Planar air breathing PEMFC with self-humidifying MEA and open cathode geometry design for portable applications

Abstract In this paper, planar air breathing PEMFCs without the need for endplates are proposed for low power portable applications. PEMFCs with 3 different cathode designs (parallel slit, circular open and oblique slit) with the same opening ratio and employing self-humidifying MEAs were investigated. Performance and stability tests were conducted in hydrogen dead-end operation under both self-breathing and forced convection condition. It was found that rib geometry and hydraulic diameter have significant impact on oxygen transportation. It was concluded that circular opening design yields the best performance and highest limiting current. This is because this design provides the shortest rib distance and smallest hydraulic diameter. However, fuel cell instability was observed under self-breathing and forced convection condition. This is due to the water accumulation that could not be removed by natural-evaporation at the opening cathode. Overall, our proposed air breathing PEMFC achieves a specific power of 150 W kg−1 and a power density of 347 mW cm−3.

[1]  W. Winkler The influence of the mass transfer on the geometric design of SOFC stacks , 2000 .

[2]  Tao Yang,et al.  A preliminary study of a six-cell stack with dead-end anode and open-slits cathode , 2008 .

[3]  Wang Ying,et al.  Effects of cathode channel configurations on the performance of an air-breathing PEMFC , 2005 .

[4]  Ay Su,et al.  Experimental evaluation of an ambient forced-feed air-supply PEM fuel cell , 2008 .

[5]  Fritz B. Prinz,et al.  Engineering model of a passive planar air breathing fuel cell cathode , 2007 .

[6]  Wang Ying,et al.  Three-dimensional analysis for effect of channel configuration on the performance of a small air-breathing proton exchange membrane fuel cell (PEMFC) , 2005 .

[7]  C. M. Rangel,et al.  High performance PEMFC stack with open-cathode at ambient pressure and temperature conditions , 2007 .

[8]  S. D. Fraser,et al.  Polarization study of a PEMFC with four reference electrodes at hydrogen starvation conditions , 2008 .

[9]  P. Lund,et al.  Effect of cathode structure on planar free-breathing PEMFC , 2004 .

[10]  T. Kallio,et al.  Water balance in a free-breathing polymer electrolyte membrane fuel cell , 2004 .

[11]  Suk Won Cha,et al.  Air-breathing miniature planar stack using the flexible printed circuit board as a current collector , 2009 .

[12]  Ki Tae Park,et al.  Improvement of water management in air-breathing and air-blowing PEMFC at low temperature using hydrophilic silica nano-particles , 2007 .

[13]  C. Arcoumanis,et al.  The formation of water droplets in an air-breathing PEMFC , 2009 .

[14]  Takemi Chikahisa,et al.  Effect of cathode separator structure on performance characteristics of free-breathing PEMFCs , 2006 .

[15]  S. H. Huang,et al.  A novel ribbed cathode polar plate design in piezoelectric proton exchange membrane fuel cells , 2008 .

[16]  In-Hwan Oh,et al.  Effects of cathode open area and relative humidity on the performance of air-breathing polymer electrolyte membrane fuel cells , 2006 .

[17]  P. Lund,et al.  Measurement of current distribution in a free-breathing PEMFC , 2002 .

[18]  Ned Djilali,et al.  Mathematical modelling of ambient air-breathing fuel cells for portable devices , 2007 .

[19]  M. Han,et al.  Investigation of self-humidifying anode in polymer electrolyte fuel cells , 2007 .

[20]  Suk Won Cha,et al.  The role of ambient conditions on the performance of a planar, air-breathing hydrogen PEM fuel cell , 2006 .

[21]  Bruno Auvity,et al.  Evidence of a non-dimensional parameter controlling the flooding of PEMFC stack , 2008 .

[22]  O. Barbera,et al.  Polymer electrolyte fuel cell stack research and development , 2008 .

[23]  Peter Lund,et al.  Evaluation of planar free-breathing polymer electrolyte membrane fuel cell design , 2004 .

[24]  Andreas Schmitz,et al.  Influence of cathode opening size and wetting properties of diffusion layers on the performance of air-breathing PEMFCs , 2006 .

[25]  Olli Himanen,et al.  Operation of a planar free-breathing PEMFC in a dead-end mode , 2007 .