Coalescence-Induced Self-Propulsion of Droplets on Superomniphobic Surfaces.

We utilized superomniphobic surfaces to systematically investigate the different regimes of coalescence-induced self-propulsion of liquid droplets with a wide range of droplet radii, viscosities, and surface tensions. Our results indicate that the nondimensional jumping velocity Vj* is nearly constant (Vj* ≈ 0.2) in the inertial-capillary regime and decreases in the visco-capillary regime as the Ohnesorge number Oh increases, in agreement with prior work. Within the visco-capillary regime, decreasing the droplet radius R0 results in a more rapid decrease in the nondimensional jumping velocity Vj* compared to increasing the viscosity μ. This is because decreasing the droplet radius R0 increases the inertial-capillary velocity Vic in addition to increasing the Ohnesorge number Oh.

[1]  Taehun Lee,et al.  Effects of initial conditions on the simulation of inertial coalescence of two drops , 2014, Comput. Math. Appl..

[2]  N. Miljkovic,et al.  Coalescence-induced nanodroplet jumping , 2016 .

[3]  Wei Wang,et al.  Metamorphic Superomniphobic Surfaces , 2017, Advanced materials.

[4]  L. Dasi,et al.  Hemocompatibility of Superhemophobic Titania Surfaces , 2017, Advanced healthcare materials.

[5]  K. Rykaczewski,et al.  Methodology for imaging nano-to-microscale water condensation dynamics on complex nanostructures. , 2011, ACS nano.

[6]  P. Angeli,et al.  On the effect of surfactants on drop coalescence at liquid/liquid interfaces , 2016 .

[7]  E. Wang,et al.  Condensation heat transfer on superhydrophobic surfaces , 2013 .

[8]  P. Angeli,et al.  Surfactant effects on the coalescence of a drop in a Hele-Shaw cell. , 2016, Physical review. E.

[9]  R. Ganguly,et al.  Surface engineering for phase change heat transfer: A review , 2014, 1409.5363.

[10]  Chunfeng Zhou,et al.  A computational study of the coalescence between a drop and an interface in Newtonian and viscoelastic fluids , 2006 .

[11]  Hieu Bui,et al.  Hemodynamic Performance and Thrombogenic Properties of a Superhydrophobic Bileaflet Mechanical Heart Valve , 2016, Annals of Biomedical Engineering.

[12]  Evelyn N Wang,et al.  Jumping-droplet-enhanced condensation on scalable superhydrophobic nanostructured surfaces. , 2012, Nano letters.

[13]  J. J. Jasper,et al.  The Surface Tension of Pure Liquid Compounds , 1972 .

[14]  A. Cassie,et al.  Wettability of porous surfaces , 1944 .

[15]  A. Kota,et al.  Free-Standing, Flexible, Superomniphobic Films. , 2016, ACS applied materials & interfaces.

[16]  A. Tuteja,et al.  The design and applications of superomniphobic surfaces , 2014 .

[17]  Shreyas Chavan,et al.  Enhanced Jumping-Droplet Departure. , 2015, Langmuir : the ACS journal of surfaces and colloids.

[18]  Y. Nam,et al.  Droplet coalescence on water repellant surfaces. , 2015, Soft matter.

[19]  J. Chen,et al.  Anti-icing surfaces based on enhanced self-propelled jumping of condensed water microdroplets. , 2013, Chemical communications.

[20]  A. Tuteja,et al.  Superoleophobic surfaces: design criteria and recent studies , 2013 .

[21]  Jian Yu Huang,et al.  Nanowire liquid pumps. , 2013, Nature nanotechnology.

[22]  P. Cheng,et al.  3D multiphase lattice Boltzmann simulations for morphological effects on self-propelled jumping of droplets on textured superhydrophobic surfaces☆ , 2015 .

[23]  A. Yalin,et al.  Fabrication of Nanostructured Omniphobic and Superomniphobic Surfaces with Inexpensive CO2 Laser Engraver. , 2017, ACS applied materials & interfaces.

[24]  E. Wang,et al.  How coalescing droplets jump. , 2014, ACS nano.

[25]  A. Kota,et al.  Tunable superomniphobic surfaces for sorting droplets by surface tension. , 2016, Lab on a chip.

[26]  Konrad Rykaczewski,et al.  Microdroplet growth mechanism during water condensation on superhydrophobic surfaces. , 2012, Langmuir : the ACS journal of surfaces and colloids.

[27]  James J. Feng,et al.  Self-propelled jumping upon drop coalescence on Leidenfrost surfaces , 2014, Journal of Fluid Mechanics.

[28]  Lei Jiang,et al.  Manipulating and dispensing micro/nanoliter droplets by superhydrophobic needle nozzles. , 2013, ACS nano.

[29]  A. Tuteja,et al.  Superomniphobic surfaces: Design and durability , 2013 .

[30]  J. Boreyko,et al.  Self-propelled dropwise condensate on superhydrophobic surfaces. , 2009, Physical review letters.

[31]  J. B. Segur,et al.  Viscosity of Glycerol and Its Aqueous Solutions , 1951 .

[32]  K. Kim,et al.  Dropwise Condensation on Micro- and Nanostructured Surfaces , 2014 .

[33]  James J. Feng,et al.  Numerical simulations of self-propelled jumping upon drop coalescence on non-wetting surfaces , 2014, Journal of Fluid Mechanics.

[34]  Daniel Bonn,et al.  Hydrodynamics of droplet coalescence. , 2005, Physical review letters.

[35]  Hong Zhao,et al.  Fabrication, surface properties, and origin of superoleophobicity for a model textured surface. , 2011, Langmuir : the ACS journal of surfaces and colloids.

[36]  P. Collier,et al.  Delayed frost growth on jumping-drop superhydrophobic surfaces. , 2013, ACS nano.

[37]  R. N. Wenzel RESISTANCE OF SOLID SURFACES TO WETTING BY WATER , 1936 .

[38]  A. Tuteja,et al.  Hierarchically Structured Superoleophobic Surfaces with Ultralow Contact Angle Hysteresis , 2012, Advanced materials.

[39]  D. J. Preston,et al.  Nanoengineered materials for liquid–vapour phase-change heat transfer , 2017 .

[40]  Lichao Gao,et al.  The "lotus effect" explained: two reasons why two length scales of topography are important. , 2006, Langmuir : the ACS journal of surfaces and colloids.

[41]  Gareth H. McKinley,et al.  Wolfgang von Ohnesorge , 2011 .

[42]  C. Kim,et al.  Turning a surface superrepellent even to completely wetting liquids , 2014, Science.

[43]  F. Chevy,et al.  Water spring: A model for bouncing drops , 2003 .

[44]  Jolanta A Watson,et al.  A dual layer hair array of the brown lacewing: repelling water at different length scales. , 2011, Biophysical journal.

[45]  Ya-Pu Zhao,et al.  Size effect on the coalescence-induced self-propelled droplet , 2011 .

[46]  K. Popat,et al.  Metallic superhydrophobic surfaces via thermal sensitization , 2017 .

[47]  Evelyn N Wang,et al.  Electric-field-enhanced condensation on superhydrophobic nanostructured surfaces. , 2013, ACS nano.

[48]  J. Weibel,et al.  Coalescence-Induced Jumping of Multiple Condensate Droplets on Hierarchical Superhydrophobic Surfaces , 2016, Scientific Reports.

[49]  Tongxi Yu,et al.  Fabrication of Novel Superhydrophobic Surfaces and Droplet Bouncing Behavior — Part 2: Water Droplet Impact Experiment on Superhydrophobic Surfaces Constructed Using ZnO Nanoparticles , 2011 .

[50]  Seungwon Shin,et al.  Energy and hydrodynamic analyses of coalescence-induced jumping droplets , 2013 .

[51]  Evelyn N Wang,et al.  Condensation on superhydrophobic surfaces: the role of local energy barriers and structure length scale. , 2012, Langmuir : the ACS journal of surfaces and colloids.

[52]  Jinliang Xu,et al.  Numerical investigation of coalescence-induced droplet jumping on superhydrophobic surfaces for efficient dropwise condensation heat transfer , 2016 .

[53]  Wei Wang,et al.  Superhydrophobic Coatings with Edible Materials. , 2016, ACS applied materials & interfaces.

[54]  T. Young III. An essay on the cohesion of fluids , 1805, Philosophical Transactions of the Royal Society of London.

[55]  Xuemei Chen,et al.  Multimode multidrop serial coalescence effects during condensation on hierarchical superhydrophobic surfaces. , 2013, Langmuir : the ACS journal of surfaces and colloids.

[56]  N. Kovalchuk,et al.  Effect of surfactant concentration and viscosity of outer phase during the coalescence of a surfactant-laden drop with a surfactant-free drop , 2016 .

[57]  Jolanta A Watson,et al.  Self-cleaning of superhydrophobic surfaces by self-propelled jumping condensate , 2013, Proceedings of the National Academy of Sciences.

[58]  M Paturzo,et al.  Dispensing nano-pico droplets and liquid patterning by pyroelectrodynamic shooting. , 2010, Nature nanotechnology.

[59]  Evelyn N Wang,et al.  Effect of droplet morphology on growth dynamics and heat transfer during condensation on superhydrophobic nanostructured surfaces. , 2012, ACS nano.