New Strategy and Excellent Fluorescence Property of Unique Core-Shell Structure Based on Liquid Metals/Metal Halides.

The further applications of liquid metals (LMs) are limited by their common shortcoming of silver-white physical appearance, which deviates from the impose stringent requirements for color and aesthetics. Herein, a concept is proposed for constructing fluorescent core-shell structures based on the components and properties of LMs, and metal halides. The metal halides endow LMs with polychromatic and stable fluorescence characteristics. As a proof-of-concept, LMs-Al obtained by mixing of LMs with aluminum (Al) is reported. The surface of LMs-Al is transformed directly from Al to a multi-phase metal halide of K3 AlCl6 with double perovskites structure, via redox reactions with KCl + HCl solution in a natural environment. The formation of core-shell structure from the K3 AlCl6 and LMs is achieved, and the shell with different phases can emit a cyan light by the superimposition of the polychromatic spectrum. Furthermore, the LMs can be directly converted into a fluorescent shell without affecting their original features. In particular, the luminescence properties of shells can be regulated by the components in LMs. This study provides a new direction for research in spontaneous interfacial modification and fluorescent functionalization of LMs and promises potential applications, such as lighting and displays, anti-counterfeiting measures, sensing, and chameleon robots.