Studying the Wettability and Bonding Properties of Acetylated Hornbeam Wood Using PVAc and PUR Adhesives

The present study aimed to determine how acetylation affected the bonding properties of European hornbeam wood. The research was supplemented with the investigation of wetting properties, wood shear strength, and microscopical studies of bonded wood, as these all have strong relationships with wood bonding. Acetylation was carried out on an industrial scale. Acetylated hornbeam showed a higher contact angle and lower surface energy than untreated hornbeam. Although the adhesion of the acetylated wood surface is lower due to its lower polarity and porosity, the bonding strength of acetylated hornbeam was similar to that of untreated hornbeam when bonded with PVAc D3 adhesive, and it was higher in the case of PVAc D4 and PUR adhesives. Microscopical studies proved these findings. After acetylation, hornbeam could be used in applications where it is exposed to moisture, as its bonding strength after soaking or boiling in water was significantly higher than that of untreated hornbeam.

[1]  H. Militz,et al.  Bonding performance of hot-bonded acetylated beech (Fagus sylvatica L.) laminated veneer lumber (LVL) , 2022, Wood Material Science & Engineering.

[2]  R. Rousek,et al.  Microscopic characterization of sound and decayed acetylated hornbeam (Carpinus betulus L.) , 2022, Wood Material Science & Engineering.

[3]  R. Ibach,et al.  Comparative Adhesive Bonding of Wood Chemically Modified with Either Acetic Anhydride or Butylene Oxide , 2021, Forests.

[4]  A. Brunner,et al.  Quasi-static and fatigue performance of bonded acetylated rubberwood (Hevea brasiliensis, Müll. Arg.) , 2020, European Journal of Wood and Wood Products.

[5]  A. Treu,et al.  Enhanced bonding of acetylated wood with an MUF-based adhesive and a resorcinol-formaldehyde-based primer , 2019 .

[6]  Reza Hosseinpourpia,et al.  Ammonium Lignosulfonate Adhesives for Particleboards with pMDI and Furfuryl Alcohol as Crosslinkers , 2019, Polymers.

[7]  H. Militz,et al.  Distinctive Impact of Processing Techniques on Bonding Surfaces of Acetylated and Heat-Treated Beech Wood and Its Relation to Bonding Strength* , 2019 .

[8]  T. Hofmann,et al.  Effect of acetylation on the chemical composition of hornbeam (Carpinus betulus L.) in relation with the physical and mechanical properties , 2018 .

[9]  R. Németh,et al.  Testing common hornbeam (Carpinus betulus L.) acetylated with the Accoya method under industrial conditions , 2017 .

[10]  R. Ibach,et al.  Adhesives for Achieving Durable Bonds with Acetylated Wood , 2017, Polymers.

[11]  M. Wålinder,et al.  Microstructure of chemically modified wood using X-ray computed tomography in relation to wetting properties , 2017 .

[12]  J. Konnerth,et al.  Survey of selected adhesive bonding properties of nine European softwood and hardwood species , 2016, European Journal of Wood and Wood Products.

[13]  M. Altinok,et al.  Bonding Strength of Some Adhesives in Heat-Treated Hornbeam (Carpinus betulus L.) Wood Used for Interior and Exterior Decoration , 2016 .

[14]  S. Adamopoulos,et al.  Study of adhesive bondlines in modified wood with fluorescence microscopy and X-ray micro-computed tomography , 2016 .

[15]  H. Militz,et al.  Bonding of acetylated wood , 2016 .

[16]  S. Adamopoulos,et al.  Gross adhesive penetration in furfurylated, N-methylol melamine-modified and heat-treated wood examined by fluorescence microscopy , 2015, European Journal of Wood and Wood Products.

[17]  Maziar Sedighi Moghaddam,et al.  Wettability and swelling of acetylated and furfurylated wood analyzed by multicycle Wilhelmy plate method , 2015 .

[18]  Julian Marcroft,et al.  Structural Performance of Accoya® Wood under Service Class 3 Conditions , 2014 .

[19]  M. Wålinder,et al.  Wettability of acetylated Southern yellow pine , 2013 .

[20]  M. Šernek,et al.  Microscopic analysis of the wood bond line using liquefied wood as adhesive , 2013 .

[21]  H. R. Taghiyari CORRELATION BETWEEN GAS AND LIQUID PERMEABILITIES IN SOME NANOSILVER-IMPREGNATED AND UNTREATED HARDWOODS , 2012 .

[22]  P. Niemz,et al.  Influence of the adhesive formulation on the mechanical properties and bonding performance of polyurethane prepolymers , 2011 .

[23]  H. Herrmann,et al.  Adhesive penetration in beech wood: experiments , 2011, Wood Science and Technology.

[24]  H. Herrmann,et al.  Adhesive penetration of hardwood: a generic penetration model , 2011, Wood Science and Technology.

[25]  H. Herrmann,et al.  Adhesive Penetration in Beech Wood Part I: Experiments , 2010, 1007.0762.

[26]  H. Herrmann,et al.  Adhesive penetration in Beech wood Part II: Penetration Model , 2010, 1007.0761.

[27]  L. Bryne,et al.  Ageing of modified wood. Part 1: Wetting properties of acetylated, furfurylated, and thermally modified wood , 2010 .

[28]  A. Pilgård,et al.  Material properties of furfurylated wood for window production , 2010 .

[29]  Charles R. Frihart,et al.  Adhesive Groups and How They Relate to the Durability of Bonded Wood , 2009 .

[30]  L. Bryne Aspects on wettability and surface composition of modified wood , 2008 .

[31]  F. Kamke,et al.  ADHESIVE PENETRATION IN WOOD—A REVIEW , 2007 .

[32]  F. Kamke,et al.  Penetration of Liquid Urea-Formaldehyde Adhesive into Beech Wood , 2007 .

[33]  N. Yan,et al.  Characterizing Liquid Resin Penetration In Wood Using A Mercury Intrusion Porosimeter , 2007 .

[34]  O. Suchsland Über das Eindringen des Leimes bei der Holzverleimung und die Bedeutung der Eindringtiefe für die Fugenfestigkeit , 1958, Holz als Roh- und Werkstoff.

[35]  R. Ibach,et al.  Effects of Chemically Modified Wood on Bond Durability , 2007 .

[36]  Acetylation of Wood-Journey from Analytical Technique to Commerial Reality , 2007 .

[37]  R. Ibach,et al.  What does bonding to modified wood tell us about adhesion , 2007 .

[38]  Seung‐Hwan Lee,et al.  Adhesive penetration of wood cell walls investigated by scanning thermal microscopy (SThM) , 2007 .

[39]  P. Tingaut,et al.  Penetration of amino-silicone micro- and macro-emulsions into Scots pine sapwood and the effect on water-related properties , 2007 .

[40]  R. Moon,et al.  Effects of swelling forces on the durability of wood adhesive bonds , 2006 .

[41]  C. Frihart,et al.  Examination of adhesive penetration in modified wood using fluorescence microscopy , 2005 .

[42]  P. Niemz,et al.  Untersuchungen zur Verteilung des Klebstoffes im Bereich der Leimfuge mittels Neutronenradiographie und Mikroskopie , 2004, Holz als Roh- und Werkstoff.

[43]  J. E. Reeb,et al.  Relating traditional surface roughness measures to gluebond quality in plywood , 2004 .

[44]  E. Beckers,et al.  Mechanical properties of acetylated solid wood treated on pilot plant scale , 2003 .

[45]  C. Boehme,et al.  Water Absorption and Contact Angle Measurement of Native European, North American and Tropical Wood Species to Predict Gluing Properties , 1996 .

[46]  R. Rowell,et al.  Structural bonding of acetylated Scandinavian softwoods for exterior lumber laminates , 1993 .

[47]  Alan A. Marra,et al.  Technology of Wood Bonding : Principles in Practice , 1992 .

[48]  R. Rowell,et al.  Adhesive bonding of acetylated pine and spruce , 1992 .

[49]  R. Rowell,et al.  Adhesive bonding of acetylated wood , 1990 .

[50]  R. Rowell,et al.  Adhesive bonding of acetylated aspen flakes, Part 2. Effects of emulsifiers on phenolic resin bonding , 1988 .

[51]  R. Rowell,et al.  Adhesive bonding of acetylated aspen flakes. Part 1. Surface changes, hydrophobicity, adhesive penetration and strength , 1987 .

[52]  R. Krahmer,et al.  Relationship between chemical characteristics of phenol-formaldehyde resins and adhesive performance , 1985 .

[53]  John Finn Siau,et al.  Transport Processes in Wood , 1984, Springer Series in Wood Science.

[54]  D. K. Owens,et al.  Estimation of the surface free energy of polymers , 1969 .