High-temperature (350°C) glass phosphor layer for converted white light-emitting diodes

The high-temperature operation up to 350°C of glass phosphor layer for using in converted white light-emitting diodes is demonstrated. The results showed that the phosphor-converted white light-emitting diode (PC-WLEDs) maintained good thermal stability in lumen, chromaticity, and transmittance characteristics at the high temperature up to 350°C. The lumen degradation, chromaticity shift, and transmittance loss in glass based high-power PC-WLEDs under thermal aging at 150, 250, 350, and 450°C are presented and compared with the silicone based high-power PC-WLEDs under thermal aging at 150 and 250°C. The result clearly indicated that the glass based PC-WLEDs exhibited better thermal stability in lumen degradation, chromaticity shift, and transmittance loss than the silicone based PC-WLEDs. The advantages of glass doped encapsulation in high temperature PC-WLEDs could be arisen from the material property of glass transition temperature 567°C higher than silicone of 150°C. These newly developed high-temperature glass based PC-WLEDs are essentially critical to the application of LED modules in the area where the high-power, high-temperature, and absolute reliability are required for use in the next-generation solid-state lighting.

[1]  Wood-Hi Cheng,et al.  High Thermal Stability of Phosphor-Converted White Light-Emitting Diodes Employing Ce:YAG-Doped Glass , 2011, IEEE Journal of Selected Topics in Quantum Electronics.

[2]  Y.K. Lin,et al.  Failure Mechanisms Associated with Lens Shape of High-Power LED Modules in Aging Test , 2007, LEOS 2007 - IEEE Lasers and Electro-Optics Society Annual Meeting Conference Proceedings.

[3]  D. H. Mash,et al.  Light-emitting diodes , 1977, Nature.

[4]  Jao-Hwa Kuang,et al.  Decay Mechanisms of Radiation Pattern and Optical Spectrum of High-Power LED Modules in Aging Test , 2009, IEEE Journal of Selected Topics in Quantum Electronics.

[5]  G. G. Stokes "J." , 1890, The New Yale Book of Quotations.

[6]  W. Cheng,et al.  High humidity resistance of high-power white-light-emitting diode modules employing Ce:YAG doped glass , 2011, 2011 IEEE 61st Electronic Components and Technology Conference (ECTC).

[7]  Takeshi Yanagisawa,et al.  Long-term accelerated current operation of white light-emitting diodes , 2005 .

[8]  Wood-Hi Cheng,et al.  Investigation of Ce:YAG Doping Effect on Thermal Aging for High-Power Phosphor-Converted White-Light-Emitting Diodes , 2009, IEEE Transactions on Device and Materials Reliability.

[9]  Wood-Hi Cheng,et al.  Lumen degradation and chromaticity shift in glass and silicone based high-power phosphor-converted white-emitting diodes under thermal tests , 2011, Optical Engineering + Applications.

[10]  Wood-Hi Cheng,et al.  Mean-time-to-failure evaluations of encapsulation materials for LED package in accelerated thermal tests , 2012, Microelectron. Reliab..

[11]  Saburo Imamura,et al.  Polymeric optical waveguide circuits formed using silicone resin , 1998 .