Lithology and mineralisation types of the Rockliden Zn–Cu massive sulphide deposit, north-central Sweden: Implications for ore processing

Abstract The Rockliden Zn–Cu volcanic-hosted massive sulphide deposit is located approximately 150 km south of the Skellefte ore district, north-central Sweden. Most of the mineralisation is found at the altered stratigraphic top of the felsic volcanic rocks, which are intercalated in the metamorphosed siliciclastic sedimentary rocks of the Bothnian Basin. Mafic dykes cross-cut all lithological units, including the massive sulphides, at the Rockliden deposit. The relatively high Sb grade of some parts of the mineralisation results in challenges in handling of the Cu–Pb concentrate in the smelting process. The aim of this study is to characterise different host rock units and ore types by their main mineralogy, as well as by their trace mineralogy with focus on the Sb-bearing minerals. Ore types are distinguished largely on the basis of their main base-metal bearing sulphide minerals, which are chalcopyrite and sphalerite. Several Sb-bearing minerals are documented and differences in the trace mineralogy between rock and ore types are highlighted. Based on the qualitative ore characterisation, rock- and ore-intrinsic parameters, such as the pyrite, pyrrhotite and magnetite content of the massive sulphides, the trace mineralogy and its association with base-metal sulphide minerals, are outlined and discussed in terms of relevance to the ore processing.

[1]  C. Wanhainen,et al.  Detailed characterisation of antimony mineralogy in a geometallurgical context at the Rockliden ore deposit, North-Central Sweden , 2013 .

[2]  F. Minz Mineralogical characterisation of the Rockliden antimony-bearing volcanic-hosted massive sulphide deposit, Sweden , 2013 .

[3]  S. Awe Antimony recovery from complex copper concentrates through hydro- and electrometallurgical processes , 2013 .

[4]  P. Lamberg Particles - the bridge between geology and metallurgy , 2011 .

[5]  G. Depauw Geology of the Rockliden volcanogenic massive sulphide deposit, north central Sweden , 2009 .

[6]  S. Elming,et al.  The Central Scandinavian Dolerite Group—Protracted hotspot activity or back-arc magmatism?: Constraints from U–Pb baddeleyite geochronology and Hf isotopic data , 2006 .

[7]  A. Galley,et al.  Volcanogenic Massive Sulfide Deposits , 2005 .

[8]  P. Weihed Overview of the Geology and Tectonic Setting of Northern Sweden , 2004 .

[9]  M. P. Gorton,et al.  APPLICATION OF HIGH FIELD STRENGTH ELEMENTS TO DISCRIMINATE TECTONIC SETTINGS IN VMS ENVIRONMENTS , 2002 .

[10]  R. Rutland,et al.  Nature of a major tectonic discontinuity in the Svecofennian province of northern Sweden. , 2001 .

[11]  S. Williams,et al.  The impact of ore characterization and blending on metallurgical plant performance , 2001 .

[12]  Ross R. Large,et al.  The Alteration Box Plot: A Simple Approach to Understanding the Relationship between Alteration Mineralogy and Lithogeochemistry Associated with Volcanic-Hosted Massive Sulfide Deposits , 2001 .

[13]  W. Petruk,et al.  Applied Mineralogy in the Mining Industry , 2000 .

[14]  W. Petruk Applied mineralogy: Porphyry copper deposits , 2000 .

[15]  P. Persson,et al.  U-Pb ages of plutonic and volcanic rocks in the Svecofennian Bothnian Basin, central Sweden, and their implications for the Palaeoproterozoic evolution of the Basin , 1998 .

[16]  D.,et al.  VOLCANOGENIC MASSIVE SULPHIDE DEPOSITS , 1998 .

[17]  T. Wagner,et al.  Mineral reactions in sulphide systems as indicators of evolving fluid geochemistry − a case study from the Apollo mine, Siegerland, FRG , 1997, Mineralogical Magazine.

[18]  M. Hannington,et al.  Classification of Volcanic-Associated Massive Sulfide Deposits Based on Host-Rock Composition , 1997 .

[19]  P. Weihed,et al.  Setting of Zn-Cu-Au-Ag massive sulfide deposits in the evolution and facies architecture of a 1.9 Ga marine volcanic arc, Skellefte District, Sweden , 1996 .

[20]  C. Mellqvist The Archaean–Proterozoic Palaeoboundary in the Luleå area, northern Sweden: field and isotope geochemical evidence for a sharp terrane boundary , 1999 .

[21]  T. Lundqvist,et al.  Origins and ages of Proterozoic granitoids in the Bothnian Basin, central Sweden; isotopic and geochemical constraints , 1995 .

[22]  E. Middlemost,et al.  A classification of igneous rocks and glossary of terms , 1991 .

[23]  R. Ixer,et al.  Evidence for the mechanism of the reaction producing a bournonite–galena symplectite from meneghinite , 1991, Mineralogical Magazine.

[24]  R. W. Le Maitre,et al.  A Classification of igneous rocks and glossary of terms : recommendations of the International Union of Geological Sciences Subcommission on the Systematics of Igneous Rocks , 1989 .

[25]  E. Welin The depositional evolution of the Svecofennian supracrustal sequence in Finland and Sweden , 1987 .

[26]  T. Lundqvist Early Svecofennian stratigraphy of southern and central Norrland, Sweden, and the possible existence of an Archaean basement west of the Svecokarelides , 1987 .

[27]  B. Mishra,et al.  ‘Derived’ and observed sulphosalt-sulphide phase assemblages compared — A case study from Rajpura-Dariba, India , 1984 .

[28]  B. Skinner,et al.  Mineral textures and their bearing on formation of the kuroko orebodies , 1983 .

[29]  J. Winchester,et al.  Geochemical discrimination of different magma series and their differentiation products using immobile elements , 1977 .

[30]  B. R. Clark,et al.  Sulfide Deformation Studies; I, Experimental Deformation of Pyrrhotite and Sphalerite to 2,000 Bars and 500 degrees C , 1973 .

[31]  Richard J. Anderson Microscopic features of ore from the Sunshine Mine [Idaho] , 1940 .