Swelling and radiation-induced segregation in austentic alloys

Abstract To elucidate the relationship between radiation-induced segregation and swelling in austenitic stainless steels, a series of alloys were irradiated with 3.2 MeV protons to doses of 0.5 and 1.0 dpa at 400 °C. Three alloy series were irradiated, the first to examine the effect of bulk nickel in Fe–16–18Cr–xNi, the second to determine the effect of Mo and P in an Fe–16Cr–13Ni base alloy, and the third to examine the effect of oversized solute Zr addition to an Fe–18Cr–0.5Ni alloy. The addition of nickel in Fe–16–18Cr–xNi caused a significant decrease in swelling and increase in segregation. The addition of Mo+P to Fe–16Cr–13Ni eliminated swelling and reduced segregation. The addition of Zr to Fe–18Cr–9.5Ni decreased swelling and altered the segregation. Comparison of swelling with changes in lattice parameter and shear modulus caused by the segregation showed that swelling correlates well with the decreases in lattice parameter caused by radiation-induced segregation. Those alloys whose segregation decreased the lattice parameter the greatest showed the lowest swelling. These results are consistent with theoretical predictions made by Wolfer.

[1]  M. L. Hamilton,et al.  Effects of radiation on materials: 18. international symposium , 1990 .

[2]  M. Grossbeck Effects of radiation on materials : 21th international symposium , 2001 .

[3]  E. Kenik,et al.  On the mechanism of radiation-induced segregation in austenitic Fe–Cr–Ni alloys , 1998 .

[4]  Guk-Rwang Won American Society for Testing and Materials , 1987 .

[5]  T. Allen,et al.  Intercomparison of microchemical evolution under various types of particle irradiation , 1993 .

[6]  M. Guttmann,et al.  Role of molybdenum in phosphorus-induced temper embrittlement of 12%Cr martensitic stainless steel , 1981 .

[7]  J. S. Perrin,et al.  Effects of radiation on materials , 1981 .

[8]  Todd R. Allen,et al.  Dependence of radiation-induced segregation on dose, temperature and alloy composition in austenitic alloys , 1995 .

[9]  E. Kenik,et al.  Effects of proton irradiation on the microstructure and microchemistry of type 304L stainless steel , 1993 .

[10]  E. Kenik Application of analytical electron microscopy to radiation damage studies , 1994 .

[11]  Takahiko Kato,et al.  Effects of Systematic Modification with Oversized Elements on Void Formation in 316L Austenitic Stainless Steel under Electron Irradiation , 1991 .

[12]  L. Mansur Theory and experimental background on dimensional changes in irradiated alloys , 1994 .

[13]  E. J. Fulton,et al.  Voids in Irradiated Stainless Steel , 1967, Nature.

[14]  L. Mansur,et al.  The capture efficiency of coated voids , 1980 .

[15]  T. Allen,et al.  Modeling radiation-induced segregation in austenitic Fe-Cr-Ni alloys , 1998 .

[16]  J. Venables,et al.  Developments in Electron Microscopy and Analysis , 1977 .

[17]  A. Marwick Segregation in irradiated alloys: The inverse Kirkendall effect and the effect of constitution on void swelling , 1978 .

[18]  G. Was,et al.  Proton-induced grain boundary segregation in stainless steel , 1991 .

[19]  T. Okita,et al.  A critical test of the classical rate theory for void swelling , 2004 .

[20]  F. Garner,et al.  Spinodal-like decomposition of Fe-35Ni and Fe-Cr-35Ni alloys during irradiation or thermal aging , 1993 .

[21]  John W. Davis,et al.  Proceedings of Topical Conference on Ferritic Alloys for Use in Nuclear Energy Technologies, Snowbird, Utah, June 19-23, 1983 , 1984 .

[22]  L. Rehn,et al.  Radiation-induced segregation in binary and ternary alloys , 1979 .

[23]  Frank A. Garner,et al.  Irradiation Performance of Cladding and Structural Steels in Liquid Metal Reactors , 2006 .

[24]  Takahiko Kato,et al.  Grain boundary segregation under electron irradiation in austenitic stainless steels modified with oversized elements , 1992 .

[25]  W. G. Johnston,et al.  An experimental survey of swelling in commercial Fe-Cr-Ni alloys bombarded with 5 MeV Ni Ions , 1974 .

[26]  L. Mansur,et al.  Evidence for a mechanism of swelling variation with composition in irradiated Fe-Cr-Ni alloys , 1985 .

[27]  J. Bradshaw,et al.  Pupil Size as a Measure of Arousal during Information Processing , 1967, Nature.