Asymmetric anti-Prelog reduction of ketones catalysed by Paracoccus pantotrophus and Comamonas sp. cells via hydrogen transfer

[1]  John M Woodley,et al.  New opportunities for biocatalysis: making pharmaceutical processes greener. , 2008, Trends in biotechnology.

[2]  A. Glieder,et al.  An exceptionally DMSO-tolerant alcohol dehydrogenase for the stereoselective reduction of ketones. , 2008, ChemSusChem.

[3]  G. Oberdorfer,et al.  Stereocomplementary Asymmetric Reduction of Bulky–Bulky Ketones by Biocatalytic Hydrogen Transfer , 2008 .

[4]  Delong Liu,et al.  Enantioselective transfer hydrogenation of ketones with planar chiral ruthenocene-based phosphinooxazoline ligands , 2008 .

[5]  Hui Lin,et al.  Preparation the Key Intermediate of Angiotensin‐Converting Enzyme (ACE) Inhibitors: High Enantioselective Production of Ethyl (R)‐2‐Hydroxy‐4‐Phenylbutyrate with Candida boidinii CIOC21 , 2008 .

[6]  H. Pellissier Recent Developments in Dynamic Kinetic Resolution , 2008 .

[7]  R. Stenkamp,et al.  X-ray structure and designed evolution of an artificial transfer hydrogenase. , 2008, Angewandte Chemie.

[8]  K. Kantardjieff,et al.  Inverting the enantioselectivity of a carbonyl reductase via substrate-enzyme docking-guided point mutation. , 2008, Organic letters.

[9]  H. Gröger,et al.  Practical Two‐Step Synthesis of an Enantiopure Aliphatic Terminal (S)‐Epoxide Based on Reduction of Haloalkanones with “Designer Cells” , 2007 .

[10]  Paul N. Devine,et al.  Chemo- and enantioselective routes to chiral fluorinated hydroxyketones using ketoreductases. , 2007, Organic letters.

[11]  Oliver May,et al.  Biocatalytic reductions: from lab curiosity to "first choice". , 2007, Accounts of chemical research.

[12]  J. Stewart,et al.  Reductions of cyclic β-keto esters by individual Saccharomyces cerevisiae dehydrogenases and a chemo-enzymatic route to (1R,2S)-2-methyl-1-cyclohexanol , 2007 .

[13]  Dunming Zhu,et al.  Enzymatic ketone reduction: mapping the substrate profile of a short-chain alcohol dehydrogenase (YMR226c) from Saccharomyces cerevisiae , 2007 .

[14]  Andreas Liese,et al.  Biocatalytic ketone reduction—a powerful tool for the production of chiral alcohols—part I: processes with isolated enzymes , 2007, Applied Microbiology and Biotechnology.

[15]  Andreas Liese,et al.  Biocatalytic ketone reduction—a powerful tool for the production of chiral alcohols—part II: whole-cell reductions , 2007, Applied Microbiology and Biotechnology.

[16]  Wolfgang Kroutil,et al.  Enzymatic reduction of ketones in "micro-aqueous" media catalyzed by ADH-A from Rhodococcus ruber. , 2007, Organic letters.

[17]  T. Ema,et al.  Highly enantioselective and efficient synthesis of methyl (R)-o-chloromandelate with recombinant E. coli: toward practical and green access to clopidogrel. , 2007, Organic & biomolecular chemistry.

[18]  M. Beller,et al.  New Ruthenium Catalysts for Asymmetric Transfer Hydrogenation of Prochiral Ketones , 2007 .

[19]  K. Drauz,et al.  Enantioselective reduction of 4-fluoroacetophenone at high substrate concentration using a tailor-made recombinant whole-cell catalyst , 2007 .

[20]  Junhua Tao,et al.  Recent Advances in Developing Chemoenzymatic Processes for Active Pharmaceutical Ingredients , 2007 .

[21]  Paul N. Devine,et al.  Enzyme-catalyzed enantioselective diaryl ketone reductions. , 2007, Organic letters.

[22]  Dunming Zhu,et al.  Enantioselective enzymatic reductions of sterically bulky aryl alkyl ketones catalyzed by a NADPH-dependent carbonyl reductase. , 2006, The Journal of organic chemistry.

[23]  Jung Woon Yang,et al.  Catalytic asymmetric transfer hydrogenation of alpha-ketoesters with hantzsch esters. , 2006, Organic letters.

[24]  H. Adolfsson,et al.  Enantioswitchable catalysts for the asymmetric transfer hydrogenation of aryl alkyl ketones. , 2006, Organic letters.

[25]  Oliver May,et al.  Enantioselective reduction of ketones with "designer cells" at high substrate concentrations: highly efficient access to functionalized optically active alcohols. , 2006, Angewandte Chemie.

[26]  G. Clarkson,et al.  An outstanding catalyst for asymmetric transfer hydrogenation in aqueous solution and formic acid/triethylamine. , 2006, Chemical communications.

[27]  Dunming Zhu,et al.  Stereoselective ketone reduction by a carbonyl reductase from Sporobolomyces salmonicolor. Substrate specificity, enantioselectivity and enzyme-substrate docking studies. , 2006, Organic & biomolecular chemistry.

[28]  N. Iwai,et al.  An effective method to use ionic liquids as reaction media for asymmetric reduction by Geotrichum candidum , 2006 .

[29]  Christian C. Gruber,et al.  Biocatalytic deuterium- and hydrogen-transfer using over-expressed ADH-‘A’: enhanced stereoselectivity and 2H-labeled chiral alcohols , 2006 .

[30]  P. Moran,et al.  Bioreduction of 2-azido-1-arylethanones mediated by Geotrichum candidum and Rhodotorula glutinis , 2006 .

[31]  J. Rozzell,et al.  A Two‐Step Chemoenzymatic Synthesis of the Natural Pheromone (+)‐Sitophilure Utilizing Isolated, NADPH‐Dependent Ketoreductases , 2006 .

[32]  Dunming Zhu,et al.  Enzymatic enantioselective reduction of α-ketoesters by a thermostable 7α-hydroxysteroid dehydrogenase from Bacteroides fragilis , 2006 .

[33]  S. Leite,et al.  Microbial reduction of ethyl 2-oxo-4-phenylbutyrate. Searching for R-enantioselectivity. New access to the enalapril like ACE inhibitors , 2006 .

[34]  W. Kroutil,et al.  Regio‐ and Stereoselective Reduction of Diketones and Oxidation of Diols by Biocatalytic Hydrogen Transfer , 2006 .

[35]  B. Witholt,et al.  Efficient NADPH Recycling in Enantioselective Bioreduction of a Ketone with Permeabilized Cells of a Microorganism Containing a Ketoreductase and a Glucose 6-Phosphate Dehydrogenase , 2006 .

[36]  M. Reetz,et al.  An efficient catalyst system for the asymmetric transfer hydrogenation of ketones: remarkably broad substrate scope. , 2006, Journal of the American Chemical Society.

[37]  J. Sinisterra,et al.  Enantioselective production of halohydrin precursor of Propranolol catalysed by immobilized yeasts , 2005 .

[38]  Christian C. Gruber,et al.  Non‐Racemic Halohydrins via Biocatalytic Hydrogen‐Transfer Reduction of Halo‐Ketones and One‐Pot Cascade Reaction to Enantiopure Epoxides , 2005 .

[39]  Y. Makino,et al.  Production of (R)-chiral alcohols by a hydrogen-transfer bioreduction with NADH-dependent Leifsonia alcohol dehydrogenase (LSADH) , 2005 .

[40]  Ramesh N. Patel,et al.  Purification and Cloning of a Ketoreductase used for the Preparation of Chiral Alcohols , 2005 .

[41]  A. Chadha,et al.  Asymmetric reduction of alkyl 2-oxo-4-arylbutanoates and -but-3-enoates by Candida parapsilosis ATCC 7330: assignment of the absolute configuration of ethyl 2-hydroxy-4-(p-methylphenyl)but-3-enoate by 1H NMR , 2004 .

[42]  W. Kroutil,et al.  Recent advances in the biocatalytic reduction of ketones and oxidation of sec-alcohols. , 2004, Current opinion in chemical biology.

[43]  J. D. Carballeira,et al.  Highly stereoselective reduction of haloketones using three new yeasts: application to the synthesis of (S)-adrenergic β-blockers related to propranolol , 2004 .

[44]  J. Bäckvall,et al.  Chemoenzymatic dynamic kinetic resolution. , 2004, Trends in biotechnology.

[45]  Bernhard Hauer,et al.  Industrial methods for the production of optically active intermediates. , 2004, Angewandte Chemie.

[46]  H. Pellissier Dynamic Kinetic Resolution , 2003 .

[47]  J. Bäckvall,et al.  Combination of enzymes and metal catalysts. A powerful approach in asymmetric catalysis. , 2003, Chemical reviews.

[48]  W. Kroutil,et al.  Enzymatic Racemisation and its Application to Synthetic Biotransformations , 2003 .

[49]  W. Kroutil,et al.  Biocatalytic asymmetric hydrogen transfer employing Rhodococcus ruber DSM 44541. , 2003, The Journal of organic chemistry.

[50]  Yangsoo Ahn,et al.  Dynamic kinetic resolutions and asymmetric transformations by enzymes coupled with metal catalysis. , 2002, Current opinion in biotechnology.

[51]  Hiroaki Yamamoto,et al.  Practical application of recombinant whole-cell biocatalysts for the manufacturing of pharmaceutical intermediates such as chiral alcohols , 2002 .

[52]  T. Matsuda,et al.  Asymmetric reduction of simple aliphatic ketones with dried cells of Geotrichum candidum , 2002 .

[53]  C. Moitzi,et al.  Biocatalytic asymmetric hydrogen transfer. , 2002, Angewandte Chemie.

[54]  H. Ohta,et al.  Microbial asymmetric reduction of α-hydroxyketones in the anti-Prelog selectivity , 2001 .

[55]  T. Miura,et al.  Asymmetric synthesis of (R)-2-chloro-1-(m-chlorophenyl)ethanol using acetone powder of Geotrichum candidum , 2001, Biotechnology Letters.

[56]  Petra Hildebrandt,et al.  Efficient resolution of prostereogenic arylaliphatic ketones using a recombinant alcohol dehydrogenase from Pseudomonas fluorescens , 2001 .

[57]  Ryoji Noyori,et al.  Asymmetric Catalysis by Architectural and Functional Molecular Engineering: Practical Chemo- and Stereoselective Hydrogenation of Ketones. , 2001, Angewandte Chemie.

[58]  A. Medici,et al.  Combined microbial oxidation and reduction: a new approach to the highyield synthesis of homochiral unsaturated secondary alcohols from racemates , 1995 .

[59]  Karlheinz Drauz,et al.  Enzyme Catalysis in Organic Synthesis , 1995 .

[60]  A. Klibanov,et al.  Asymmetric oxidoreductions catalyzed by alcohol dehydrogenase in organic solvents , 1986 .

[61]  V. Prelog Specification of the stereospecificity of some oxido-reductases by diamond lattice sections , 1964 .

[62]  R. Phillips,et al.  Asymmetric reduction of ethynyl ketones and ethynylketoesters by secondary alcohol dehydrogenase from Thermoanaerobacter ethanolicus , 2000 .

[63]  R. Noyori,et al.  Quantitative expression of dynamic kinetic resolution of chirally labile enantiomers: stereoselective hydrogenation of 2-substituted 3-oxo carboxylic esters catalyzed by BINAP-ruthenium(II) complexes , 1993 .

[64]  Kurt Faber,et al.  Biotransformations in Organic Chemistry , 1992 .

[65]  S. Servi Microbial reagents in organic synthesis , 1992 .