Thin layers of microwave absorbing metamaterials with carbon fibers and FeSi alloy ribbons to enhance the absorption properties

In order to break through the bottleneck of narrow effective absorption bandwidth (reflection loss RL ≤ −10 dB) of microwave absorbing materials, herein, we fabricate the metamaterials with carbon fiber (CF) and FeSi alloy (FSA) ribbon metastructure which is distributed in the carbonyl iron powders (CIP)/polyurethane (PU) matrix. The experimental results show that the microwave absorption capacity of the matrix can be significantly enhanced by CF. Compared with the pure matrix, the effective absorption bandwidth increases from 9.4–13.44 GHz to 11–16.8 GHz when the CF is parallel to the electric field vector and the spacing between adjacent CF is 20 mm. Furthermore, the CF and FSA ribbons are arranged in the matrix as an orthogonal arrangement, and the best absorption bandwidth cover 9.76–14.46 GHz when the electric field is parallel and 9.96–14.1GHz when the electric field is vertical when the spacing is 30 mm. The electromagnetic simulation of the metamaterials is calculated, it is proved that the increase of effective absorption bandwidth is due to the strengthening of carbon fiber and its coupling with FSA ribbon. This paper provides a new research path for improving the absorption properties of thin layer microwave absorbing materials.

[1]  R. Che,et al.  Novel broadband electromagnetic-wave absorption metasurfaces composed of C-doped FeCoNiSiAl high-entropy-alloy ribbons with hierarchical nanostructures , 2022, Composites Part B: Engineering.

[2]  R. Che,et al.  Chiral Asymmetric Polarizations Generated by Bioinspired Helical Carbon Fibers to Induce Broadband Microwave Absorption and Multispectral Photonic Manipulation , 2022, Advanced Optical Materials.

[3]  Run‐Wei Li,et al.  0D/1D/2D architectural Co@C/MXene composite for boosting microwave attenuation performance in 2–18 GHz , 2022, Carbon.

[4]  G. Qin,et al.  Quinary High‐Entropy‐Alloy@Graphite Nanocapsules with Tunable Interfacial Impedance Matching for Optimizing Microwave Absorption (Small 4/2022) , 2022, Small.

[5]  Guojia Ma,et al.  Broadband Microwave Absorption and Adaptable Multifunctionality of Carbonaceous Chiral Metamaterials under Deep Subwavelength Thickness , 2021, ACS Applied Electronic Materials.

[6]  G. Qin,et al.  Quinary High-Entropy-Alloy@Graphite Nanocapsules with Tunable Interfacial Impedance Matching for Optimizing Microwave Absorption. , 2021, Small.

[7]  Yuping Duan,et al.  Research advances in composition, structure and mechanisms of microwave absorbing materials , 2021 .

[8]  Wanchun Guo,et al.  Structure Engineering of Graphene Nanocages toward High‐Performance Microwave Absorption Applications , 2021, Advanced Optical Materials.

[9]  Xuefeng Zhang,et al.  Synthesizing CNx heterostructures on ferromagnetic nanoparticles for improving microwave absorption property , 2021 .

[10]  Run‐Wei Li,et al.  Dumbbell-Like Fe3O4@N-Doped Carbon@2H/1T-MoS2 with Tailored Magnetic and Dielectric Loss for Efficient Microwave Absorbing. , 2021, ACS applied materials & interfaces.

[11]  R. Che,et al.  Hollow Engineering to Co@N‐Doped Carbon Nanocages via Synergistic Protecting‐Etching Strategy for Ultrahigh Microwave Absorption , 2021, Advanced Functional Materials.

[12]  Guojia Ma,et al.  Bionic composite metamaterials for harvesting of microwave and integration of multifunctionality , 2021 .

[13]  K. Sista,et al.  Carbonyl iron powders as absorption material for microwave interference shielding: A review , 2021 .

[14]  Yi Huang,et al.  A Review on Metal–Organic Framework-Derived Porous Carbon-Based Novel Microwave Absorption Materials , 2021, Nano-Micro Letters.

[15]  Yuping Duan,et al.  Assembled Ag-doped α-MnO2@δ-MnO2 nanocomposites with minimum lattice mismatch for broadband microwave absorption , 2020 .

[16]  Guojia Ma,et al.  Bioinspired Gyrotropic Metamaterials with Multifarious Wave Adaptability and Multifunctionality , 2020, Advanced Optical Materials.

[17]  Guojia Ma,et al.  Ultra-flexible composite metamaterials with enhanced and tunable microwave absorption performance , 2019 .

[18]  Chuanhui Zhang,et al.  Laminated microwave absorbers of A-site cation deficiency perovskite La0.8FeO3 doped at hybrid RGO carbon , 2019, Composites Part B: Engineering.

[19]  Guojia Ma,et al.  Bioinspired Metamaterials: Multibands Electromagnetic Wave Adaptability and Hydrophobic Characteristics. , 2019, Small.

[20]  Yunhao Zhao,et al.  Boosted Interfacial Polarization from Multishell TiO2 @Fe3 O4 @PPy Heterojunction for Enhanced Microwave Absorption. , 2019, Small.

[21]  Zhichuan J. Xu,et al.  Biomass-Derived Porous Carbon-Based Nanostructures for Microwave Absorption , 2019, Nano-micro letters.

[22]  Namkyu Lee,et al.  Hierarchical Metamaterials for Multispectral Camouflage of Infrared and Microwaves , 2019, Advanced Functional Materials.

[23]  Wei Li,et al.  Broadband radar cross section reduction by in-plane integration of scattering metasurfaces and magnetic absorbing materials , 2019, Results in Physics.

[24]  Qingliang Liao,et al.  Toward the Application of High Frequency Electromagnetic Wave Absorption by Carbon Nanostructures , 2019, Advanced science.

[25]  Yazheng Yang,et al.  Weather-Manipulated Smart Broadband Electromagnetic Metamaterials. , 2018, ACS applied materials & interfaces.

[26]  Wei Li,et al.  Refractory Metamaterial Microwave Absorber with Strong Absorption Insensitive to Temperature , 2018, Advanced Optical Materials.

[27]  B. Wen,et al.  Thermally Driven Transport and Relaxation Switching Self-Powered Electromagnetic Energy Conversion. , 2018, Small.

[28]  B. Muneer,et al.  A Broadband Compatible Multispectral Metamaterial Absorber for Visible, Near‐Infrared, and Microwave Bands , 2018 .

[29]  Yazheng Yang,et al.  Constructing Repairable Meta-Structures of Ultra-Broad-Band Electromagnetic Absorption from Three-Dimensional Printed Patterned Shells. , 2017, ACS applied materials & interfaces.

[30]  Shaoyun Guo,et al.  Improved microwave absorbing property provided by the filler's alternating lamellar distribution of carbon nanotube/ carbonyl iron/ poly (vinyl chloride) composites , 2017 .

[31]  Jianguo Guan,et al.  Optically Transparent Broadband Microwave Absorption Metamaterial By Standing‐Up Closed‐Ring Resonators , 2017 .

[32]  T. Cui,et al.  Broadband metamaterial for optical transparency and microwave absorption , 2017 .

[33]  Hao Huang,et al.  Microwave absorption and flexural properties of Fe nanoparticle/carbon fiber/epoxy resin composite plates , 2015 .

[34]  Zhibin Yang,et al.  Cross‐Stacking Aligned Carbon‐Nanotube Films to Tune Microwave Absorption Frequencies and Increase Absorption Intensities , 2014, Advanced materials.

[35]  W. Cao,et al.  Enhanced microwave absorption property of reduced graphene oxide (RGO)-MnFe2O4 nanocomposites and polyvinylidene fluoride. , 2014, ACS applied materials & interfaces.

[36]  Young Jae Shin,et al.  Transparent and Flexible Polarization-Independent Microwave Broadband Absorber , 2014 .

[37]  Wancheng Zhou,et al.  Evolution of double magnetic resonance behavior and electromagnetic properties of flake carbonyl iron and multi-walled carbon nanotubes filled epoxy-silicone , 2014 .

[38]  Sailing He,et al.  Ultra-broadband microwave metamaterial absorber , 2011, 1201.0062.

[39]  K. Rozanov Ultimate thickness to bandwidth ratio of radar absorbers , 2000 .

[40]  Guoguo Tan,et al.  0D/1D/2D Architectural Co@C@MXene Composite for Boosting Microwave Attenuation Performance in 2-18 GHz , 2022, SSRN Electronic Journal.

[41]  Hao Huang,et al.  Enhanced microwave absorption by arrayed carbon fibers and gradient dispersion of Fe nanoparticles in epoxy resin composites , 2016 .

[42]  Zhu Dongmei,et al.  Graphene nanosheets/BaTiO3 ceramics as highly efficient electromagnetic interference shielding materials in the X-band , 2016 .

[43]  Walter J. Riker A Review of J , 2010 .