Industrial SBR Process: Computer Simulation Study for Online Estimation of Steady‐State Variables Using Neural Networks

This work investigates the industrial production of styrene-butadiene rubber in a continuous reactor train, and proposes a soft sensor for online monitoring of several processes and polymer quality variables in each reactor. The soft sensor includes two independent artificial neural networks (ANN). The first ANN estimates monomer conversion, solid content, polymer production, average particle diameter, and average copolymer composition; the second ANN estimates average molecular weights and average branching degrees. The required ANN inputs are: (i) the reagent feed rates into the first reactor and (ii) the reaction heat rate in each reactor. The proposed ANN-based soft sensor proved robust to several measurement errors, and is suitable for online estimation and closed-loop control strategies.

[1]  Jorge R. Vega,et al.  Emulsion Copolymerization of Acrylonitrile and Butadiene in an Industrial Batch Reactor. Estimation of Conversion and Polymer Quality from On-line Energy Measurements , 1999 .

[2]  Fabiano A.N. Fernandes,et al.  Inverse modeling applications in emulsion polymerization of vinyl acetate , 2004 .

[3]  Mohammad Bagher Menhaj,et al.  Training feedforward networks with the Marquardt algorithm , 1994, IEEE Trans. Neural Networks.

[4]  Fabiano A.N. Fernandes,et al.  APPLICATION OF NEURAL NETWORKS FOR THE DEFINITION OF THE OPERATING CONDITIONS OF FLUIDIZED BED POLYMERIZATION REACTORS , 2002 .

[5]  C. Kiparissides,et al.  Inferential Estimation of Polymer Quality Using Stacked Neural Networks , 1997 .

[6]  Babu Joseph,et al.  Predictive control of quality in batch polymerization using hybrid ANN models , 1996 .

[7]  Yuan Tian,et al.  Optimal control of a batch emulsion copolymerisation reactor based on recurrent neural network models , 2002 .

[8]  R. K. Mutha and,et al.  A New Multirate-Measurement-Based Estimator: Emulsion Copolymerization Batch Reactor Case Study , 1997 .

[9]  T. McKenna,et al.  Artificial Neural Networks Associated to Calorimetric Measurements Used as a Method to Predict Polymer Composition of High Solid Content Emulsion Copolymerizations , 2005 .

[10]  A. J. Morris,et al.  Estimation of impurity and fouling in batch polymerisation reactors through the application of neural networks , 1999 .

[11]  Alicia D'Anjou,et al.  Model Reduction in Emulsion Polymerization Using Hybrid First-Principles/Artificial Neural Network Models , 2003 .

[12]  Allan Pinkus,et al.  Approximation theory of the MLP model in neural networks , 1999, Acta Numerica.

[13]  Jorge R. Vega,et al.  EMULSION COPOLYMERIZATION OF ACRYLONITRILE AND BUTADIENE. SEMIBATCH STRATEGIES FOR CONTROLLING MOLECULAR STRUCTURE ON THE BASIS OF CALORIMETRIC MEASUREMENTS , 2002 .

[14]  Jorge R. Vega,et al.  Dynamic model of a continuous emulsion: copolymerization of styrene and butadiene , 1995 .

[15]  John R. Richards,et al.  Measurement and control of polymerization reactors , 2006, Comput. Chem. Eng..

[16]  W. Harmon Ray,et al.  Mathematical Modeling of Emulsion Copolymerization Reactors. I. Model Formulation and Application to Reactors Operating with Micellar Nucleation , 1998 .

[17]  L. Ljung,et al.  Overtraining, regularization and searching for a minimum, with application to neural networks , 1995 .

[18]  N. Bekkedahl Rubber Chem. Technol , 1969 .

[19]  Alexander Penlidis,et al.  Mathematical modeling and computer simulator/database for emulsion polymerizations , 2002 .

[20]  Jie Zhang,et al.  A batch-to-batch iterative optimal control strategy based on recurrent neural network models , 2005 .

[21]  D. J. Dougherty,et al.  Continuous Emulsion Polymerization , 1977 .

[22]  G. Padmavathi,et al.  Neural modelling of Mooney viscosity of polybutadiene rubber , 2005, Comput. Chem. Eng..

[23]  Jorge R. Vega,et al.  Continuous Emulsion Styrene-Butadiene Rubber (SBR) Process: Computer Simulation Study for Increasing Production and for Reducing Transients between Steady States , 2006 .

[24]  Edmond S. Perry,et al.  Encyclopedia of Chemical Technology. , 1961 .

[25]  Magali R. G. Meireles,et al.  A comprehensive review for industrial applicability of artificial neural networks , 2003, IEEE Trans. Ind. Electron..

[27]  Fabiano A.N. Fernandes,et al.  Neural network applications in polymerization processes , 2005 .

[28]  Jie Zhang,et al.  Prediction of polymer quality in batch polymerisation reactors using robust neural networks , 1998 .

[29]  Taizo Hanai,et al.  Analysis of initial conditions for polymerization reaction using fuzzy neural network and genetic algorithm , 2003, Comput. Chem. Eng..

[30]  Mohamed S. El-Aasser,et al.  Emulsion polymerization and emulsion polymers , 1997 .