Inclusion of nano metakaolin as additive in ultra high performance concrete (UHPC)

Abstract The utilisation of nano particles to enhance concrete can be seen in its densification and refining. In this study, nano metakaolined UHPC mixes were used as an additive range of 1%, 3%, 5%, 7%, 9% and 10% from cement weight. All UHPC specimens were compared to the plain UHPC and metakaolined UHPC mixes. The effect of nano metakaolined UHPC was evaluated in the forms of workability in fresh state, strength property and the morphology of the microstructure in the UHPC. The determination of the fresh property was conducted by a workability test. Meanwhile, the strength property was conducted by compressive strength in 3, 7 and 28 days. Next, the morphology in the UHPC microstructure was analysed by Scanning Electron Microscope (SEM). The uniqueness and difference morphology formation was analysed and compared to the plain UHPC. It can then be concluded that the nano metakaolined UHPC mix contributed to a low workability effect due to its clay properties and ultrafine size as compared to the OPC and metakaolin. The inclusion of nano metakaolin in UHPC shows similar compressive strength at early age but gradually increased at later ages as compared to the plain UHPC and metakaolined UHPC.

[1]  A. Chaipanich,et al.  Compressive strength and drying shrinkage of fly ash-bottom ash-silica fume multi-blended cement mortars , 2012 .

[2]  Kay Wille,et al.  Material efficiency in the design of ultra-high performance concrete , 2015 .

[3]  A. M. Fadzil,et al.  Applications of using nano material in concrete: A review , 2017 .

[4]  Halit Yazici,et al.  Mechanical properties of reactive powder concrete containing mineral admixtures under different curing regimes , 2009 .

[5]  V. M. Malhotra,et al.  Pozzolanic and cementitious materials , 1996 .

[6]  P. K. Mehta,et al.  Concrete: Microstructure, Properties, and Materials , 2005 .

[7]  V. Matte,et al.  Durability of reactive powder composites: influence of silica fume on the leaching properties of very low water/binder pastes , 1999 .

[8]  A. Neville Properties of Concrete , 1968 .

[9]  F. Curcio,et al.  Metakaolin as a pozzolanic microfiller for high-performance mortars , 1998 .

[10]  Halit Yazıcı,et al.  The effect of curing conditions on compressive strength of ultra high strength concrete with high volume mineral admixtures , 2007 .

[11]  M. E. Stavroulaki,et al.  Physico-chemical and mechanical characterization of hydraulic mortars containing nano-titania for restoration applications , 2013 .

[12]  V. Bonavetti,et al.  Role of the filler on Portland cement hydration at early ages , 2012 .

[13]  Gilles Escadeillas,et al.  Metakaolin in the formulation of UHPC , 2009 .

[14]  Zhihui Sun,et al.  Effects of nano-silica and nano-limestone on flowability and mechanical properties of ultra-high-performance concrete matrix , 2015 .

[15]  Pierre-Claude Aitcin,et al.  Cements of yesterday and today Concrete of tomorrow , 2000 .

[16]  K. Uzawa,et al.  Mechanical, thermal, and interfacial shear properties of polyamide/nanoclay nanocomposites , 2018 .

[17]  Shan Somayaji Civil Engineering Materials , 1995 .

[18]  Zeinab H.Naji زینب هاتف ناجي,et al.  THE EFFECT OF NANO METAKAOLIN MATERIAL ON SOME PROPERTIES OF CONCRETE , 2013 .

[19]  Konstantin Sobolev,et al.  How Nanotechnology Can Change the Concrete World , 2014 .

[20]  Roland J.-M. Pellenq,et al.  Engineering the bonding scheme in C–S–H: The iono-covalent framework , 2008 .

[21]  Fang Liu,et al.  Preparation of Ultra-High Performance Concrete with common technology and materials , 2012 .

[22]  Guler Fakhraddin Muhyaddin,et al.  Properties of low binder ultra-high performance cementitious composites: Comparison of nanosilica and microsilica , 2016 .

[23]  M. Ramli,et al.  Properties of hybrid cementitious composite with metakaolin, nanosilica and epoxy , 2017 .

[24]  J. Brooks,et al.  Effect of admixtures on the setting times of high-strength concrete , 2000 .

[25]  J. Dugat,et al.  Mechanical properties of reactive powder concretes , 1996 .

[26]  J. E. Gillott,et al.  Microstructural investigation of innovative UHPC , 1999 .

[27]  S. Tsivilis,et al.  Pozzolanic activity of thermally and mechanically treated kaolins of hydrothermal origin , 2015 .

[28]  I. Richardson The nature of C-S-H in hardened cements , 1999 .

[29]  T Sedran,et al.  Optimization of ultra-high-performance concrete by the use of a packing model , 1994 .

[30]  P. Richard,et al.  Composition of reactive powder concretes , 1995 .

[31]  E. Fehling,et al.  A review and analysis of circular UHPC filled steel tube columns under axial loading , 2017 .

[32]  J. Přikryl,et al.  Metakaolinite/TiO2 composite: Photoactive admixture for building materials based on Portland cement binder , 2012 .

[33]  J. Ou,et al.  Microstructure of cement mortar with nano-particles , 2004 .

[34]  G. Barluenga,et al.  Hardened properties and microstructure of SCC with mineral additions , 2015 .

[35]  Norbert Randl,et al.  Development of UHPC mixtures from an ecological point of view , 2014 .

[36]  M. F. Kotkata,et al.  Flexural strength and physical properties of fiber reinforced nano metakaolin cementitious surface compound , 2013 .

[37]  F. El-hosiny,et al.  Pozzolanic and hydraulic activity of nano-metakaolin , 2014 .

[38]  Eva Vejmelková,et al.  High performance concrete with Czech metakaolin: Experimental analysis of strength, toughness and durability characteristics , 2010 .

[39]  B. Meng,et al.  Einflussgrößen auf die Wirksamkeit einer Wärmebehandlung von Ultrahochfestem Beton (UHFB) , 2017 .

[40]  D. M. Roy,et al.  Effect of silica fume, metakaolin, and low-calcium fly ash on chemical resistance of concrete , 2001 .

[41]  Min Ook Kim,et al.  Uncovering the role of micro silica in hydration of ultra-high performance concrete (UHPC) , 2018 .

[42]  Sukhoon Pyo,et al.  Characteristics of ultra high performance concrete subjected to dynamic loading , 2014 .

[43]  Konstantin Sobolev,et al.  The development of a new method for the proportioning of high-performance concrete mixtures , 2004 .

[44]  Hjh Jos Brouwers,et al.  Effect of nano-silica on the hydration and microstructure development of Ultra-High Performance Concrete (UHPC) with a low binder amount , 2014 .

[45]  C. Chiu,et al.  A preliminary study of reactive powder concrete as a new repair material , 2007 .

[46]  P. Rivard,et al.  Influence of supplementary cementitious materials on engineering properties of high strength concrete , 2011 .