The Clar covering polynomial of hexagonal systems III

Abstract The Clar covering polynomial is a recently proposed concept of hexagonal systems by which some important topological indices such as perfect matching count, Clar number, first Herndon number, etc., can be easily obtained. In this paper we establish a relationship between the Clar covering polynomial and sextet polynomial. A lower bound of the Clar number and some properties of coefficients of the Clar covering polynomial are thus deduced. It is mentioned that the summation of coefficients of Clar covering polynomial can be used to calculate the number of perfect matchings of a certain kind of polyominoes relating to crystal physics.