Incorporation of Alternative Sensors in the SOCAT Database and Adjustments to Dataset Quality Control Flags Recommendations

Wanninkhof, R., D.C.E. Bakker, N. Bates, A. Olsen, T. Steinhoff and A.J. Sutton. 2013. Incorporation of Alternative Sensors in the SOCAT Database and Adjustments to Dataset Quality Control Flags. http://cdiac.ornl.gov/oceans/Recommendationnewsensors.pdf. Carbon Dioxide Information Analysis Center, Oak Ridge National Laboratory, US Department of Energy, Oak Ridge, Tennessee. doi: 10.3334/CDIAC/OTG.SOCAT_ADQCF With the advent of new sensors and platforms to measure surface water carbon dioxide (CO2) levels, the dataset quality control (QC) criteria are updated in the Surface Ocean CO2 Atlas (SOCAT) to accommodate surface water fugacity of CO2 (fCO2w) data from these sensors. The current dataset QC flags and their rationale are described. The new sensors and platforms are briefly presented. Some changes in the criteria for assigning dataset QC flags and a new data quality flag are introduced. The term “dataset QC flag” replaces “cruise QC flag” to reflect the alternate platforms that are included in SOCAT. All dataset QC flags will incorporate a specified accuracy of the data. For equilibrator based systems the criteria for equilibrator pressure measurements are relaxed as they are unnecessary stringent for the accuracy of fCO2 in surface seawater. The acceptable comparison with other in situ data, defined as a high quality cross-over, will meet specific criteria of maximum distance, differences in fCO2w and sea surface temperature (SST) between two datasets. The scientist submitting the dataset will enter a preliminary dataset flag. Platform type including alternative platforms, such as buoys and selfpropelled surface vehicles, will be provided in the metadata and will be available as a selectable option in the Live Access Server (LAS) for SOCAT. These updates facilitate better separation of 1 Since there is no absolute standard for pCO2 in seawater, the term accuracy throughout refers to agreement with accepted values obtained from conventional state-of-the art systems such as described in Pierrot et al. (2009).

[1]  Francisco P. Chavez,et al.  Measurement of sea surface partial pressure of C02 from a moored buoy , 1995 .

[2]  N. Lefèvre,et al.  Variability of fCO2 in the Eastern Tropical Atlantic from a moored buoy , 2008 .

[3]  L. Merlivat,et al.  The warm oceanic surface layer: Implications for CO2 fluxes and surface gas measurements , 1996 .

[4]  Taro Takahashi,et al.  Carbon dioxide in the atmosphere and in Atlantic Ocean water , 1961 .

[5]  L. Merlivat,et al.  Air‐sea CO2 flux variability in frontal regions of the Southern Ocean from CARbon Interface OCean Atmosphere drifters , 2008 .

[6]  Jacqueline Boutin,et al.  Surface Ocean CO2 Atlas (SOCAT) gridded data products , 2012 .

[7]  Nicholas R. Bates,et al.  Intercomparison of shipboard and moored CARIOCA buoy seawater fCO2 measurements in the Sargasso Sea , 2000 .

[8]  R. Weiss Determinations of Carbon Dioxide and Methane by Dual Catalyst Flame Ionization Chromatography and Nitrous Oxide by Electron Capture Chromatography , 1981 .

[9]  J. Karstensen,et al.  The seasonal pCO2 cycle at 49°N/16.5°W in the northeastern Atlantic Ocean and what it tells us about biological productivity , 2008 .

[10]  James D. Irish,et al.  Temporal and spatial dynamics of CO2 air-sea flux in the Gulf of Maine , 2018 .

[11]  P. Quay,et al.  Evidence of O 2 consumption in underway seawater lines : Implications for air-sea O 2 and CO 2 fluxes , 2009 .

[12]  Richard A. Feely,et al.  Recommendations for autonomous underway pCO2 measuring systems and data-reduction routines , 2009 .

[13]  L. Merlivat,et al.  Variability of the partial pressure of CO2 on diel to annual time scales in the Northwestern Mediterranean Sea , 2004 .

[14]  L. Merlivat,et al.  Variability of surface water fCO2 during seasonal upwelling in the equatorial Atlantic Ocean as observed by a drifting buoy , 2001 .

[15]  R. Weiss Carbon dioxide in water and seawater: the solubility of a non-ideal gas , 1974 .

[16]  Andrew G. Dickson,et al.  Guide to best practices for ocean CO2 measurements , 2007 .

[17]  A. Körtzinger,et al.  Using cavity ringdown spectroscopy for continuous monitoring of δ13C(CO2) and ƒCO2 in the surface ocean , 2012 .

[18]  Tobias Steinhoff,et al.  In situ Quality Assessment of a Novel Underwater pCO2 Sensor Based on Membrane Equilibration and NDIR Spectrometry , 2014 .

[19]  P. Quay,et al.  Evidence of O2 consumption in underway seawater lines: Implications for air‐sea O2 and CO2 fluxes , 2010 .

[20]  Jacqueline Boutin,et al.  A uniform, quality controlled Surface Ocean CO2 Atlas (SOCAT) , 2012 .