Gold-based screen-printed sensor for detection of trace lead

Abstract The application of a novel gold-based screen-printed sensor to lead detection is described. The sensor consists of a screen-printed three electrode cell: a gold working electrode, a silver pseudo-reference electrode and a graphite counter electrode. It is used in combination with square wave anodic stripping voltammetry (SWASV). Sensor characterisation experiments as well as the optimisation of the analytical procedure are reported. The optimised parameters allow the detection of micrograms per litre of lead concentrations following short analysis time (detection limit 0.5 μg l−1 at 120 s deposition). Measurements of other metals such as copper, cadmium and mercury are reported.

[1]  J Wang,et al.  Mercury-free disposable lead sensors based on potentiometric stripping analysis at gold-coated screen-printed electrodes. , 1993, Analytical chemistry.

[2]  K. Brainina,et al.  Stripping voltammetric determination of mercury at modified solid electrodes: Determination of mercury traces using PDC/AU(III) modified electrodes , 1999 .

[3]  Ilaria Palchetti,et al.  Miniaturised stripping-based carbon modified sensor for in field analysis of heavy metals , 2005 .

[4]  John P. Hart,et al.  Screen-printed electrochemical sensors for monitoring metal pollutants , 2003 .

[5]  J. Slater,et al.  Flow injection measurement of lead using mercury-free disposable gold-sputtered screen-printed carbon electrodes (SPCE) , 2003 .

[6]  E. Kirowa-Eisner,et al.  Determination of sub-μg l−1 concentrations of copper by anodic stripping voltammetry at the gold electrode , 1999 .

[7]  G. Staikov,et al.  Combined in situ SPM and EIS studies of Pb UPD on Ag(111) and Ag(100) , 1998 .

[8]  Joseph Wang,et al.  Screen-printed electrodes for stripping measurements of trace mercury , 1993 .

[9]  T. Florence Anodic stripping voltammetry with a glassy carbon electrode mercury-plated in situ , 1970 .

[10]  L. Sipos,et al.  Applications of polarography and voltammetry to marine and aquatic chemistry: IV. A new voltammetric method for the study of mercury traces in sea water and inland waters , 1977 .

[11]  E. Neyman,et al.  Electroanalytical stripping methods , 1993 .

[12]  Joseph Wang,et al.  Gold ultramicroelectrodes for on-site monitoring of trace lead , 1993 .

[13]  Lijun He,et al.  THE DETERMINATION OF LEAD IN TEA SAMPLES BY UPD-SWASV METHOD ON GOLD DISC ELECTRODE , 2002 .

[14]  E. Kirowa-Eisner,et al.  Determination of sub-nanomolar concentrations of lead by anodic-stripping voltammetry at the silver electrode , 1999 .

[15]  E. Kirowa-Eisner,et al.  The Silver Electrode in Square-Wave Anodic Stripping Voltammetry. Determination of Pb2+ without Removal of Oxygen , 1997 .

[16]  Kevin Ashley,et al.  Electroanalytical applications in occupational and environmental health , 1994 .

[17]  E. Kirowa-Eisner,et al.  Trace determination of mercury by anodic stripping voltammetry at the rotating gold electrode , 2000 .