Study on Polymer Blends from Recycled Polypropylene and Plastic Waste Processed in a Hydrothermal Carbonization Process

: The remaining residues in plastic recycling facilities are incinerated or landfilled. In this study, hydro-char was prepared by hydrothermal carbonization of residue from plastics recycling facilities (RPRF) and the properties of hydro-char were analyzed. Additionally, the physical properties of the hydro-char/recycled polypropylene (PP) blends were stud-ied to evaluate the possibility of physical recycling of the RPRF. The hydro-char thus prepared was regular shaped-fine powder with uniform size, and its bulk density increased compared to the raw material ( i.e. , RPRF), making it easier to handle. The mechanical strength of the hydro-char/recycled PP blend was much higher than expected value, slightly lower than the composition average of the hydro-char and recycled PP. When a small amount of the impact modifier was incorporated into the blend, the impact strength of the blends was significantly increased. Therefore, it was concluded that physical recycling of the RPRF is possible after the hydrothermal treatment.

[1]  Clara Lisseth Mendoza Martinez,et al.  Hydrothermal carbonization of lignocellulosic agro-forest based biomass residues , 2021 .

[2]  Yafei Shen A review on hydrothermal carbonization of biomass and plastic wastes to energy products , 2020, Biomass and Bioenergy.

[3]  A. Fullana,et al.  Hydrothermal carbonization (HTC) of marine plastic debris , 2019 .

[4]  K. Yoshikawa,et al.  Utilization of mixed organic-plastic municipal solid waste as renewable solid fuel employing wet torrefaction. , 2019, Waste management.

[5]  Arun Gupta,et al.  Synthesis and characterization of carbon microspheres from rubber wood by hydrothermal carbonization , 2018, Journal of Chemical Technology & Biotechnology.

[6]  B. Xie,et al.  Hydrothermal Treatment of E-Waste Plastics for Tertiary Recycling: Product Slate and Decomposition Mechanisms , 2018, ACS Sustainable Chemistry & Engineering.

[7]  B. Xie,et al.  Products derived from waste plastics (PC, HIPS, ABS, PP and PA6) via hydrothermal treatment: Characterization and potential applications. , 2018, Chemosphere.

[8]  M. Hakkarainen,et al.  Microwave Assisted Hydrothermal Carbonization and Solid State Postmodification of Carbonized Polypropylene , 2018, ACS Sustainable Chemistry & Engineering.

[9]  Saad A. Al-Bogami,et al.  Direct crude oil cracking for producing chemicals: Thermal cracking modeling , 2018 .

[10]  Yafei Shen,et al.  Hydrothermal carbonization of medical wastes and lignocellulosic biomass for solid fuel production from lab-scale to pilot-scale , 2017 .

[11]  K. Yoshikawa,et al.  The effect of stirring in the hydrothermal process to convert the mixed municipal solid waste into uniform solid fuel , 2016 .

[12]  M. Muhler,et al.  Synthesis and characterization of lignite-like fuels obtained by hydrothermal carbonization of cellulose , 2016 .

[13]  Hao Wen,et al.  Thermal Cracking of Virgin and Waste Plastics of PP and LDPE in a Semibatch Reactor under Atmospheric Pressure , 2015 .

[14]  Shaolong Liu,et al.  Characterization of polypropylene–polyethylene blends made of waste materials with compatibilizer and nano-filler , 2013 .

[15]  T. Namioka,et al.  Effects of hydrothermal treatment on characteristics and combustion behaviors of municipal solid wastes , 2011 .

[16]  Neil R. Foster,et al.  A review of subcritical water as a solvent and its utilisation for the processing of hydrophobic organic compounds , 2011 .

[17]  Y. Son Development of a Novel Microcompounder for Polymer Blends and Nanocomposite , 2009 .

[18]  Motonobu Goto,et al.  Chemical recycling of plastics using sub- and supercritical fluids , 2009 .

[19]  T. Masuda,et al.  Thermal cracking of oils from waste plastics , 2003 .

[20]  T. Aminabhavi,et al.  A Review on Extraction and Identification of Crude Oil and Related Products Using Supercritical Fluid Technology , 2000 .

[21]  K. Yoshikawa,et al.  A Review on Pilot-Scale Applications of Hydrothermal Treatment for Upgrading Waste Materials , 2022 .