Solubilities of gases in liquids II. The solubilities of He, Ne, Ar, Kr, O2, N2, CO, CO2, CH4, CF4, and SF6 in n-octane 1-octanol, n-decane, and 1-decanol☆

Abstract The solubilities of 11 gases in n-octane, n-decane, 1-octanol, and 1-decanol have been determined at atmospheric pressure in the range 293 to 313 K. From the temperature variation of the experimental solubilities, partial molar enthalpies and entropies of solution for 1 atm partial pressure of gas and 298.15 K have been derived. Comparison with results obtained through application of scaled-particle theory showed satisfactory agreement.

[1]  R. Battino,et al.  The solubility of gases in liquids 10. The solubility of He, Ne, Ar, Kr, N2, O2, CO, CO2, CH4, CF4, and SF6 in cyclooctane at 289 to 313 K , 1977 .

[2]  J. Danielli,et al.  PERMEABILITY OF NATURAL MEMBRANES , 1953 .

[3]  R. Pierotti,et al.  Aqueous Solutions of Nonpolar Gases1 , 1965 .

[4]  R. Battino,et al.  The Solubility of Gases in Liquids I. The Solubility of a Series of Fluorine-Containing Gases in Several Non-Polar Solvents , 1971 .

[5]  K. Miller,et al.  Solubility Relations of Fluorine Compounds and Inert Gas Narcosis , 1964, Nature.

[6]  R. Battino,et al.  Thermodynamic functions of the solubilities of gases in liquids at 25.deg. , 1973 .

[7]  M. Bogan,et al.  Apparatus for rapid degassing of liquids. III , 1971 .

[8]  J. Hildebrand,et al.  Solubility, Entropy and Partial Molal Volumes in Solutions of Gases in Non-polar Solvents , 1958 .

[9]  R. Battino,et al.  The solubilities of seven gases in olive oil with references to theories of transport through the cell membrane , 1968, Journal of the American Oil Chemists' Society.

[10]  R. Battino,et al.  The solubility of gases in liquids 9. Solubility of He, Ne, Ar, Kr, N2, O2, CO, CO2, CH4, CF4, and SF6 in some dimethylcyclohexanes at 298 to 313 K , 1976 .

[11]  R. Battino,et al.  Estimation of Lennard‐Jones (6,12) Pair Potential Parameters from Gas Solubility Data , 1971 .

[12]  A. Leo,et al.  Partition coefficients and their uses , 1971 .

[13]  J. Dymond Solubility of a series of gases in cyclohexane and dimethylsulfoxide , 1967 .

[14]  R. Battino,et al.  The solubility of gases in liquids 2. The solubility of He, Ne, Ar, Kr, N2, O2, CO, and CO2 in 2-methyl-1-propanol (1 to 55 °C) , 1971 .

[15]  R. Dadson The Virial Coefficients of Gases , 1970 .

[16]  Howard Reiss,et al.  Statistical Mechanics of Rigid Spheres , 1959 .

[17]  C. Hansch,et al.  Partition coefficients and the structure-activity relationship of the anesthetic gases. , 1975, Journal of medicinal chemistry.

[18]  R. Pierotti,et al.  A scaled particle theory of aqueous and nonaqueous solutions , 1976 .

[19]  R A Smith,et al.  Physicochemical Approaches to the Mode of Action of General Anesthetics , 1972, Anesthesiology.

[20]  T. Ackermann Regular and Related Solutions , 1973 .

[21]  R. Battino,et al.  Low-pressure solubility of gases in liquid water , 1977 .

[22]  R. Pierotti,et al.  THE SOLUBILITY OF GASES IN LIQUIDS1 , 1963 .

[23]  R. Battino,et al.  The solubility of gases in liquids 6. Solubility of N2, O2, CO, CO2, CH4, and CF4 in methylcyclohexane and toluene at 283 to 313 K , 1974 .

[24]  Howard Reiss,et al.  Aspects of the Statistical Thermodynamics of Real Fluids , 1960 .

[25]  R. Battino,et al.  The solubility of gases in liquids 7. The solubilities of N2, O2, Ar, CO, CO2, and c-C3H6 in benzene and isobutanol solutions of cholesterol, lecithin, and cephalin at 310.65 K , 1974 .

[26]  K. Miller,et al.  Site of Action of General Anaesthetics , 1965, Nature.

[27]  J. Prausnitz,et al.  Entropies of Vaporization of Hydrocarbons and the Hildebrand Rule , 1961 .

[28]  R. Battino,et al.  The Solubility of Helium, Neon, Argon and Krypton in Some Hydrocarbon Solvents , 1957 .