The role of atmospheric ions in aerosol nucleation – a review

Atmospheric aerosols affect climate and yet the reason for many observed events of new aerosol formation is not understood. One of the theories put forward to explain these events is that the presence of ions can enhance the formation of aerosols. The theory is called Ion Induced Nucleation and in this paper the state of observations, theory and experiments within the field will be reviewed. While evidence for Ion Induced Nucleation is accumulating the exact mechanism is still not known and more research is required to understand and quantify the effect.

[1]  G. Yue On the characteristics of sulfate aerosols formed in the presence of ion sources , 1979 .

[2]  I. Riipinen,et al.  Initial steps of aerosol growth , 2004 .

[3]  Bandy,et al.  Particle nucleation in the tropical boundary layer and its coupling to marine sulfur sources , 1998, Science.

[4]  A. Clarke,et al.  Nucleation in the equatorial Pacific during PEM‐Tropics B: Enhanced boundary layer H2SO4 with no particle production , 2001 .

[5]  L. W. Pollak,et al.  INSTRUCTION FOR USE OF PHOTO-ELECTRIC CONDENSATION NUCLEUS COUNTERS--THEIR CARE AND MAINTENANCE TOGETHER WITH CALIBRATION AND AUXILIARY TABLES. Geophysical Bulletin No. 16. Technical (Scientific) Note No. 6 , 1959 .

[6]  J. Smith,et al.  Contribution of ion‐induced nucleation to new particle formation: Methodology and its application to atmospheric observations in Boulder, Colorado , 2006 .

[7]  D. R. Hanson,et al.  Laboratory studies of particle nucleation: Initial results for H2SO4, H2O, and NH3 vapors , 1999 .

[8]  F. Yu Interactive comment on “Ion-mediated nucleation as an important global source oftropospheric aerosols” by F. Yu et al , 2007 .

[9]  K. Froyd,et al.  Cluster Ion Thermal Decomposition (I): Experimental Kinetics Study and Ab Initio Calculations for HSO4-(H2SO4)x(HNO3)y , 2001 .

[10]  R. Turco,et al.  The formation and evolution of aerosols in stratospheric aircraft plumes: Numerical simulations and comparisons with observations , 1998 .

[11]  D. Albritton,et al.  Chapter 2 – Ion chemistry of the earth's atmosphere , 1979 .

[12]  M. Komppula,et al.  Size distributions of atmospheric ions in the Baltic Sea region , 2007 .

[13]  F. Raes,et al.  A synergism between ultraviolet and gamma radiation in producing aerosol particles from SO2H2SO4 laden atmospheres , 1985 .

[14]  M. Barth,et al.  Aerosol nucleation over oceans and the role of galactic cosmic rays , 2006 .

[15]  K. Lehtinen,et al.  Kinetic nucleation and ions in boreal forest particle formation events , 2004 .

[16]  M. Kulmala,et al.  Rapid Formation of Sulfuric Acid Particles at Near-Atmospheric Conditions , 2005, Science.

[17]  K. Froyd,et al.  Atmospheric Ion-induced Aerosol Nucleation , 2007 .

[18]  W. Birmili,et al.  The Hohenpeissenberg aerosol formation experiment (HAFEX): a long-term study including size-resolved aerosol, H 2 SO 4 , OH, and monoterpenes measurements , 2002 .

[19]  B. C. Garrett,et al.  Ion-induced nucleation: the importance of chemistry. , 2005, Physical review letters.

[20]  J. Seinfeld,et al.  Atmospheric Chemistry and Physics: From Air Pollution to Climate Change , 1997 .

[21]  Petra M. Udelhofen,et al.  Cloud cover variations over the United States: An influence of cosmic rays or solar variability? , 2001 .

[22]  Y. Viisanen,et al.  Experiments on gas–liquid nucleation of sulfuric acid and water , 1997 .

[23]  I. Riipinen,et al.  Identification and classification of the formation of intermediate ions measured in boreal forest , 2006 .

[24]  K. Aplin,et al.  Atmospheric condensation nuclei formation and high-energy radiation , 2001 .

[25]  Hannes Tammet,et al.  Finnish-Estonian air ion and aerosol workshops , 2007 .

[26]  J. W. Fitzgerald,et al.  Marine boundary layer measurements of new particle formation and the effects nonprecipitating clouds have on aerosol size distribution , 1994 .

[27]  K. Lehtinen,et al.  Heterogeneous Nucleation Experiments Bridging the Scale from Molecular Ion Clusters to Nanoparticles , 2008, Science.

[28]  Henrik Svensmark,et al.  Variation of cosmic ray flux and global cloud coverage—a missing link in solar-climate relationships , 1997 .

[29]  F. Arnold,et al.  Laboratory study of cluster ions formation in H2SO4–H2O system: Implications for threshold concentration of gaseous H2SO4 and ion-induced nucleation kinetics , 2007 .

[30]  J. Salm,et al.  Air ion measurements as a source of information about atmospheric aerosols , 1998 .

[31]  M. Kulmala,et al.  Variation and balance of positive air ion concentrations in a boreal forest , 2008 .

[32]  W. J. Megaw,et al.  The generation of condensation nuclei by ionising radiation , 1961 .

[33]  D. Stephenson,et al.  Empirical evidence for a nonlinear effect of galactic cosmic rays on clouds , 2006, Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences.

[34]  R. Turco,et al.  A new source of tropospheric aerosols: Ion‐ion recombination , 1998 .

[35]  K. Lehtinen,et al.  Charging state of the atmospheric nucleation mode : Implications for separating neutral and ion-induced nucleation , 2007 .

[36]  T. Petäjä,et al.  Detecting charging state of ultrafine particles : instrumental development and ambient measurements , 2006 .

[37]  D. Stauffer,et al.  Chemical nucleation theory for various humidities and pollutants , 1973 .

[38]  A. Bandy,et al.  Measurements of enhanced H2SO4 and 3–4 nm particles near a frontal cloud during the First Aerosol Characterization Experiment (ACE 1) , 2001 .

[39]  K. Lehtinen,et al.  Condensation and coagulation sinks and formation of nucleation mode particles in coastal and boreal forest boundary layers , 2002 .

[40]  K. Lehtinen,et al.  Ion production rate in a boreal forest based on ion, particle and radiation measurements , 2004 .

[41]  J. Haigh,et al.  The Influence of Solar Changes on the Earth’s Climate , 2005 .

[42]  A. Kip,et al.  On the Nature of Ionic Sign Preference in C. T. R. Wilson Cloud Chamber Condensation Experiments , 1938 .

[43]  J. Seinfeld,et al.  Nanometer-sized particle formation from NH3/SO2/H2O/Air mixtures by ionizing irradiation , 1998 .

[44]  R. Hillamo,et al.  Charged particle size distributions and analysis of particle formation events at the Finnish Antarctic research station Aboa , 2007 .

[45]  C. O'Dowd,et al.  On the photochemical production of new particles in the coastal boundary layer , 1999 .

[46]  F. Yu,et al.  Dipole Moment of Condensing Monomers: A New Parameter Controlling the Ion-Induced Nucleation , 2004 .

[47]  F. Arnold,et al.  Multi-ion complexes in the stratosphere—implications for trace gases and aerosol , 1980, Nature.

[48]  R. Turco,et al.  Evolution of aircraft‐generated volatile particles in the far wake regime: Potential contributions to ambient CCN/IN , 1999 .

[49]  J. Curtius,et al.  Nucleation of atmospheric aerosol particles , 2006 .

[50]  J. Seinfeld,et al.  Binary nucleation in acid–water systems. II. Sulfuric acid–water and a comparison with methanesulfonic acid–water , 1991 .

[51]  J. M. Reeves,et al.  Particle Formation by Ion Nucleation in the Upper Troposphere and Lower Stratosphere , 2003, Science.

[52]  H. Lihavainen,et al.  Observations of ultrafine aerosol particle formation and growth in boreal forest , 1997 .

[53]  K. Froyd,et al.  Experimental Thermodynamics of Cluster Ions Composed of H2SO4 and H2O. Part 1. Positive Ions. , 2004 .

[54]  R. Turco,et al.  Ultrafine aerosol formation via ion‐mediated nucleation , 2000 .

[55]  K. Froyd,et al.  Experimental Thermodynamics of Cluster Ions Composed of H2SO4 and H2O. 1. Positive Ions , 2003 .

[56]  J. Salm,et al.  Bursts of intermediate ions in atmospheric air , 1998 .

[57]  T. Petäjä,et al.  Ion and particle number concentrations and size distributions along the Trans-Siberian railroad , 2007 .

[58]  M. Kulmala,et al.  Quantum chemical studies of hydrate formation of h 2 so 4 and hso 4 – , 2007 .

[59]  J. Seinfeld,et al.  Experimental studies of ion-induced nucleation , 1992 .

[60]  K. Froyd,et al.  Experimental Thermodynamics of Cluster Ions Composed of H2SO4 and H2O. 2. Measurements and ab Initio Structures of Negative Ions , 2003 .

[61]  K. Lehtinen,et al.  Size distributions of atmospheric ions inside clouds and in cloud-free air at a remote continental site , 2007 .

[62]  R. Turco,et al.  An analysis of various nucleation mechanisms for sulfate particles in the stratosphere , 1982 .

[63]  F. Raes,et al.  Ion-induced aerosol formation in a H2O-H2SO4 system—I. Extension of the classical theory and search for experimental evidence , 1985 .

[64]  R. Busen,et al.  Massive Positive and Negative Chemiions in the Exhaust of an Aircraft Jet Engine at Ground Level: Mass Distribution Measurements and implications for Aerosol Formation , 2002 .

[65]  A. Castleman,et al.  Thomson equation revisited in light of ion-clustering experiments , 1982 .

[66]  F. Yu From molecular clusters to nanoparticles: second-generation ion-mediated nucleation model , 2006 .

[67]  P. Mcmurry,et al.  MEASURED ATMOSPHERIC NEW PARTICLE FORMATION RATES: IMPLICATIONS FOR NUCLEATION MECHANISMS , 1996 .

[68]  C. Wilson VI. The effect of Röntgen’s rays on cloudy condensation , 1896, Proceedings of the Royal Society of London.

[69]  L. Pirjola,et al.  Stable sulphate clusters as a source of new atmospheric particles , 2000, Nature.

[70]  K. Mikkelsen,et al.  Nadykto etal. Reply , 2007 .

[71]  F. Arnold,et al.  Formation and growth of sulfuric acid-water cluster ions: Experiments, modelling, and implications for ion-induced aerosol formation , 2006 .

[72]  P. Mcmurry,et al.  Measurements of new particle formation and ultrafine particle growth rates at a clean continental site , 1997 .

[73]  F. Yu Modified Kelvin-Thomson equation considering ion-dipole interaction: comparison with observed ion-clustering enthalpies and entropies. , 2005, The Journal of chemical physics.

[74]  I. Riipinen,et al.  Toward Direct Measurement of Atmospheric Nucleation , 2007, Science.

[75]  Hanna Vehkamäki,et al.  Formation and growth rates of ultrafine atmospheric particles: a review of observations , 2004 .

[76]  R. Harrison Cloud Formation and the Possible Significance of Charge for Atmospheric Condensation and Ice Nuclei , 2000 .

[77]  C. Wilson On the Condensation Nuclei Produced in Gases by the Action of Rontgen Rays, Uranium Rays, Ultra-Violet Light, and Other Agents , 1899 .

[78]  H. Svensmark,et al.  Galactic cosmic ray and El Nino Southern Oscillation trends in International Satellite Cloud Climatology Project D2 low-cloud properties , 2003 .

[79]  R. Dickinson Solar variability and the lower atmosphere. , 1975 .

[80]  Richard P. Turco,et al.  From molecular clusters to nanoparticles: Role of ambient ionization in tropospheric aerosol formation , 2001 .

[81]  Howard Reiss,et al.  The Kinetics of Phase Transitions in Binary Systems , 1950 .

[82]  Martin Bødker Enghoff,et al.  Experimental evidence for the role of ions in particle nucleation under atmospheric conditions , 2007, Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences.

[83]  K. Froyd,et al.  Atmospheric ion‐induced nucleation of sulfuric acid and water , 2004 .

[84]  F. Fehsenfeld,et al.  Laboratory studies of negative ion reactions with atmospheric trace constituents , 1974 .

[85]  R. Betts,et al.  Changes in Atmospheric Constituents and in Radiative Forcing. Chapter 2 , 2007 .

[86]  Ari Laaksonen,et al.  Cluster activation theory as an explanation of the linear dependence between formation rate of 3nm particles and sulphuric acid concentration , 2006 .

[87]  M. Bowers Gas phase ion chemistry , 1979 .

[88]  T. S. Muraleedharan,et al.  An experimental study of the role of radon and its daughter products in the conversion of sulphur dioxide into aerosol particles in the atmosphere , 1984 .

[89]  M. Kulmala,et al.  Indoor and outdoor air ions and aerosol particles in the urban atmosphere of Helsinki: characteristics, sources and formation , 2007 .

[90]  P. Mirabel,et al.  Experimental study of vapor nucleation on ions , 1987 .

[91]  Sonia M. Kreidenweis,et al.  A study of new particle formation and growth involving biogenic and trace gas species measured during ACE 1 , 1998 .

[92]  K. Mikkelsen,et al.  Quantum nature of the sign preference in ion-induced nucleation. , 2006, Physical review letters.

[93]  B. Tinsley Influence of Solar Wind on the Global Electric Circuit, and Inferred Effects on Cloud Microphysics, Temperature, and Dynamics in the Troposphere , 2000 .

[94]  Ion-induced aerosol formation: new insights from laboratory measurements of mixed cluster ions HSO4−(H2SO4)a(H2O)w and H+(H2SO4)a(H2O)w , 2004 .

[95]  J. Seinfeld,et al.  Experimental Measurement of Competitive Ion-Induced and Binary Homogeneous Nucleation in SO2/H2O/N2 Mixtures , 1997 .

[96]  F. Stratmann,et al.  Formation of atmospheric H2SO4/H2O particles in the absence of organics: A laboratory study , 2006 .

[97]  R. Turco,et al.  Ion-mediated nucleation as an important global source of tropospheric aerosols , 2007 .

[98]  M. Kulmala,et al.  Charging state of atmospheric nanoparticles during the nucleation burst events , 2006 .

[99]  R. Turco,et al.  Correspondence [ to “Ultrafine aerosol formation via ion‐mediated nucleation”] , 2000 .

[100]  F. Arnold Atmospheric Aerosol and Cloud Condensation Nuclei Formation: A Possible Influence of Cosmic Rays? , 2007 .

[101]  E. Lovejoy,et al.  Cluster Ion Thermal Decomposition (II): Master Equation Modeling in the Low-Pressure Limit and Fall-Off Regions. Bond Energies for HSO4-(H2SO4)x(HNO3)y , 2001 .

[102]  A. Viggiano In situ mass spectrometry and ion chemistry in the stratosphere and troposphere , 1993 .

[103]  M. Kulmala,et al.  Quantum chemical studies of hydrate formation of H2SO4 and HSO4 , 2007 .

[104]  M. S. El-shall,et al.  Kinetics of ion-induced nucleation in a vapor-gas mixture. , 2005, The Journal of chemical physics.

[105]  M. Kulmala,et al.  Road-side measurements of aerosol and ion number size distributions : a comparison with remote site measurements , 2007 .

[106]  K. Aplin,et al.  A computer-controlled Gerdien atmospheric ion counter , 2000 .

[107]  J. Bricard,et al.  Formation and evolution of nuclei of condensation that appear in air initially free of aerosols , 1968 .

[108]  F. Arnold,et al.  Cosmic ray‐induced aerosol‐formation: First observational evidence from aircraft‐based ion mass spectrometer measurements in the upper troposphere , 2002 .

[109]  L. Pirjola,et al.  Model studies on ion‐induced nucleation in the atmosphere , 2002 .