Liquid Phase Carbonylation with Solid Catalyst. Carboxy Methylation of Dihalo Methane with Group VIII Metals Supported on Active Carbon
暂无分享,去创建一个
It was found that cobalt supported on active carbon showed an excellent catalytic activity for the carbonylation of dibromo methane in the liquid phase. For example, when the reaction was conducted under the conditions of 140 °C, P(CO) = 31 atm, the yields of dimethyl malonate and bromomethyl acetate were 34.4% and 22.2%, respectively. Pd and Rh also showed catalytic activities.
[1] K. Fujimoto,et al. Vapor phase carbonylation of methyl chloride with transition metal-active carbon catalysts , 1986 .
[2] K. Omata,et al. Vapor-phase carbonylation of organic compounds over supported transition-metal catalysts. IV: Synthesis of acetic anhydride from methyl acetate with nickel−active carbon catalyst , 1985 .
[3] K. Yasuda,et al. Vapor Phase Carbonylation of Alkyl Chloroacetates , 1985 .