Kinetic and Fluid Dynamics Modelling of a Methane/Hydrogen Jet Flames in Diluted Coflow

Abstract MILD combustion is a recent development in the combustion of hydrocarbon fuels which promises high efficiencies and low NO x emissions. In this paper we analyze the mathematical and numerical modeling of a Jet in Hot Coflow (JHC) burner, which is designed to emulate a moderate and intense low oxygen dilution (MILD) combustion regime [1] . This paper initially discusses the effects of several modeling strategies on the prediction of the JHC flame structure using the CFD code FLUENT 6.3.26. Effects of various turbulence models and their boundary conditions have been studied. Moreover, the detailed kinetic mechanism adopted in the CFD simulations is successfully validated in the conditions of interest using recent literature data [2] on the effect of nitrogen dilution on the flame speeds of several CH 4 /H 2 /air lean mixtures. One of the aims of this paper is also to describe a methodology for computing pollutant formation in steady turbulent flows to verify its applicability to the MILD combustion regime. CFD results are post-processed for calculating the NO x using a numerical tool called Kinetic Post Processor (KPP). The modeling results agree with the experimental results [1] and support the proposed approach as a useful tool for optimizing the design of new burners also in the MILD combustion regime.

[1]  Bassam B. Dally,et al.  Flow and mixing fields of turbulent bluff-body jets and flames , 1998 .

[2]  E. Ranzi,et al.  A wide range modeling study of NOx formation and nitrogen chemistry in hydrogen combustion , 2006 .

[3]  Martin Denison,et al.  Towards comprehensive computational fluid dynamics modeling of pyrolysis furnaces with next generation low-NOx burners using finite-rate chemistry , 2009 .

[4]  Tiziano Faravelli,et al.  The ignition, combustion and flame structure of carbon monoxide/hydrogen mixtures. Note 2: Fluid dynamics and kinetic aspects of syngas combustion , 2007 .

[5]  Tiziano Faravelli,et al.  A wide-range modeling study of n-heptane oxidation , 1995 .

[6]  Tiziano Faravelli,et al.  Kinetic modeling of the interactions between NO and hydrocarbons at high temperature , 2003 .

[7]  Tiziano Faravelli,et al.  Kinetic modeling of the interactions between NO and hydrocarbons in the oxidation of hydrocarbons at low temperatures , 2003 .

[8]  Tiziano Faravelli,et al.  A Wide Range Modeling Study of Methane Oxidation , 1994 .

[9]  Bassam B. Dally,et al.  Structure of turbulent non-premixed jet flames in a diluted hot coflow , 2002 .

[10]  Pedro J. Coelho,et al.  Numerical simulation of a mild combustion burner , 2001 .

[11]  Tiziano Faravelli,et al.  Experimental and Modeling Study of a Low NOx Combustor for Aero-Engine Turbofan , 2009 .

[12]  Roman Weber,et al.  On emerging furnace design methodology that provides substantial energy savings and drastic reductions in CO2, CO and NOx emissions , 1999 .

[13]  B. Magnussen On the structure of turbulence and a generalized eddy dissipation concept for chemical reaction in turbulent flow , 1981 .

[14]  Robert J. Kee,et al.  On reduced mechanisms for methaneair combustion in nonpremixed flames , 1990 .

[15]  Tiziano Faravelli,et al.  The ignition, combustion and flame structure of carbon monoxide/hydrogen mixtures. Note 1: Detailed kinetic modeling of syngas combustion also in presence of nitrogen compounds , 2007 .

[16]  Alessandro Saponaro,et al.  Zero-dimensional analysis of diluted oxidation of methane in rich conditions , 2000 .

[17]  S. H. Kim,et al.  Conditional moment closure modeling of turbulent nonpremixed combustion in diluted hot coflow , 2005 .

[18]  Masashi Katsuki,et al.  The science and technology of combustion in highly preheated air , 1998 .

[19]  F. Williams,et al.  Concentrations of nitric oxide in laminar counterflow methane/air diffusion flames , 2005 .

[20]  Tiziano Faravelli,et al.  Wide-Range Kinetic Modeling Study of the Pyrolysis, Partial Oxidation, and Combustion of Heavy n-Alkanes , 2005 .

[21]  J. Wunning,et al.  Flameless oxidation to reduce thermal no-formation , 1997 .

[22]  R. Barlow,et al.  Scalar profiles and NO formation in laminar opposed-flow partially premixed methane/air flames , 2001 .

[23]  Ba Bogdan Albrecht,et al.  A premixed flamelet-PDF model for biomass combustion in a grate furnace , 2008 .

[24]  M. Mancini,et al.  Predicting NOx emissions of a burner operated in flameless oxidation mode , 2002 .

[25]  Tiziano Faravelli,et al.  Experimental and modelling study of low-NOx industrial burners , 2008 .

[26]  Bassam B. Dally,et al.  Modeling turbulent reacting jets issuing into a hot and diluted coflow , 2005 .

[27]  Emanuela Colombo,et al.  Determination of NOx emissions from strong swirling confined flames with an integrated CFD-based procedure , 2005 .

[28]  Madjid Birouk,et al.  Stability of a Turbulent Jet Methane Flame Issuing from an Asymmetrical Nozzles with Sudden Expansion , 2008 .