan Jeong,et al.  Mechanical properties of two-dimensional materials and their applications , 2018, Journal of Physics D: Applied Physics.

[83]  H. Zeng,et al.  2D materials via liquid exfoliation: a review on fabrication and applications , 2015 .

[84]  Zhongying Wang,et al.  Environmental Applications of 2D Molybdenum Disulfide (MoS2) Nanosheets. , 2017, Environmental science & technology.

[85]  J. D. de Mello,et al.  Tribological Behaviour of Plasma-Functionalized Graphene as Low-Viscosity Oil Additive , 2018, Tribology Letters.

[86]  Yury Gogotsi,et al.  Two-dimensional heterostructures for energy storage , 2017, Nature Energy.

[87]  Dae-Hyeong Kim,et al.  Wearable Sensing Systems with Mechanically Soft Assemblies of Nanoscale Materials , 2017 .

[88]  Application of Advanced Materials in Petroleum Engineering , 2014 .

[89]  2D Metal Carbides and Nitrides (MXenes): Structure, Properties and Applications , 2019 .