A review on the electrochemical reduction of CO2 in fuel cells, metal electrodes and molecular catalysts

Abstract In this review article, we report the development and utilisation of fuel cells, metal electrodes in aqueous electrolyte and molecular catalysts in the electrochemical reduction of CO2. Fuel cells are able to function in both electrolyser and fuel cell mode and could potentially reduce CO2 and produce energy at the same time. However, it requires considerably high temperatures for efficient operation. Direct reduction using metal electrodes and molecular catalysts are possible at room temperatures but require an additional applied potential and generally have low current densities. Density functional theory (DFT) studies have been used and have begun to unveil possible mechanisms involved which could lead to improvements and development of more efficient catalysts.

[1]  V. Thoi,et al.  Nickel N-heterocyclic carbene-pyridine complexes that exhibit selectivity for electrocatalytic reduction of carbon dioxide over water. , 2011, Chemical communications.

[2]  Yu Luo,et al.  Experimental characterization and modeling of the electrochemical reduction of CO2 in solid oxide electrolysis cells , 2013 .

[3]  Yihong Chen,et al.  Aqueous CO2 reduction at very low overpotential on oxide-derived Au nanoparticles. , 2012, Journal of the American Chemical Society.

[4]  M. Fujihira,et al.  Electrocatalytic reduction of CO2 by nickel(II) cyclam: Study of the reduction mechanism on mercury by cyclic voltammetry, polarography and electrocapillarity , 1990 .

[5]  M. Koper,et al.  Electrochemical reduction of carbon dioxide on copper electrodes , 2017 .

[6]  Yoshio Hori,et al.  Electrochemical reduction of carbon dioxide at a series of platinum single crystal electrodes , 2000 .

[7]  Andrzej Czerwiński,et al.  Voltammetric study of carbon monoxide and carbon dioxide adsorption on smooth and platinized platinum electrodes , 1985 .

[8]  A. Asthagiri,et al.  Selectivity of CO(2) reduction on copper electrodes: the role of the kinetics of elementary steps. , 2013, Angewandte Chemie.

[9]  William J. Durand,et al.  The importance of surface morphology in controlling the selectivity of polycrystalline copper for CO2 electroreduction. , 2012, Physical chemistry chemical physics : PCCP.

[10]  J. J. Kim,et al.  Reduction of CO2 and CO to methane on Cu foil electrodes , 1988 .

[11]  K. Ogura,et al.  Electrocatalytic reduction of carbon dioxide by substituted pyridine and pyrazole complexes of palladium , 1996 .

[12]  G. Balazs,et al.  Effects of CO on the electrocatalytic activity of Ni (cyclam)2+ toward the reduction of CO2 , 1993 .

[13]  G. Balazs,et al.  The adsorption of Ni(cyclam)+ at mercury electrodes and its relation to the electrocatalytic reduction of CO2 , 1992 .

[14]  A. Fujishima,et al.  Electrochemical reduction of carbon dioxide on hydrogen-storing materials , 1994 .

[15]  J. Petit,et al.  Molecular catalysts in photoelectrochemical cells , 1989 .

[16]  Masahiro Watanabe,et al.  Design of Alloy Electrocatalysts for CO 2 Reduction III . The Selective and Reversible Reduction of on Cu Alloy Electrodes , 1991 .

[17]  W. D. Collins,et al.  The Use of Hydrogenated Oils in the Manufacture of Tin Plate , 1920 .

[18]  H. Abruña,et al.  Electrocatalytic reduction of carbon dioxide with iron, cobalt, and nickel complexes of terdentate ligands , 1992 .

[19]  M. Bradley,et al.  Electrocatalytic reduction of carbon dioxide at illuminated p-type silicon semiconduccting electrodes , 1983 .

[20]  Anthony V. Cugini,et al.  CO2 attraction by specifically adsorbed anions and subsequent accelerated electrochemical reduction , 2010 .

[21]  Masahiro Watanabe,et al.  Design of alloy electrocatalysts for CO2 reduction: Improved energy efficiency, selectivity, and reaction rate for the CO2 electroreduction on Cu alloy electrodes , 1991 .

[22]  Journal of the Chemical Society , 1875, The British and Foreign Medico-Chirurgical Review.

[23]  Y. Hisaeda,et al.  The electroreduction of carbon dioxide by macrocyclic cobalt complexes chemically modified on a glassy carbon electrode , 1997 .

[24]  A. Bard,et al.  Electrochemical and Surface Studies of Carbon Dioxide Reduction to Methane and Ethylene at Copper Electrodes in Aqueous Solutions , 1989 .

[25]  H. Abruña,et al.  Electrocatalysis of CO2 Reduction in Aqueous Media at Electrodes Modified with Electropolymerized Films of Vinylterpyridine Complexes of Transition Metals , 1995 .

[26]  J. Sauvage,et al.  Electrocatalytic reduction of carbon dioxide by nickel cyclam2+ in water: study of the factors affecting the efficiency and the selectivity of the process. , 1986, Journal of the American Chemical Society.

[27]  Zhenshanl Li,et al.  Electrochemical reduction of carbon dioxide in an MFC-MEC system with a layer-by-layer self-assembly carbon nanotube/cobalt phthalocyanine modified electrode. , 2012, Environmental science & technology.

[28]  E. Carter,et al.  Theoretical insights into pyridinium-based photoelectrocatalytic reduction of CO2. , 2012, Journal of the American Chemical Society.

[29]  I. Nielsen,et al.  Cobalt-porphyrin catalyzed electrochemical reduction of carbon dioxide in water. 1. A density functional study of intermediates. , 2010, The journal of physical chemistry. A.

[30]  K. Schaber,et al.  Methanol from atmospheric carbon dioxide : A liquid zero emission fuel for the future , 1996 .

[31]  K. W. Frese,et al.  The electrochemical reduction of aqueous carbon dioxide to methanol at molybdenum electrodes with low overpotentials , 1986 .

[32]  A. Fujishima,et al.  Electrochemical reduction of carbon dioxide on hydrogenstoring materials. Part 1. The effect of hydrogen absorption on the electrochemical behavior on palladium electrodes , 1993 .

[33]  Emily Barton Cole,et al.  Using a one-electron shuttle for the multielectron reduction of CO2 to methanol: kinetic, mechanistic, and structural insights. , 2010, Journal of the American Chemical Society.

[34]  Andrew B. Bocarsly,et al.  A new homogeneous electrocatalyst for the reduction of carbon dioxide to methanol at low overpotential , 1994 .

[35]  Lin Zhao,et al.  Electrochemical reduction of CO2 in solid oxide electrolysis cells , 2010 .

[36]  S. Solomon,et al.  Irreversible climate change due to carbon dioxide emissions , 2009, Proceedings of the National Academy of Sciences.

[37]  Thomas F. Jaramillo,et al.  New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces , 2012 .

[38]  Y. Hori,et al.  Significant enhancement of the electrochemical reduction of CO2 at the kink sites on Pt(S)-[n(110)×(100)] and Pt(S)-[n(100)×(110)] , 1999 .

[39]  K. Ogura,et al.  Palladium and cobalt complexes of substituted quinoline, bipyridine and phenanthroline as catalysts for electrochemical reduction of carbon dioxide , 1997 .

[40]  A. Spek,et al.  Electrocatalytic CO2 Conversion to Oxalate by a Copper Complex , 2010, Science.

[41]  M. Kaneko,et al.  Factors affecting selective electrocatalytic co2 reduction with cobalt phthalocyanine incorporated in a polyvinylpyridine membrane coated on a graphite electrode , 1996 .

[42]  椿 範立,et al.  Methanol Synthesis , 2018, Catalyst Handbook.

[43]  H. Chandra,et al.  Application of solid oxide fuel cell technology for power generation—A review , 2013 .

[44]  M. Koper,et al.  Two pathways for the formation of ethylene in CO reduction on single-crystal copper electrodes. , 2012, Journal of the American Chemical Society.

[45]  Keiko Uemura,et al.  Photoelectrochemical reduction of CO(2) in water under visible-light irradiation by a p-type InP photocathode modified with an electropolymerized ruthenium complex. , 2010, Chemical communications.

[46]  Joseph Montoya,et al.  Insights into CC Coupling in CO2 Electroreduction on Copper Electrodes , 2013 .

[47]  D. Alwis,et al.  Cyclic voltammetry study of the electrocatalysis of carbon dioxide reduction by bis(polyazamacrocyclic) nickel complexes , 2000 .

[48]  Gyoichi Nogami,et al.  Pulsed Electroreduction of CO 2 on Copper Electrodes , 1993 .

[49]  Emily A. Carter,et al.  Electrochemical reactivities of pyridinium in solution: consequences for CO2 reduction mechanisms , 2013 .

[50]  C. Kubiak,et al.  Dinuclear Nickel Complexes as Catalysts for Electrochemical Reduction of Carbon Dioxide , 2005 .

[51]  S. R. Biaggio,et al.  Electrochemical reduction of CO2 mediated by poly-M-aminophthalocyanines (M = Co, Ni, Fe): poly-Co-tetraaminophthalocyanine, a selective catalyst , 2005 .

[52]  K. Ogura,et al.  Electrochemical Reduction of Carbon Dioxide on Dual‐Film Electrodes Modified With and Without Cobalt (II) and Iron (II) Complexes , 1994 .

[53]  Michele Aresta,et al.  The contribution of the utilization option to reducing the CO2 atmospheric loading: research needed to overcome existing barriers for a full exploitation of the potential of the CO2 use , 2004 .

[54]  M. Bradley,et al.  p-Type silicon based photoelectrochemical cells for optical energy conversion: Electrochemistry of tetra-azomacrocyclic metal complexes at illuminated , 1982 .

[55]  M. Specht,et al.  Comparison of the renewable transportation fuels, liquid hydrogen and methanol, with gasoline—Energetic and economic aspects , 1998 .

[56]  Aaron J. Sathrum,et al.  Electrocatalytic and homogeneous approaches to conversion of CO2 to liquid fuels. , 2009, Chemical Society reviews.

[57]  K. Sridhar,et al.  Study of carbon dioxide electrolysis at electrode/electrolyte interface: Part I. Pt/YSZ interface , 2004 .

[58]  John T. S. Irvine,et al.  Electrochemical reduction of CO2 in a proton conducting solid oxide electrolyser , 2011 .

[59]  Akira Murata,et al.  "Deactivation of copper electrode" in electrochemical reduction of CO2 , 2005 .

[60]  Victor S Batista,et al.  Functional Role of Pyridinium during Aqueous Electrochemical Reduction of CO2 on Pt(111). , 2013, The journal of physical chemistry letters.

[61]  Manfred Rudolph,et al.  Macrocyclic [N42-] Coordinated Nickel Complexes as Catalysts for the Formation of Oxalate by Electrochemical Reduction of Carbon Dioxide , 2000 .

[62]  W. Vielstich,et al.  Adsorbate formation during the electrochemical reduction of carbon dioxide at palladium—A DEMS study , 1996 .

[63]  Andrew A. Peterson,et al.  Structure effects on the energetics of the electrochemical reduction of CO2 by copper surfaces , 2011 .

[64]  John Aurie Dean,et al.  Lange's Handbook of Chemistry , 1978 .

[65]  Revocatus Lazaro Machunda,et al.  Electrocatalytic reduction of CO2 gas at Sn based gas diffusion electrode , 2011 .

[66]  Y. Hori,et al.  Electroreduction of carbon monoxide to methane and ethylene at a copper electrode in aqueous solutions at ambient temperature and pressure , 1987 .

[67]  M. Halmann,et al.  Photoelectrochemical reduction of carbon dioxide to formic acid, formaldehyde and methanol on p-gallium arsenide in an aqueous V(II)-V(III) chloride redox system , 1983 .

[68]  C. Huang,et al.  A solar cell driven electrochemical process for the concurrent reduction of carbon dioxide and degradation of azo dye in dilute KHCO3 electrolyte , 2013 .

[69]  Katsuhei Kikuchi,et al.  Production of CO and CH4 in electrochemical reduction of CO2 at metal electrodes in aqueous hydrogencarbonate solution. , 1985 .

[70]  H. Abruña,et al.  Electrocatalytic reduction of carbon dioxide mediated by transition metal complexes with terdentate ligands derived from diacetylpyridine , 2000 .

[71]  Ta-Jen Huang,et al.  Electrochemical CO2 reduction with power generation in SOFCs with Cu-added LSCF–GDC cathode , 2009 .

[72]  Jun Yi,et al.  CO2-reforming of methane on transition metal surfaces , 1998 .

[73]  Pierre Friedlingstein,et al.  Persistence of climate changes due to a range of greenhouse gases , 2010, Proceedings of the National Academy of Sciences.

[74]  J. Petit,et al.  Photoassisted electro-reduction of CO2 on p-GaAs in the presence of Ni cyclam2+ , 1986 .

[75]  M. Dry,et al.  The Fischer–Tropsch process: 1950–2000 , 2002 .

[76]  Malcolm L. H. Green,et al.  Partial oxidation of methane to synthesis gas using carbon dioxide , 1991, Nature.

[77]  A. Fujishima,et al.  Electrochemical reduction of carbon dioxide on hydrogen-storing materials.: Part II. Copper-modified palladium electrode , 1993 .

[78]  Uday B. Pal,et al.  Effect of oxygen-containing species on the impedance of the Pt/YSZ interface , 1997 .

[79]  E. Garcı́a-España,et al.  CO2 fixation by copper(II) complexes of a terpyridinophane aza receptor. , 2004, Journal of the American Chemical Society.

[80]  H. Inoue,et al.  Catalytic reduction of carbon dioxide with atomic hydrogen permeating through palladized Pd sheet electrodes , 1998 .

[81]  Y. Momose,et al.  Relationship between hydrocarbon production in the electrochemical reduction of CO2 and the characteristics of the Cu electrode , 1997 .

[82]  A. Anagnostopoulos,et al.  Electrochemical reduction of CO2 at Cu + Au electrodes , 1992 .

[83]  E. Garcı́a-España,et al.  CO2 Fixation and Activation by CuII Complexes of 5,5 -Terpyridinophane Macrocycles , 2008 .

[84]  Yoshio Hori,et al.  Structural effect on the rate of CO2 reduction on single crystal electrodes of palladium , 1997 .

[85]  Hongming Wang,et al.  Adsorption of CO2 on Cu2O (111) oxygen-vacancy surface: First-principles study , 2013 .

[86]  John T. S. Irvine,et al.  Efficient Reduction of CO2 in a Solid Oxide Electrolyzer , 2008 .

[87]  Anne C. Co,et al.  A review of the aqueous electrochemical reduction of CO2 to hydrocarbons at copper , 2006 .

[88]  Y. Hori,et al.  Electrochemical reduction of CO2 at copper single crystal Cu(S)-[n(111)×(111)] and Cu(S)-[n(110)×(100)] electrodes , 2002 .

[89]  M. Shibata,et al.  Simultaneous reduction of carbon dioxide and nitrate ions at gas-diffusion electrodes with various metallophthalocyanine catalysts , 2003 .

[90]  Y. Hori,et al.  Adsorption of CO accompanied with simultaneous charge transfer on copper single crystal electrodes related with electrochemical reduction of CO2 to hydrocarbons , 1995 .

[91]  Fatih Köleli,et al.  Reduction of CO2 under high pressure and high temperature on Pb-granule electrodes in a fixed-bed reactor in aqueous medium , 2004 .

[92]  Daniel L DuBois,et al.  Development of molecular electrocatalysts for CO2 reduction and H2 production/oxidation. , 2009, Accounts of chemical research.

[93]  C. Kubiak,et al.  Photoreduction of CO2 on p-type Silicon Using Re(bipy-But)(CO)3Cl: Photovoltages Exceeding 600 mV for the Selective Reduction of CO2 to CO , 2010 .

[94]  C. D. Keeling,et al.  Atmospheric CO2 and 13CO2 Exchange with the Terrestrial Biosphere and Oceans from 1978 to 2000: Observations and Carbon Cycle Implications , 2005 .

[95]  D. Lowy,et al.  Electrochemical reduction of carbon dioxide on flat metallic cathodes , 1997 .

[96]  Akira Murata,et al.  PRODUCTION OF METHANE AND ETHYLENE IN ELECTROCHEMICAL REDUCTION OF CARBON DIOXIDE AT COPPER ELECTRODE IN AQUEOUS HYDROGENCARBONATE SOLUTION , 1986 .

[97]  Toshio Tsukamoto,et al.  Electrocatalytic process of CO selectivity in electrochemical reduction of CO2 at metal electrodes in aqueous media , 1994 .

[98]  Antonino S. Aricò,et al.  Direct utilization of methanol in solid oxide fuel cells: An electrochemical and catalytic study , 2011 .

[99]  Kristian Sommer Thygesen,et al.  Electrochemical CO2 and CO reduction on metal-functionalized porphyrin-like graphene , 2013 .

[100]  J. Sauvage,et al.  Electrocatalytic properties of (tetraazacyclotetradecane)nickel(2+) and Ni2(biscyclam)4+ with respect to carbon dioxide and water reduction , 1988 .

[101]  Miss A.O. Penney.  (b) , 1974, The New Yale Book of Quotations.

[102]  Andrew A. Peterson,et al.  How copper catalyzes the electroreduction of carbon dioxide into hydrocarbon fuels , 2010 .

[103]  H. Abruña,et al.  Electrocatalytic reduction of CO2 and O2 with electropolymerized films of vinyl-terpyridine complexes of Fe, Ni and Co , 1994 .

[104]  C. Buess-Herman,et al.  Electroreduction of Carbon Dioxide on Copper-Based Electrodes: Activity of Copper Single Crystals and Copper–Gold Alloys , 2012, Electrocatalysis.

[105]  G. G. Stokes.  "J." , 1890, The New Yale Book of Quotations.

[106]  A. Sammells,et al.  Evidence for Formaldehyde, Formic Acid, and Acetaldehyde as Possible Intermediates during Electrochemical Carbon Dioxide Reduction at Copper , 1989 .

[107]  Bruce A. Parkinson,et al.  Photoelectrochemical pumping of enzymatic CO2 reduction , 1984, Nature.

[108]  P. Hirunsit.  Electroreduction of Carbon Dioxide to Methane on Copper, Copper–Silver, and Copper–Gold Catalysts: A DFT Study , 2013 .

[109]  H. Yano,et al.  Selective electrochemical reduction of CO2 to ethylene at a three-phase interface on copper(I) halide-confined Cu-mesh electrodes in acidic solutions of potassium halides , 2004 .

[110]  John B. Shoven,et al.  I , Edinburgh Medical and Surgical Journal.

[111]  N. Sai,et al.  Cobalt-porphyrin catalyzed electrochemical reduction of carbon dioxide in water. 2. Mechanism from first principles. , 2010, The journal of physical chemistry. A.

[112]  Héctor D. Abruña,et al.  Electrocatalysis of CO2 reduction at surface modified metallic and semiconducting electrodes , 1986 .

[113]  G. Wallace,et al.  Electrocatalytic Reduction of Carbon Dioxide by Cobalt-Phthalocyanine-Incorporated Polypyrrole , 2009 .

[114]  J. Popić,et al.  Reduction of carbon dioxide on ruthenium oxide and modified ruthenium oxide electrodes in 0.5 M NaHCO3 , 1997 .

[115]  K. Sridhar,et al.  Study of carbon dioxide electrolysis at electrode/electrolyte interface: Part II. Pt-YSZ cermet/YSZ interface , 2004 .

[116]  K. Hara,et al.  Electrochemical Reduction of CO 2 on a Cu Electrode under High Pressure Factors that Determine the Product Selectivity , 1994 .

[117]  David Archer,et al.  The millennial atmospheric lifetime of anthropogenic CO2 , 2008 .

[118]  Benjamin Erable,et al.  Electrochemical reduction of CO2 catalysed by Geobacter sulfurreducens grown on polarized stainless steel cathodes , 2013 .

[119]  K. Ogura,et al.  Electrocatalytic generation of C2 and C3 compounds from carbon dioxide on a cobalt complex-immobilized dual-film electrode , 1993 .

[120]  Y. Hori,et al.  Electrochemical reduction of carbon dioxide at various series of copper single crystal electrodes , 2003 .

[121]  Yongsug Tak,et al.  Electrocatalytic activity of Cu electrode in electroreduction of CO2 , 2001 .

[122]  Richard L. Kurtz,et al.  Electrochemical Reduction of CO2 to CH3OH at Copper Oxide Surfaces , 2011 .

[123]  Andrew A. Peterson,et al.  Activity Descriptors for CO2 Electroreduction to Methane on Transition-Metal Catalysts , 2012 .

[124]  Y. Hori,et al.  Formation of hydrocarbons in the electrochemical reduction of carbon dioxide at a copper electrode in aqueous solution , 1990 .

[125]  D. Dubois,et al.  Electrochemical Reduction of CO2 Catalyzed by a Dinuclear Palladium Complex Containing a Bridging Hexaphosphine Ligand: Evidence for Cooperativity , 1995 .

[126]  Matthew W Kanan,et al.  CO2 reduction at low overpotential on Cu electrodes resulting from the reduction of thick Cu2O films. , 2012, Journal of the American Chemical Society.

[127]  A. Fujishima,et al.  Electrochemical reduction of carbon dioxide on hydrogen-storing materials , 1994 .

[128]  Andrew B. Bocarsly,et al.  Selective solar-driven reduction of CO2 to methanol using a catalyzed p-GaP based photoelectrochemical cell. , 2008, Journal of the American Chemical Society.

[129]  D. Dubois,et al.  Electrochemical Reduction of CO2 to CO Catalyzed by a Bimetallic Palladium Complex , 2006 .

[130]  G. Prentice,et al.  Electrochemical synthesis of methanol from CO{sub 2} in high-pressure electrolyte , 1997 .

[131]  Xiaogang Zhang,et al.  Electrochemical reduction of CO2 on RuO2/TiO2 nanotubes composite modified Pt electrode , 2005 .

[132]  S. Ishimaru,et al.  Pulsed Electroreduction of CO 2 on Cu‐Ag Alloy Electrodes , 2000 .

[133]  Isao Taniguchi,et al.  Photoelectrochemical reduction of carbon dioxide using polyaniline-coated silicon , 1983 .

[134]  K. R. Sridhar,et al.  Oxygen Production on Mars Using Solid Oxide Electrolysis , 1995 .

[135]  K. Ogura,et al.  Reduction of CO2 to Ethylene at Three-Phase Interface Effects of Electrode Substrate and Catalytic Coating , 2005 .

[136]  Robert T McGibbon,et al.  Electrocatalytic carbon dioxide activation: the rate-determining step of pyridinium-catalyzed CO2 reduction. , 2011, ChemSusChem.

[137]  K. W. Frese,et al.  Electrochemical Reduction of CO 2 at Intentionally Oxidized Copper Electrodes , 1991 .

[138]  M. Okada,et al.  Isolation of Oxygen Formed during Catalytic Reduction of Carbon Dioxide Using a Solid Electrolyte Membrane , 1999 .

[139]  Suk-In Hong,et al.  Internal carbon dioxide reforming by methane over Ni-YSZ-CeO2 catalyst electrode in electrochemical cell , 2002 .

[140]  P. Strasser,et al.  Controlling Catalytic Selectivities during CO2 Electroreduction on Thin Cu Metal Overlayers , 2013 .