论文信息 - Novel synthesis of substoichiometric ultrafine titanium carbide

Novel synthesis of substoichiometric ultrafine titanium carbide

Abstract Ultrafine titanium carbide particles were synthesized by liquid-magnesium reduction of vaporized TiCl 4 +CCl 4 solution. Fine TiC particles were produced by the reaction of released Ti and C atoms, and after reduction process vacuum was used to remove the residual phases of MgCl 2 and excess Mg. Fixed and free carbon were measured in products synthesized with various parameters as well as stoichiometry and microstructure.

D. W. Lee | B. K. Kim | S. V. Alexandrovskii | S. Alexandrovskii

[1] Lutz-Michael Berger,et al. Studies on the Carbothermal Preparation of Titanium Carbide from Different Gel Precursors , 1999 .

[2] N. Thadhani,et al. REACTION SYNTHESIS MECHANISM IN DYNAMICALLY DENSIFIED Ti + C POWDER COMPACTS , 1997 .

[3] T. Helander,et al. An Experimental Investigation of Possible B2-Ordering in the Al-Cr System , 1999 .

[4] P. Ettmayer,et al. Ti(C,N) cermets — Metallurgy and properties , 1995 .

[5] N. Durlu. Titanium carbide based composites for high temperature applications , 1999 .