Olive stone an attractive source of bioactive and valuable compounds.

The olive stone and seed are an important byproduct generated in the olive oil extraction and pitted table olive industries. As a lignocellulosic material, the hemicellulose, cellulose and lignin are the main components of olive stone as wells as protein, fat, phenols, free sugars and poliols composition. The main use of this biomass is as combustion to produce electric energy or heat. Other uses such as activated carbon, furfural production, plastic filled, abrasive and cosmetic or other potential uses such as biosorbent, animal feed or resin formation have been cited. In this article, an overview of the characterization and main uses of olive stone and seed are described for the first time. Also, this review discusses the potential use of this material based on each component. In this way, a new approach to the olive stone and seed by pretreating with a steam explosion followed by chemical fractionation is described.

[1]  C. Genot,et al.  Volatile compounds of oxidized pork phospholipids , 1998 .

[2]  J. Hoult,et al.  Inhibition of leukocyte 5-lipoxygenase by phenolics from virgin olive oil. , 1999, Biochemical pharmacology.

[3]  J. de Dios Alché,et al.  Biochemical characterization and cellular localization of 11S type storage proteins in olive (Olea europaea L.) seeds. , 2006, Journal of agricultural and food chemistry.

[4]  Luca Carraro,et al.  Dietary supplementation with olive stone meal in growing rabbits , 2005 .

[5]  M. Ballesteros,et al.  Ethanol from lignocellulosic materials by a simultaneous saccharification and fermentation process (SFS) with Kluyveromyces marxianus CECT 10875 , 2004 .

[6]  C O Eromosele,et al.  Fatty acid compositions of seed oils of Haematostaphis barteri and Ximenia americana. , 2002, Bioresource technology.

[7]  J. Fernández-Bolaños,et al.  Olive stones as a source of fermentable sugars , 1987 .

[8]  A. Zabaniotou,et al.  Production and characterization of activated carbons from olive-seed waste residue , 2005 .

[9]  S. Zarini,et al.  Antioxidant and other biological activities of olive mill waste waters. , 1999, Journal of agricultural and food chemistry.

[10]  N. Petrov,et al.  Removal of arsenic(III) from aqueous solution by activated carbons prepared from solvent extracted olive pulp and olive stones , 2006 .

[11]  G. Blázquez,et al.  Removal of cadmium ions with olive stones: the effect of somes parameters , 2005 .

[12]  S. Samra,et al.  Removal of Aluminum from Some Water Samples by Sorptive-Flotation Using Powdered Modified Activated Carbon as a Sorbent and Oleic Acid as a Surfactant , 2006, Analytical sciences : the international journal of the Japan Society for Analytical Chemistry.

[13]  David Fairen-Jimenez,et al.  Granular and monolithic activated carbons from KOH-activation of olive stones , 2006 .

[14]  P. Prenzler,et al.  Quantitative changes in phenolic content during physiological development of the olive (Olea europaea) cultivar Hardy's Mammoth. , 2003, Journal of agricultural and food chemistry.

[15]  C. Vaca-Garcia,et al.  Design of a Batch Solvolytic Liquefaction Reactor for the Valorization of Residues from the Agricultural Foodstuff , 2003 .

[16]  J. Fernández-Bolaños,et al.  Characterization of the lignin obtained by alkaline delignification and of the cellulose residue from steam-exploded olive stones , 1999 .

[17]  C. Vaca-Garcia,et al.  Solvent-free fatty acylation of cellulose and lignocellulosic wastes. Part 2: reactions with fatty acids , 1999 .

[18]  G. Bianchi Lipids and phenols in table olives , 2003 .

[19]  H. Järvinen,et al.  Impaired absorption of cholesterol and bile acids in patients with an ileoanal anastomosis , 1997, Gut.

[20]  J. Fernández-Bolaños,et al.  Hydroxytyrosol and tyrosol as the main compounds found in the phenolic fraction of steam-exploded olive stones , 1998 .

[21]  J. F. González,et al.  Combustion optimisation of biomass residue pellets for domestic heating with a mural boiler , 2004 .

[22]  J. Fernández-Bolaños,et al.  Fibre fraction carbohydrates in Olea europaea (Gordal and Manzanilla var.) , 1992 .

[23]  M. Asther,et al.  Enzymatic saccharification of wheat straw for bioethanol production by a combined cellulase xylanase and feruloyl esterase treatment , 2006 .

[24]  Valentina Ruiz-Gutiérrez,et al.  Glucósidos fenólicos amargos de las semillas del olivo (Olea europea) , 1994 .

[25]  K. Akimoto,et al.  Modulation of interleukin-8 and nitric oxide synthase mRNA levels by interferon-gamma in macrophages stimulated with lignin derivatives and lipopolysaccharides. , 2003, Cancer detection and prevention.

[26]  C. Guzmán,et al.  Preparation and characteristics of activated carbon from olive stones and walnut shells , 2006 .

[27]  M. Newman,et al.  Effects of temperature and moisture on dilute-acid steam explosion pretreatment of corn stover and cellulase enzyme digestibility , 2003, Applied biochemistry and biotechnology.

[28]  G. Zacchi,et al.  Optimization of steam pretreatment of corn stover to enhance enzymatic digestibility , 2004, Applied biochemistry and biotechnology.

[29]  E. Cuerda-Correa,et al.  Preparation of activated carbons previously treated with hydrogen peroxide: Study of their porous texture , 2006 .

[30]  María del Rosario Martínez Martínez,et al.  Sorption of Pb(II), Ni(II), Cu(II) and Cd(II) from aqueous solution by olive stone waste , 2006 .

[31]  S. Fujisawa,et al.  Molecular requirements of lignin-carbohydrate complexes for expression of unique biological activities. , 2005, Phytochemistry.

[32]  Y. Yamamoto,et al.  Immunopotentiating activity of the water-soluble lignin rich fraction prepared from LEM--the extract of the solid culture medium of Lentinus edodes mycelia. , 1997, Bioscience, biotechnology, and biochemistry.

[33]  F. Bornet,et al.  Olive oil phenolics are dose‐dependently absorbed in humans , 2000, FEBS letters.

[34]  H. Sakagami,et al.  Effect of lignins and their precursors on nitric oxide, citrulline and asparagine production by mouse macrophage-like Raw 264.7 cells. , 2002, Anticancer research.

[35]  Ioannis S. Arvanitoyannis,et al.  Current and potential uses of thermally treated olive oil waste , 2007 .

[36]  Alpeorujo y semillas de olivo presentan el mismo tipo de proteinas de almacenamiento , 2007 .

[37]  M. Coimbra,et al.  Isolation and characterisation of cell wall polymers from the heavily lignified tissues of olive (Olea europaea) seed hull , 1995 .

[38]  M. Coimbra,et al.  Structural characterisation by MALDI-MS of olive xylo-oligosaccharides obtained by partial acid hydrolysis , 2003 .

[39]  A. Ranalli,et al.  Acylglycerol and fatty acid components of pulp, seed, and whole olive fruit oils. Their use to characterize fruit variety by chemometrics. , 2002, Journal of agricultural and food chemistry.

[40]  H. Bartsch,et al.  The antioxidant/anticancer potential of phenolic compounds isolated from olive oil. , 2000, European journal of cancer.

[41]  D. Montané,et al.  High-temperature dilute-acid hydrolysis of olive stones for furfural production , 2002 .

[42]  N. Cresswell,et al.  Characterization of activated carbon prepared from a single cultivar of Jordanian Olive stones by chemical and physicochemical techniques , 2004 .

[43]  D. Ruiz,et al.  Chemical composition and nutrients availability for goats and sheep of two-stage olive cake and olive leaves , 2003 .

[44]  V. Siracusa,et al.  Eco-Compatible Use of Olive Husk as Filler in Thermoplastic Composites , 2001 .

[45]  G. Rivas,et al.  Equilibrium modeling of removal of cadmium ions by olive stones , 2006 .

[46]  A. Ouederni,et al.  Adsorption of dyes onto activated carbon prepared from olive stones. , 2005, Journal of environmental sciences.

[47]  A. Ranalli,et al.  Sterol and alcohol components of seed, pulp and whole olive fruit oils. Their use to characterise olive fruit variety by multivariates , 2002 .

[48]  M. Molina-Sabio,et al.  Development of porosity in a char during reaction with steam or supercritical water. , 2006, The journal of physical chemistry. B.

[49]  S. Lim,et al.  Anti-inflammatory effect of roasted licorice extracts on lipopolysaccharide-induced inflammatory responses in murine macrophages. , 2006, Biochemical and biophysical research communications.

[50]  Luigi Petarca,et al.  Treatment of olive oil industry wastes , 1999 .

[51]  J. Fernández-Bolaños,et al.  Steam-explosion of olive stones: hemicellulose solubilization and enhancement of enzymatic hydrolysis of cellulose. , 2001, Bioresource technology.

[52]  B. Halliwell,et al.  Effect of hydroxytyrosol found in extra virgin olive oil on oxidative DNA damage and on low-density lipoprotein oxidation , 1998 .

[53]  L. Zoumpoulakis,et al.  Optical properties of carbon materials formed by pyrolysis of novolac-resin/biomass composites , 2004 .

[54]  A. Pütün,et al.  Bio-oil from olive oil industry wastes: Pyrolysis of olive residue under different conditions , 2005 .

[55]  C. Sanz,et al.  Role of olive seed in the biogenesis of virgin olive oil aroma. , 2003, Journal of agricultural and food chemistry.