Oxidative Deoximation with Sodium Perborate1

Abstract An efficient and convenient conversion of oximes to corresponding carbonyl compounds with sodium perborate in glacial acetic acid is reported.

[1]  T. Straub Epoxidation of α,β-unsaturated ketones with sodium perborate , 1995 .

[2]  P. K. Sahoo,et al.  Oxidative Deoximation with Sodium Hypochlorite , 1994 .

[3]  L. Singh,et al.  Deoximation of Oximes, Sodium Oximates, and O-Benzoyloximes with Copper (II) Chloride Dihydrate , 1993 .

[4]  N. Vicker,et al.  A Facile Preparation of Quinazolin-4-(3H)-ones from O-Amido Benzonitriles Using Sodium Perborate , 1993 .

[5]  Tongshuang Li,et al.  Ozone Oxidation of Oximes to Carbonyl Compounds , 1993 .

[6]  G. O. Page The Mild Oxidation of Some Alpha-Difluoro Sulfides to Sulfones with Sodium Perborate , 1993 .

[7]  G. Olah,et al.  Efficient and Mild Oxidation of Ketoximes to Their Parent Ketones with Dimethyldioxirane1 , 1993 .

[8]  Jae Nyoung Kim,et al.  Regeneration of Cyclohexanone from Its Oxime with Various Dicarbonyl Compounds. , 2010 .

[9]  L. Kaczmarek,et al.  Mild Reductive Deoximation with TiCl4/NaI Reagent System , 1991 .

[10]  H. Meshram,et al.  Enzymatic deoximation of oximes by ultrasonically stimulated baker's yeast , 1991 .

[11]  R. D. Pace,et al.  The palladium assisted transfer reduction of. alpha. ,. beta. -unsaturated nitroalkenes to oximes using ammonium formate , 1990 .

[12]  J. Gupton,et al.  A Mild and Convenient Oxidation of Aryl Nitriles to Aryl Amides by Aqueous Sodium Perborate , 1990 .

[13]  Gun Lee Jong,et al.  Chlorotrimethylsilane-sodium nitrite or nitrate. Efficient deoximating reagents for aldoximes and ketoximes. , 1990 .

[14]  S. Chandrasekaran,et al.  An efficient and highly selective method for deoximation of ketoximes , 1989 .

[15]  S. B. Shim,et al.  Direct conversion of oximes and hydrazones into their ketones with dinitrogen tetroxide , 1987 .

[16]  P. S. Vankar,et al.  A mild and highly selective method for the regeneration of carbonyl compounds from oximes and (2,4-dinitrophenyl)hydrazones , 1986 .

[17]  S. Stiver,et al.  Reaction of an α,β-unsaturated nitro-compound with lithium dimethylcuprate. A novel synthesis of a 3α,5α-cyclosteroid , 1983 .

[18]  J. Drabowicz Rapid Deoximation with Pyridinium Chlorochromate/Hydrogen Peroxide System , 1980 .

[19]  S. Ley,et al.  Regeneration of ketones from hydrazones, oximes, and semicarbazones by benzeneseleninic anhydride , 1977 .

[20]  G. Olah,et al.  Synthetic Methods and Reactions; XX1. Oxidative Cleavage of Oximes and Dimethylhydrazones with Nitronium and Nitrosonium Salts , 1976 .

[21]  T. Hosokawa,et al.  The mild deoxymation reaction of ketoximes with the dioxygen complex of palladium , 1974 .

[22]  Katsuyuki Watanabe,et al.  Steroid nitrogen compounds. II. A novel synthesis of 5-chloro- and 5-bromo-6-oximino-5α-cholestanes and its reaction with nitrosyl chloride☆ , 1970 .

[23]  D. Barton,et al.  A Synthesis of Aldosterone Acetate1 , 1960 .

[24]  D. Barton,et al.  A New Photochemical Reaction1 , 1960 .

[25]  C. DePuy,et al.  Levulinic Acid as a Reagent for the Hydrolysis of Oximes and 2,4-Dinitrophenylhydrazones , 1959 .

[26]  J. M. Chemerda,et al.  The Synthesis of 5α-Pregnane-3β,17,α,21-triol-11,20-dione (Reichstein's Substance D) and 5α-Pregnane-3β,11β,17α,21-tetrol-20-one (Reichstein's Substance V) from 5α-Pregnan-3β-ol-11,20-dione , 1955 .

[27]  J. W. COOK,et al.  A Text-Book of Practical Organic Chemistry , 1948, Nature.

[28]  W. Hartung,et al.  alpha-Oximino acid intermediates for the synthesis of alpha-amino acids. , 1947, The Journal of organic chemistry.