Solar Concentration for Wastewaters Remediation: A Review of Materials and Technologies

As the effectiveness of conventional wastewater treatment processes is increasingly challenged by the growth of industrial activities, a demand for low-cost and low-impact treatments is emerging. A possible solution is represented by systems coupling solar concentration technology with advanced oxidation processes (AOP). In this paper, a review of solar concentration technologies for wastewater remediation is presented, with a focus on photocatalyst materials used in this specific research context. Recent results, though mostly on model systems, open promising perspectives for the use of concentrated sunlight as the energy source powering AOPs. We identify (i) the development of photocatalyst materials capable of efficiently working with sunlight, and (ii) the transition to real wastewater investigation as the most critical issues to be addressed by research in the field.

[1]  I. Oller,et al.  Inactivation of E. coli and E. faecalis by solar photo-Fenton with EDDS complex at neutral pH in municipal wastewater effluents. , 2019, Journal of hazardous materials.

[2]  N. Negishi,et al.  Effect of dissolved silica on photocatalytic water purification with a TiO2 ceramic catalyst. , 2019, Water research.

[3]  Yingnan Yang,et al.  Effect of HCO3− concentration in groundwater on TiO2 photocatalytic water purification , 2019, Applied Catalysis B: Environmental.

[4]  A. Azapagic,et al.  Environmental assessment of solar photo-Fenton processes in combination with nanofiltration for the removal of micro-contaminants from real wastewaters. , 2019, The Science of the total environment.

[5]  J. A. Sánchez Pérez,et al.  Comparison of different detoxification pilot plants for the treatment of industrial wastewater by solar photo-Fenton: Are raceway pond reactors a feasible option? , 2019, The Science of the total environment.

[6]  Adisa Azapagic,et al.  Life cycle costs of advanced treatment techniques for wastewater reuse and resource recovery from sewage sludge , 2018, Journal of Cleaner Production.

[7]  M. A. Mutalib,et al.  A review of integrated photocatalyst adsorbents for wastewater treatment , 2018, Journal of Environmental Chemical Engineering.

[8]  J. Fenoll,et al.  Solar reclamation of wastewater effluent polluted with bisphenols, phthalates and parabens by photocatalytic treatment with TiO2/Na2S2O8 at pilot plant scale. , 2018, Chemosphere.

[9]  A. Miotello,et al.  Treatment of surfactant-rich industrial wastewaters with concentrated sunlight: toward solar wastewater remediation , 2018, International Journal of Environmental Science and Technology.

[10]  A. Verma,et al.  Detoxification of real pharmaceutical wastewater by integrating photocatalysis and photo-Fenton in fixed-mode , 2018, Chemical Engineering Journal.

[11]  M. Khraisheh,et al.  Potential use of solar photocatalytic oxidation in removing emerging pharmaceuticals from wastewater: A pilot plant study , 2018, Solar Energy.

[12]  A. Ochieng,et al.  UV and solar photocatalytic disinfection of municipal wastewater: inactivation, reactivation and regrowth of bacterial pathogens , 2018, International Journal of Environmental Science and Technology.

[13]  E. Imam,et al.  TiO2 water-bell photoreactor for wastewater treatment , 2018, Solar Energy.

[14]  Jong-Oh Kim,et al.  Photodegradation of perfluorooctanoic acid by graphene oxide-deposited TiO2 nanotube arrays in aqueous phase. , 2018, Journal of environmental management.

[15]  A. Trapananti,et al.  Two-step growth mechanism of supported Co 3 O 4 -based sea-urchin like hierarchical nanostructures , 2018 .

[16]  M. Manzano,et al.  Combining sun-based technologies (microalgae and solar disinfection) for urban wastewater regeneration. , 2018, The Science of the total environment.

[17]  D. Sannino,et al.  Photocatalytic activity of a visible light active structured photocatalyst developed for municipal wastewater treatment , 2018 .

[18]  Ying Zhang,et al.  Application of solar energy in water treatment processes: A review , 2018 .

[19]  Spyros Foteinis,et al.  Environmental sustainability of the solar photo-Fenton process for wastewater treatment and pharmaceuticals mineralization at semi-industrial scale. , 2018, The Science of the total environment.

[20]  Amenallah Guizani,et al.  Energetic end exergetic performance of a parabolic trough collector receiver: An experimental study , 2018 .

[21]  P. Fernández-Ibáñez,et al.  Solar photocatalytic disinfection of agricultural pathogenic fungi (Curvularia sp.) in real urban wastewater. , 2017, The Science of the total environment.

[22]  R. Fernandes,et al.  3D hierarchical nanostructures of iron oxides coatings prepared by pulsed laser deposition for photocatalytic water purification , 2017 .

[23]  N. Gulhane,et al.  Optical evaluation of compound parabolic collector with low acceptance angle , 2017 .

[24]  Jianhua Fan,et al.  Annual measured and simulated thermal performance analysis of a hybrid solar district heating plant with flat plate collectors and parabolic trough collectors in series , 2017 .

[25]  J. A. S. Pérez,et al.  Effective solar processes in fresh-cut wastewater disinfection: Inactivation of pathogenic E. coli O157:H7 and Salmonella enteritidis , 2017, Catalysis Today.

[26]  Charles E. Andraka,et al.  Dish systems for CSP , 2017 .

[27]  N. R. Khalid,et al.  Nanostructured-based WO3 photocatalysts: recent development, activity enhancement, perspectives and applications for wastewater treatment , 2017, International Journal of Environmental Science and Technology.

[28]  Khairurrijal,et al.  Prototype of a flat-panel photoreactor using TiO2 nanoparticles coated on transparent granules for the degradation of Methylene Blue under solar illumination , 2017 .

[29]  J. Pérez,et al.  Strategies for reducing cost by using solar photo-Fenton treatment combined with nanofiltration to remove microcontaminants in real municipal effluents: Toxicity and economic assessment , 2017 .

[30]  G. Zalidis,et al.  Evaluation of an alternative method for wastewater treatment containing pesticides using solar photocatalytic oxidation and constructed wetlands. , 2017, Journal of environmental management.

[31]  M. Guida,et al.  Solar photocatalytic processes for treatment of soil washing wastewater , 2017 .

[32]  M. E. Borges,et al.  Solar photocatalysis at semi-pilot scale: wastewater decontamination in a packed-bed photocatalytic reactor system with a visible-solar-light-driven photocatalyst , 2017, Clean Technologies and Environmental Policy.

[33]  A. Miotello,et al.  Simulation of phase explosion in the nanosecond laser ablation of aluminum. , 2017, Journal of colloid and interface science.

[34]  R. Fernandes,et al.  Dependence of photocatalysis on charge carrier separation in Ag-doped and decorated TiO2 nanocomposites , 2016 .

[35]  Stefano Pauletta,et al.  A Solar Fresnel Collector Based on an Evacuated Flat Receiver , 2016 .

[36]  Paola Boito,et al.  Optimization of the geometry of Fresnel linear collectors , 2016 .

[37]  C. Bignozzi,et al.  Porous versus Compact Nanosized Fe(III)-Based Water Oxidation Catalyst for Photoanodes Functionalization. , 2016, ACS applied materials & interfaces.

[38]  R. Chaudhary,et al.  Feasibility study for the treatment of municipal wastewater by using a hybrid bio-solar process. , 2016, Journal of environmental management.

[39]  J. Crittenden,et al.  Design of visible light responsive photocatalysts for selective reduction of chlorinated organic compounds in water , 2016 .

[40]  R. Fernandes,et al.  Enhanced H2 production from hydrolysis of sodium borohydride using Co3O4 nanoparticles assembled coatings prepared by pulsed laser deposition , 2016 .

[41]  V. Goetz,et al.  Use of solar advanced oxidation processes for wastewater treatment: Follow-up on degradation products, acute toxicity, genotoxicity and estrogenicity. , 2016, Chemosphere.

[42]  R. Fernandes,et al.  Efficient Co-B-codoped TiO2 photocatalyst for degradation of organic water pollutant under visible light , 2016 .

[43]  Ossama Mokhiamar,et al.  Mechanical design of a low cost parabolic solar dish concentrator , 2016 .

[44]  M. I. Maldonado,et al.  Decontamination and disinfection of water by solar photocatalysis: The pilot plants of the Plataforma Solar de Almeria , 2016 .

[45]  J. Pérez,et al.  Wastewater disinfection by neutral pH photo-Fenton: The role of solar radiation intensity , 2016 .

[46]  P. Scardi,et al.  Effect of annealing and nanostructuring on pulsed laser deposited WS2 for HER catalysis , 2016 .

[47]  Mohamed Gar Alalm,et al.  Comparison of solar TiO2 photocatalysis and solar photo-Fenton for treatment of pesticides industry wastewater: Operational conditions, kinetics, and costs , 2015 .

[48]  L. Rizzo,et al.  Urban wastewater disinfection for agricultural reuse: effect of solar driven AOPs in the inactivation of a multidrug resistant E. coli strain , 2015 .

[49]  N. Misra The contribution of non-thermal and advanced oxidation technologies towards dissipation of pesticide residues , 2015 .

[50]  S. Jahangiri Mamouri,et al.  A new desalination system using a combination of heat pipe, evacuated tube and parabolic trough collector. , 2015 .

[51]  Sixto Malato,et al.  Solar photocatalysis: Materials, reactors, some commercial, and pre-industrialized applications. A comprehensive approach , 2015 .

[52]  A. Durán,et al.  Solar-photo-Fenton treatment of wastewater from the beverage industry: intensification with ferrioxalate. , 2015 .

[53]  D. Kothari,et al.  Copper and Nitrogen co-doped TiO2 photocatalyst with enhanced optical absorption and catalytic activity , 2015 .

[54]  V. Bello,et al.  Highly photo-catalytically active hierarchical 3D porous/urchin nanostructured Co3O4 coating synthesized by Pulsed Laser Deposition , 2015 .

[55]  C. Pulgarin,et al.  Iron oxides semiconductors are efficients for solar water disinfection: A comparison with photo-Fenton processes at neutral pH , 2015 .

[56]  R. Bergamasco,et al.  Insights into solar photo-Fenton process using iron(III)–organic ligand complexes applied to real textile wastewater treatment , 2015 .

[57]  M. Zimbone,et al.  Photocatalytical and antibacterial activity of TiO2 nanoparticles obtained by laser ablation in water , 2015 .

[58]  Sittha Sukkasi,et al.  Improving the efficacy of solar water disinfection by incremental design innovation , 2015, Clean Technologies and Environmental Policy.

[59]  Aránzazu Fernández-García,et al.  A parabolic-trough collector for cleaner industrial process heat , 2015 .

[60]  Santanu Bandyopadhyay,et al.  Optimization of concentrating solar thermal power plant based on parabolic trough collector , 2015 .

[61]  Adrián M.T. Silva,et al.  An overview on the advanced oxidation processes applied for the treatment of water pollutants defined in the recently launched Directive 2013/39/EU. , 2015, Environment international.

[62]  Kun Wang,et al.  TiO2 based photocatalytic membranes: A review , 2014 .

[63]  I. Oller,et al.  Assessment of solar photo-Fenton, photocatalysis, and H2O2 for removal of phytopathogen fungi spores in synthetic and real effluents of urban wastewater , 2014 .

[64]  J. A. Sánchez Pérez,et al.  Inactivation of natural enteric bacteria in real municipal wastewater by solar photo-Fenton at neutral pH. , 2014, Water research.

[65]  R. Abbas,et al.  A comparative analysis of configurations of linear Fresnel collectors for concentrating solar power , 2014 .

[66]  A. Xu,et al.  Efficient adsorption/photodegradation of organic pollutants from aqueous systems using Cu2O nanocrystals as a novel integrated photocatalytic adsorbent , 2014 .

[67]  N. Soin,et al.  Role of graphene/metal oxide composites as photocatalysts, adsorbents and disinfectants in water treatment: a review , 2014 .

[68]  S. Tesfamariam,et al.  Modeling exposure period for solar disinfection (SODIS) under varying turbidity and cloud cover conditions , 2014, Clean Technologies and Environmental Policy.

[69]  D. Kothari,et al.  Efficient photocatalytic degradation of organic water pollutants using V–N-codoped TiO2 thin films , 2014 .

[70]  J. Rodríguez-Chueca,et al.  Disinfection of real and simulated urban wastewater effluents using a mild solar photo-Fenton , 2014 .

[71]  C. Pulgarin,et al.  Relevant impact of irradiance (vs. dose) and evolution of pH and mineral nitrogen compounds during natural water disinfection by photo-Fenton in a solar CPC reactor , 2014 .

[72]  Thomas Egli,et al.  Solar water disinfection by a Parabolic Trough Concentrator (PTC): flow-cytometric analysis of bacterial inactivation , 2014 .

[73]  R. Brusa,et al.  Construction method and optical characterization of parabolic solar modules for concentration systems , 2013 .

[74]  Muhammad Tanveer,et al.  Solar assisted photo degradation of wastewater by compound parabolic collectors: Review of design and operational parameters , 2013 .

[75]  A. Chianese,et al.  Photocatalytic treatment of olive mill wastewater by n-doped titanium dioxide nanoparticles under visible light , 2013 .

[76]  P. Pichat Photocatalysis and water purification : from fundamentals to recent applications , 2013 .

[77]  Frank E. Osterloh,et al.  Inorganic nanostructures for photoelectrochemical and photocatalytic water splitting. , 2013, Chemical Society reviews.

[78]  L. Gurevich,et al.  Pore size dependence of diffuse light scattering from anodized aluminum solar cell backside reflectors. , 2013, Optics express.

[79]  P. Flores,et al.  Semiconductor oxides-sensitized photodegradation of fenamiphos in leaching water under natural sunlight , 2012 .

[80]  I. Oller,et al.  Mild solar photo-Fenton: An effective tool for the removal of Fusarium from simulated municipal effluents , 2012 .

[81]  María José Montes,et al.  Performance analysis of an Integrated Solar Combined Cycle using Direct Steam Generation in parabolic trough collectors , 2011 .

[82]  Fenglian Fu,et al.  Removal of heavy metal ions from wastewaters: a review. , 2011, Journal of environmental management.

[83]  Andreas Poullikkas,et al.  Parametric analysis for the installation of solar dish technologies in Mediterranean regions , 2010 .

[84]  C. Saint,et al.  Recent developments in photocatalytic water treatment technology: a review. , 2010, Water research.

[85]  M. I. Maldonado,et al.  Degradation study of 15 emerging contaminants at low concentration by immobilized TiO2 in a pilot plant , 2010 .

[86]  M. I. Maldonado,et al.  Efficiency of different solar advanced oxidation processes on the oxidation of bisphenol A in water , 2010 .

[87]  Andrew T. Harris,et al.  Review of Major Design and Scale-up Considerations for Solar Photocatalytic Reactors , 2009 .

[88]  A. Durán,et al.  Effect of continuous addition of H2O2 and air injection on ferrioxalate-assisted solar photo-Fenton degradation of Orange II , 2009 .

[89]  M. I. Maldonado,et al.  Abatement of ibuprofen by solar photocatalysis process: Enhancement and scale up , 2009 .

[90]  Mohammed S. Al-Soud,et al.  A 50 MW concentrating solar power plant for Jordan , 2009 .

[91]  Jingjing Xu,et al.  Photocatalytic activity on TiO2-coated side-glowing optical fiber reactor under solar light , 2008 .

[92]  M. I. Maldonado,et al.  Pilot plant scale reactive dyes degradation by solar photo-Fenton and biological processes , 2008 .

[93]  Abdul Halim Abdullah,et al.  Heterogeneous photocatalytic degradation of organic contaminants over titanium dioxide : A review of fundamentals, progress and problems , 2008 .

[94]  F. García-Peña,et al.  Solar TiO2-assisted photocatalytic degradation of IGCC power station effluents using a Fresnel lens. , 2008, Chemosphere.

[95]  C. Sichel,et al.  Effect of UV solar intensity and dose on the photocatalytic disinfection of bacteria and fungi , 2007 .

[96]  T. Sornakumar,et al.  Design, manufacture and testing of fiberglass reinforced parabola trough for parabolic trough solar collectors , 2007 .

[97]  N. Jaffrezic‐Renault,et al.  Malic acid photocatalytic degradation using a TiO2-coated optical fiber reactor , 2007 .

[98]  Julián Blanco,et al.  PHOTOCATALYTIC DECONTAMINATION AND DISINFECTION OF WATER WITH SOLAR COLLECTORS , 2007 .

[99]  A. Durán,et al.  Solar photocatalytic degradation of reactive blue 4 using a Fresnel lens. , 2007, Water research.

[100]  G. Orellana,et al.  Solar water disinfection by photocatalytic singlet oxygen production in heterogeneous medium , 2006 .

[101]  A. Durán,et al.  Fresnel lens to concentrate solar energy for the photocatalytic decoloration and mineralization of orange II in aqueous solution. , 2006, Chemosphere.

[102]  John T Yates,et al.  Surface science studies of the photoactivation of TiO2--new photochemical processes. , 2006, Chemical reviews.

[103]  E. Oliveros,et al.  Advanced Oxidation Processes for Organic Contaminant Destruction Based on the Fenton Reaction and Related Chemistry , 2006 .

[104]  G. Marcì,et al.  Degradation of lincomycin in aqueous medium : Coupling of solar photocatalysis and membrane separation , 2005 .

[105]  G. L. Puma,et al.  Dimensionless Analysis of Photocatalytic Reactors Using Suspended Solid Photocatalysts , 2005 .

[106]  J. Herrmann,et al.  From the fundamentals of photocatalysis to its applications in environment protection and in solar purification of water in arid countries , 2005 .

[107]  J. Blanco,et al.  Water disinfection by solar photocatalysis using compound parabolic collectors , 2005 .

[108]  Jincai Zhao,et al.  Solar photocatalysis, photodegradation of a commercial detergent in aqueous TiO2 dispersions under sunlight irradiation , 2004 .

[109]  Laurence Gill,et al.  Solar disinfection of contaminated water: a comparison of three small-scale reactors , 2004 .

[110]  Koji Takeuchi,et al.  Degradation of toluene and acetaldehyde with Pt-loaded TiO2 catalyst and parabolic trough concentrator , 2004 .

[111]  Detlef W. Bahnemann,et al.  Photocatalytic water treatment: solar energy applications , 2004 .

[112]  P. Pichat,et al.  Field solar photocatalytic purification of pesticides-containing rinse waters from tractor cisterns used for grapevine treatment , 2004 .

[113]  J. Farinha Mendes,et al.  Engineering of solar photocatalytic collectors , 2004 .

[114]  Camilo A. Arancibia-Bulnes,et al.  Solar photoreactors comparison based on oxalic acid photocatalytic degradation , 2004 .

[115]  S. Malato-Rodríguez Engineering of solar photocatalytic collectors , 2004 .

[116]  I. Poulios,et al.  Solar photocatalytic treatment of synthetic municipal wastewater. , 2004, Water research.

[117]  O. Chiavone-Filho,et al.  Treatment of saline wastewater contaminated with hydrocarbons by the photo-Fenton process. , 2004, Environmental science & technology.

[118]  M. Subrahmanyam,et al.  Photocatalytic degradation of H-acid over a novel TiO2 thin film fixed bed reactor and in aqueous suspensions , 2003 .

[119]  J. F. Porter,et al.  Solar photocatalytic thin film cascade reactor for treatment of benzoic acid containing wastewater. , 2003, Water research.

[120]  C. Baiocchi,et al.  Azo-dyes photocatalytic degradation in aqueous suspension of TiO2 under solar irradiation. , 2002, Chemosphere.

[121]  G. Rajarajeswari,et al.  Sunlight/ZnO-mediated photocatalytic degradation of reactive red 22 using thin film flat bed flow photoreactor , 2002 .

[122]  D. Robert,et al.  Solar photocatalysis: a clean process for water detoxification. , 2002, The Science of the total environment.

[123]  T. Waite,et al.  Evaluation of two solar pilot scale fixed-bed photocatalytic reactors , 2000 .

[124]  K. Hashimoto,et al.  TiO2-coated optical fiber bundles used as a photocatalytic filter for decomposition of gaseous organic compounds , 2000 .

[125]  J. Broekaert,et al.  Degradation of short-chain alkyl- and alkanolamines by TiO2- and Pt/TiO2-assisted photocatalysis. , 2000, Chemosphere.

[126]  Alberto E. Cassano,et al.  Photocatalysis in water environments using artificial and solar light , 2000 .

[127]  D. Bahnemann,et al.  Large scale studies in solar catalytic wastewater treatment , 1999 .

[128]  Sixto Malato,et al.  Photoelectrochemical reactors for the solar decontamination of water , 1999 .

[129]  A. K. Ray,et al.  A new photocatalytic reactor for destruction of toxic water pollutants by advanced oxidation process , 1998 .

[130]  Soteris A. Kalogirou,et al.  Use of parabolic trough solar energy collectors for sea-water desalination , 1998 .

[131]  X. Doménech,et al.  Aniline mineralization by AOP's: anodic oxidation, photocatalysis, electro-Fenton and photoelectro-Fenton processes , 1998 .

[132]  Soo-Myung Kim,et al.  Degradation of Organic Pollutants by the Photo‐Fenton‐Process , 1998 .

[133]  M. Hoffmann,et al.  Solar-Powered Photocatalytic Fiber-Optic Cable Reactor for Waste Stream Remediation , 1997 .

[134]  D. Bahnemann,et al.  A Novel Nonconcentrating Reactor for Solar Water Detoxification , 1997 .

[135]  J. Blanco,et al.  Large solar plant photocatalytic water decontamination: Effect of operational parameters , 1996 .

[136]  C. Pulgarin,et al.  Effect of Fenton and photo-Fenton reactions on the degradation and biodegradability of 2 and 4-nitrophenols in water treatment , 1994 .

[137]  N. Muradov Solar detoxification of nitroglycerine-contaminated water using immobilized titania , 1994 .

[138]  R. Bauer,et al.  The photo-Fenton reaction — an effective photochemical wastewater treatment process , 1993 .

[139]  Julián Blanco,et al.  Large solar plant photocatalytic water decontamination : degradation of pentachlorophenol , 1993 .

[140]  André M. Braun,et al.  Photochemical processes for water treatment , 1993 .

[141]  Craig Turchi,et al.  Pilot-scale study of the solar detoxification of VOC-contaminated groundwater , 1992 .

[142]  Gary Jorgensen,et al.  Outdoor testing of advanced optical materials for solar thermal electric applications , 1992 .

[143]  D. J. Alpert,et al.  Sandia National Laboratories' work in solar detoxification of hazardous wastes , 1991 .

[144]  M. Bohn,et al.  Development of solar detoxification technology in the USA - an introduction , 1991 .

[145]  Rangaprasad Govindarajan,et al.  Ultraviolet reflector materials for solar detoxification of hazardous waste , 1991, Optics & Photonics.

[146]  William H. Glaze,et al.  The Chemistry of Water Treatment Processes Involving Ozone, Hydrogen Peroxide and Ultraviolet Radiation , 1987 .

[147]  J. Calkins,et al.  THE ROLE OF SOLAR ULTRAVIOLET RADIATION IN ‘NATURAL’ WATER PURIFICATION , 1976, Photochemistry and photobiology.

[148]  Zewei Yang,et al.  Photocatalytic activity of Pt–TiO2 films supported on hydroxylated fly ash cenospheres under visible light , 2015 .

[149]  Hasimah Abdul Rahman,et al.  Historical development of concentrating solar power technologies to generate clean electricity efficiently – A review , 2015 .

[150]  Y. Oh Photocatalytic degradation of organic contaminants in water , 2004 .

[151]  A. Vogelpohl,et al.  Detoxification and recycling of wastewater by solar-catalytic treatment , 1997 .

[152]  J. Giménez,et al.  Low-concentrating CPC collectors for photocatalytic water detoxification: Comparison with a medium concentrating solar collector , 1997 .