论文信息 - B2N4Se‐Bicyclo[2.2.1]heptanes and B2N4Se2‐Bicyclo[2.2.2]octanes

B2N4Se‐Bicyclo[2.2.1]heptanes and B2N4Se2‐Bicyclo[2.2.2]octanes

B2N4Se2-Bicyclo[2.2.2]octanes Aus 3,5-Dialkyl-1,2,4,3,5-triselenadiborolanen [Alkyl = C2H5 (1a) und Alkyl = n-C3H7 (1b)] werden mit Pyrazol (Pz), 3-Methylpyrazol (mPz) und 3-Phenylpyrazol (pPz) die Diselenabicyclo[2.2.2]octane 2–4 hergestellt. Demgegenuber reagieren 3,5-Dimethyl- und 3,5-Diphenylpyrazol (m2Pz, P2Pz) mit 1a zu den Monoselenabicyclo[2.2.1]heptanen 5 und 6. Von 2a und 5 liegen Kristallstrukturanalysen vor.

R. Boese | R. Köster | M. Yalpani

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