Charge trapping and reliability characteristics of ultra-thin HfYOx films on n-GaAs substrates

Abstract Ultra-thin layers of the HfYO x gate dielectric were deposited on n-GaAs substrates by employing radio frequency (rf) sputter deposition system with a Si interface control layer sandwiched between the dielectric and semiconductor. The trapping/detrapping behaviour of charge carriers in the ultra-thin HfYO x /Si gate dielectric stack has been extensively studied during constant-voltage stressing (CVS) and compared with the results obtained from directly deposited HfYO x films on n-GaAs. The increase in gate leakage current observed during electrical stress is estimated and explained by taking into account the build up of trap charges and stress induced trap generation. Also, the capture cross-section of the generated traps is estimated. The variation of the trap centroid and the trapped charge density with injected influences have been investigated using constant current stressing (CCS) measurements. The dielectric breakdown and reliability of the dielectric films have been studied using constant-voltage stressing. A high time-dependent dielectric breakdown (TDDB, t bd  ⩾ 1700 s) is observed for HfYO x gate dielectric with a silicon inter-layer under a high constant-voltage stress (8 V).

[1]  Alessandro Paccagnella,et al.  Electrically and radiation induced leakage currents in thin oxides , 2000 .

[2]  J. Stathis Percolation models for gate oxide breakdown , 1999 .

[3]  P. Ehrhart,et al.  Comparison of precursors for pulsed metal–organic chemical vapor deposition of HfO2 high-K dielectric thin films , 2005 .

[4]  D. Schroder Semiconductor Material and Device Characterization , 1990 .

[5]  Soon-Gil Yoon,et al.  Interfacial and electrical properties of ZrxTi1−xO4 (x=0.66) films deposited by liquid-delivery metal organic chemical vapor deposition to be used as high-k gate dielectric , 2008 .

[6]  Elyse Rosenbaum,et al.  Silicon dioxide breakdown lifetime enhancement under bipolar bias conditions , 1993 .

[7]  C. Maiti,et al.  Charge trapping properties of ultra-thin TiO2 films on strained-Si , 2007 .

[8]  C. Maiti,et al.  Effects of an ultrathin Si passivation layer on the interfacial properties of RF-sputtered HfYOx on n-GaAs substrates , 2009 .

[9]  K. C. Kao,et al.  Electrical Transport in Solids , 1983 .

[10]  Inversion-type enhancement-mode HfO2-based GaAs metal-oxide-semiconductor field effect transistors with a thin Ge layer , 2008 .

[11]  Marc Heyns,et al.  Relation between stress-induced leakage current and time-dependent dielectric breakdown in ultra-thin gate oxides , 1999 .

[12]  G. Dalapati,et al.  Characterization of Y2O3 gate dielectric on n-GaAs substrates , 2010 .

[13]  Young-Hee Kim,et al.  Reliability characteristics of high-k dielectrics , 2004, Microelectron. Reliab..

[14]  Model for the charge trapping in high permittivity gate dielectric stacks , 2001 .

[15]  P. Lenahan,et al.  Magnetic resonance studies of trapping centers in high-/spl kappa/ dielectric films on silicon , 2005, IEEE Transactions on Device and Materials Reliability.

[16]  A. Asenov,et al.  Enhancement-Mode GaAs MOSFETs With an $\hbox{In}_{0.3} \hbox{Ga}_{0.7}\hbox{As}$ Channel, a Mobility of Over 5000 $ \hbox{cm}^{2}/\hbox{V} \cdot \hbox{s}$, and Transconductance of Over 475 $\mu\hbox{S}/\mu\hbox{m}$ , 2007, IEEE Electron Device Letters.

[17]  R. Chau,et al.  Benchmarking nanotechnology for high-performance and low-power logic transistor applications , 2004, IEEE Transactions on Nanotechnology.

[18]  R. Wallace,et al.  High-κ gate dielectrics: Current status and materials properties considerations , 2001 .

[19]  V. Misra,et al.  Electrical characteristics of metal-oxide-semiconductor capacitors on p-GaAs using atomic layer deposition of ultrathin HfAlO gate dielectric , 2008 .

[20]  G. Dalapati,et al.  Characterization of sputtered TiO2 gate dielectric on aluminum oxynitride passivated p-GaAs , 2008 .

[21]  S. Haddad,et al.  The nature of charge trapping responsible for thin-oxide breakdown under a dynamic field stress , 1987, IEEE Electron Device Letters.

[22]  F. B. McLean A Framework for Understanding Radiation-Induced Interface States in SiO2 MOS Structures , 1980, IEEE Transactions on Nuclear Science.