Temperature-Responsive Switch Constructed from an Anthracene-Functionalized Pillar[5]arene-Based Host-Guest System.

A monofunctionalized anthracene pillar[5]arene (MAP5) was designed and synthesized by a click reaction. MAP5 was bound to an ionic liquid through host-guest interactions to modify a gold interface. The bonding and release of MAP5 was readily and reversibly controlled by temperature regulation. The developed temperature-responsive switch at an interface can be used in memory storage, drug delivery, and sensing.

[1]  V. Truong,et al.  Simultaneous orthogonal dual-click approach to tough, in-situ-forming hydrogels for cell encapsulation. , 2015, Journal of the American Chemical Society.

[2]  Wei Zhao,et al.  Cationic vesicles based on amphiphilic pillar[5]arene capped with ferrocenium: a redox-responsive system for drug/siRNA co-delivery. , 2014, Angewandte Chemie.

[3]  Zhuxian Zhou,et al.  Molecularly precise dendrimer-drug conjugates with tunable drug release for cancer therapy. , 2014, Angewandte Chemie.

[4]  R. Raines,et al.  Optimal Interstrand Bridges for Collagen-like Biomaterials , 2014, Journal of the American Chemical Society.

[5]  G. Belfort,et al.  Egg white varnishes on ancient paintings: a molecular connection to amyloid proteins. , 2014, Angewandte Chemie.

[6]  Yongmei Zheng,et al.  Controlled directional water-droplet spreading on a high-adhesion surface. , 2014, Angewandte Chemie.

[7]  Feihe Huang,et al.  LCST‐Type Phase Behavior Induced by Pillar[5]arene/Ionic Liquid Host–Guest Complexation , 2013, Advanced materials.

[8]  Xiaofan Ji,et al.  A Novel Diblock Copolymer with a Supramolecular Polymer Block and a Traditional Polymer Block: Preparation, Controllable Self‐Assembly in Water, and Application in Controlled Release , 2013, Advanced materials.

[9]  E. Saiz,et al.  Designing smart particles for the assembly of complex macroscopic structures. , 2013, Angewandte Chemie.

[10]  M. Rubčić,et al.  Dynamic molecular recognition in solid state for separating mixtures of isomeric dicarboxylic acids. , 2013, Angewandte Chemie.

[11]  Feihe Huang,et al.  A supramolecular cross-linked conjugated polymer network for multiple fluorescent sensing. , 2013, Journal of the American Chemical Society.

[12]  Xia Ding,et al.  A Multiresponsive, Shape‐Persistent, and Elastic Supramolecular Polymer Network Gel Constructed by Orthogonal Self‐Assembly , 2012, Advanced materials.

[13]  Ying Li,et al.  Synthesis of a redox-responsive quadruple hydrogen-bonding unit for applications in supramolecular chemistry. , 2011, Journal of the American Chemical Society.

[14]  Guosong Chen,et al.  Dual responsive supramolecular hydrogel with electrochemical activity. , 2011, Langmuir : the ACS journal of surfaces and colloids.

[15]  K. Müllen,et al.  A fluorescent, shape-persistent dendritic host with photoswitchable guest encapsulation and intramolecular energy transfer. , 2011, Journal of the American Chemical Society.

[16]  Bo Zheng,et al.  A dual-responsive supramolecular polymer gel formed by crown ether based molecular recognition. , 2011, Angewandte Chemie.

[17]  Feihe Huang,et al.  Supramolecular AA-BB-type linear polymers with relatively high molecular weights via the self-assembly of bis(m-phenylene)-32-crown-10 cryptands and a bisparaquat derivative. , 2011, Journal of the American Chemical Society.

[18]  Ying Wang,et al.  Controlling binding affinities for anions by a photoswitchable foldamer. , 2010, Organic letters.

[19]  Feihe Huang,et al.  Photoresponsive host-guest systems based on a new azobenzene-containing cryptand. , 2010, Organic letters.

[20]  Feihe Huang,et al.  Metal coordination mediated reversible conversion between linear and cross-linked supramolecular polymers. , 2010, Angewandte Chemie.

[21]  M. Amelia,et al.  Probing donor-acceptor interactions and co-conformational changes in redox active desymmetrized [2]catenanes. , 2010, Journal of the American Chemical Society.

[22]  Feihe Huang,et al.  Responsive supramolecular gels constructed by crown ether based molecular recognition. , 2009, Angewandte Chemie.

[23]  A. Credi,et al.  Cyclohexenylphenyldiazene: a simple surrogate of the azobenzene photochromic unit. , 2007, Journal of the American Chemical Society.

[24]  Sarah J. Vella,et al.  Push-pull [2]pseudorotaxanes. Electronic control of threading by switching ON/OFF an intramolecular charge transfer. , 2006, Organic letters.

[25]  Allan S Hoffman,et al.  Poly(N-isopropylacrylamide-co-propylacrylic acid) copolymers that respond sharply to temperature and pH. , 2006, Biomacromolecules.

[26]  Xi Zhang,et al.  Polymer micelles as building blocks for the incorporation of azobenzene: enhancing the photochromic properties in layer-by-layer films. , 2006, Langmuir : the ACS journal of surfaces and colloids.

[27]  A. Kaifer,et al.  Dimeric molecular capsules under redox control. , 2004, Journal of the American Chemical Society.

[28]  A. Kaifer,et al.  Cucurbit[8]uril-mediated redox-controlled self-assembly of viologen-containing dendrimers. , 2004, Angewandte Chemie.

[29]  He Tian,et al.  A Single Photochromic Molecular Switch with Four Optical Outputs Probing Four Inputs , 2003 .

[30]  Takuzo Aida,et al.  Light-driven open-close motion of chiral molecular scissors. , 2003, Journal of the American Chemical Society.

[31]  A. Bosman,et al.  Crowned dendrimers: pH-responsive pseudorotaxane formation. , 2003, The Journal of organic chemistry.

[32]  P. K. Bharadwaj,et al.  Supramolecular amphiphiles: spontaneous formation of vesicles triggered by formation of a charge-transfer complex in a host. , 2002, Angewandte Chemie.

[33]  A. Kaifer,et al.  Electrochemically driven formation of a molecular capsule around the ferrocenium ion. , 2002, Journal of the American Chemical Society.

[34]  Ashutosh Chilkoti,et al.  Targeted drug delivery by thermally responsive polymers. , 2002, Advanced drug delivery reviews.

[35]  Richard A. Silva,et al.  Unidirectional rotary motion in a molecular system , 1999, Nature.

[36]  N. Harada,et al.  Light-driven monodirectional molecular rotor , 2022 .

[37]  W. Hennink,et al.  Thermosensitive polymers as carriers for DNA delivery. , 1999, Journal of controlled release : official journal of the Controlled Release Society.

[38]  Pablo Gaviña,et al.  Rotaxanes Incorporating Two Different Coordinating Units in Their Thread: Synthesis and Electrochemically and Photochemically Induced Molecular Motions , 1999 .

[39]  Jean-Pierre Sauvage,et al.  Transition Metal-Containing Rotaxanes and Catenanes in Motion: Toward Molecular Machines and Motors , 1998 .

[40]  Mitsuhiro Shibayama,et al.  Cross-link Density Dependence of Spatial Inhomogeneities and Dynamic Fluctuations of Poly(N-isopropylacrylamide) Gels , 1996 .

[41]  Jean-Pierre Sauvage,et al.  Electrochemically Triggered Swinging of a [2]-Catenate. , 1994, Journal of the American Chemical Society.

[42]  H. G. Schild.  Poly(N-isopropylacrylamide): experiment, theory and application , 1992 .