Structural and magnetic properties of the superconductors Mo₃Sb₇, Mo₃Al₂C and KₓFe₂₋ySe₂ under high pressure

This thesis is based on high pressure structural and superconducting phase diagrams of the three compounds Mo3Sb7, Mo3Al2C and KxFe2−ySe2, which have all been reported to exhibit unconventional superconductivity. A new technique for measuring magnetic susceptibility at high pressure in a Bridgman type pressure cell has been developed which places counterwound detection and compensation coils within the high pressure sample space, which allows for improved signal-to-noise ratios compared to other methods. X-ray powder diffraction using diamond anvil cells was utilised to study the structural evolution of these compounds with increasing pressure. The pressure-temperature phase diagram of Mo3Sb7 has been extended to higher pressures than reported previously and shows that the superconducting transition temperature increases. Structural measurements reveal that the cubic structure remains stable up to 13.6 GPa. Similar measurements on Mo3Al2C show a slight pressure dependence of Tc. A jump in the unit cell volume of Mo3Al2C indicates a structural transition occuring near 13.8 GPa. Finally high pressure X-ray powder diffraction measurements confirm a structural transition in both superconducting and insulating samples of K0.8Fe2−ySe2 (y = 0, 0.4). Low temperature structural measurements have been carried out to build up the pressure-temperature phase diagram of superconducting K0.8Fe2Se2. The strucutral transition occurs at a pressure between 13.2 and 15 GPa at low temperatures and appears to be strongly linked to the emergence of a second superconducting phase.

[1]  Jiaqiang Yan,et al.  The hybrid lattice of KxFe2−ySe2: where superconductivity and magnetism coexist , 2013, Scientific Reports.

[2]  H. Cao,et al.  Flux growth and physical properties of Mo3Sb7 single crystals , 2013, 1303.1106.

[3]  M. Fang,et al.  Role of the 245 phase in alkaline iron selenide superconductors revealed by high-pressure studies , 2012, 1209.1340.

[4]  Q. Xue,et al.  KFe2Se2 is the parent compound of K-doped iron selenide superconductors. , 2012, Physical review letters.

[5]  Z. Wang,et al.  Microstructure and ordering of iron vacancies in the superconductor system K y Fe x Se 2 as seen via transmission electron microscopy , 2011 .

[6]  M. Fang,et al.  Superconductivity at 32 K and anisotropy in Tl0.58Rb0.42Fe1.72Se2 crystals , 2011, 1101.0462.

[7]  H. Mao,et al.  Pressure-driven quantum criticality in iron-selenide superconductors. , 2010, Physical review letters.

[8]  Gang Wang,et al.  Superconductivity in the iron selenide KxFe2Se2 (0<= x<= 1) , 2010, 1012.2924.

[9]  D. Jaccard,et al.  Multiprobe experiments under high pressure: resistivity, magnetic susceptibility, heat capacity, and thermopower measurements around 5 GPa. , 2010, The Review of scientific instruments.

[10]  J. Chervin,et al.  Hydrostatic limits of 11 pressure transmitting media , 2009 .

[11]  F. Hsu,et al.  Superconductivity in the PbO-type structure α-FeSe , 2008, Proceedings of the National Academy of Sciences.

[12]  K. Syassen Ruby under pressure , 2008 .

[13]  D. Jaccard,et al.  Adaptation of the Bridgman anvil cell to liquid pressure mediums. , 2007, The Review of scientific instruments.

[14]  J. Hejtmánek,et al.  Spin fluctuations and superconductivity in Mo3Sb7. , 2007, Physical review letters.

[15]  T. Kamiya,et al.  Iron-based layered superconductor: LaOFeP. , 2006, Journal of the American Chemical Society.

[16]  L. Greene High‐Temperature Superconductors: Playgrounds for Broken Symmetries , 2005 .

[17]  S. Julian,et al.  Susceptibility measurements at high pressures using a microcoil system in an anvil cell , 2003 .

[18]  Goodhew The Basics of Crystallography and Diffraction , 1998 .

[19]  S. Girvin,et al.  Continuous quantum phase transitions , 1996, cond-mat/9609279.

[20]  B. Andersson,et al.  Electrical transport properties of dense bulk YBa2Cu4O8 produced by hot isostatic pressing , 1990 .

[21]  Moss,et al.  Optical evidence for the metallization of xenon at 132(5) GPa. , 1989, Physical review letters.

[22]  J. Wittig,et al.  A diamond anvil cell for the investigation of superconductivity under pressures of up to 50 GPa: Pb as a low temperature manometer , 1988 .

[23]  Chu,et al.  Superconductivity at 93 K in a new mixed-phase Yb-Ba-Cu-O compound system at ambient pressure. , 1987, Physical review letters.

[24]  P. Y. Yu,et al.  Technique for high‐pressure electrical conductivity measurement in diamond anvil cells at cryogenic temperatures , 1987 .

[25]  Ruoff,et al.  Nature of the state of stress produced by xenon and some alkali iodides when used as pressure media. , 1986, Physical review. B, Condensed matter.

[26]  Stanley Block,et al.  Hydrostatic limits in liquids and solids to 100 kbar , 1973 .

[27]  J. D. Barnett,et al.  Viscosity Measurements on Liquids to Pressures of 60 kbar , 1969 .

[28]  T. F. Smith,et al.  Superconducting manometers for high pressure measurement at low temperature , 1969 .

[29]  F. Murnaghan The Compressibility of Media under Extreme Pressures. , 1944, Proceedings of the National Academy of Sciences of the United States of America.

[30]  C. Harrison High pressure study of magnetic quantum phase transitions in transition metal materials , 2013 .

[31]  W. Marsden I and J , 2012 .

[32]  A. Chubukov Manifesto for a higher Tc , 2011 .

[33]  R. Khan,et al.  Pressure studies on the superconductor Mo3Sb7 , 2011 .

[34]  Ōnuki Yoshichika,et al.  Magnetism and Superconductivity in CePt3Si Under Pressure , 2006 .

[35]  R. Angel High-Pressure Structural Phase Transitions , 2000 .

[36]  B. Gyorffy Electron a Centenary Volume , 1997 .

[37]  A. P. Hammersley,et al.  Two-dimensional detector software: From real detector to idealised image or two-theta scan , 1996 .

[38]  J. Freund,et al.  Inverted isothermal equations of state and determination of B0, B'0 and B0 , 1989 .

[39]  Ian Jackson,et al.  The Elasticity of Periclase to 3 GPa and Some Geophysical Implications , 1982 .