Fiber-shaped Supercapacitors: Advanced Strategies toward High-performances and Multi-functions

Fiber-shaped supercapacitors (FSSCs) show great potential in portable and wearable electronics due to their unique advantages of high safety, environmental friendliness, high performances, outstanding flexibility and integrability. They can directly act as the power sources or be easily integrated with other flexible devices to constitute self-powered and sustainable energy suppliers, providing excellent adaptability to irregular surfaces. This review mainly summarizes the recently reported works of FSSCs including preparation methods of various fiber electrodes, construction strategies of FSSCs and multi-functional device integrations, exploration of reaction mechanisms and strategies to improve the electrochemical performance and provision of suggestions on further designing and optimization of FSSCs. Meanwhile, it shares our perspectives on challenges and opportunities in this field, shedding light on the development of high-performance fiber-shaped supercapacitors with multi-functions.

[1]  Huisheng Peng,et al.  High-Performance Lithium-Air Battery with a Coaxial-Fiber Architecture. , 2016, Angewandte Chemie.

[2]  Li Zhang,et al.  High performance carbon nanotube based fiber-shaped supercapacitors using redox additives of polypyrrole and hydroquinone , 2015 .

[3]  Yuanyuan Li,et al.  Scalable Wire‐Type Asymmetric Pseudocapacitor Achieving High Volumetric Energy/Power Densities and Ultralong Cycling Stability of 100 000 Times , 2019, Advanced science.

[4]  S. Shi,et al.  A sodium perchlorate-based hybrid electrolyte with high salt-to-water molar ratio for safe 2.5 V carbon-based supercapacitor , 2019 .

[5]  Shing‐Jong Huang,et al.  Supplementary Information for , 2013 .

[6]  Chao Gao,et al.  Wet-spinning of ternary synergistic coaxial fibers for high performance yarn supercapacitors , 2017 .

[7]  R. Kötz,et al.  Hybridization of rechargeable batteries and electrochemical capacitors: Principles and limits , 2012 .

[8]  Chi-Chang Hu,et al.  Important parameters affecting the cell voltage of aqueous electrical double-layer capacitors , 2013 .

[9]  Jayan Thomas,et al.  Fiber‐Type Solar Cells, Nanogenerators, Batteries, and Supercapacitors for Wearable Applications , 2018, Advanced science.

[10]  Dong-Ha Kim,et al.  All-Transparent Stretchable Electrochromic Supercapacitor Wearable Patch Device. , 2019, ACS nano.

[11]  Xin Cai,et al.  Integrated power fiber for energy conversion and storage , 2013 .

[12]  C. Zhi,et al.  Magnetic-Assisted, Self-Healable, Yarn-Based Supercapacitor. , 2015, ACS nano.

[13]  Yongyao Xia,et al.  Electrochemical capacitors: mechanism, materials, systems, characterization and applications. , 2016, Chemical Society reviews.

[14]  Shanshan Qin,et al.  Hybrid Piezo/Triboelectric‐Driven Self‐Charging Electrochromic Supercapacitor Power Package , 2018, Advanced Energy Materials.

[15]  C. Berger,et al.  Ultrathin epitaxial graphite: 2D electron gas properties and a route toward graphene-based nanoelectronics. , 2004, cond-mat/0410240.

[16]  T. Someya,et al.  Organic Photodetectors for Next‐Generation Wearable Electronics , 2019, Advanced materials.

[17]  W. Ni,et al.  Omnidirectional porous fiber scrolls of polyaniline nanopillars array-N-doped carbon nanofibers for fiber-shaped supercapacitors , 2017 .

[18]  Evgueniy Entchev,et al.  Hybrid battery/supercapacitor energy storage system for the electric vehicles , 2018 .

[19]  Bin Li,et al.  A comprehensive review on self-healing of asphalt materials: Mechanism, model, characterization and enhancement. , 2018, Advances in colloid and interface science.

[20]  C. Cao,et al.  Microwave Assisted Synthesis of Porous NiCo2O4 Microspheres: Application as High Performance Asymmetric and Symmetric Supercapacitors with Large Areal Capacitance , 2016, Scientific Reports.

[21]  Bo Li,et al.  Twisted yarns for fiber-shaped supercapacitors based on wetspun PEDOT:PSS fibers from aqueous coagulation , 2016 .

[22]  Ray H. Baughman,et al.  Biomolecule based fiber supercapacitor for implantable device , 2018 .

[23]  Bin Wang,et al.  Highly-wrinkled reduced graphene oxide-conductive polymer fibers for flexible fiber-shaped and interdigital-designed supercapacitors , 2018 .

[24]  Aihua Liu,et al.  An integrated device of enzymatic biofuel cells and supercapacitor for both efficient electric energy conversion and storage , 2017 .

[25]  Hua Zhang,et al.  Self-assembly of well-ordered whisker-like manganese oxide arrays on carbon fiber paper and its application as electrode material for supercapacitors , 2012 .

[26]  Qiang Liu,et al.  2.2V high performance symmetrical fiber-shaped aqueous supercapacitors enabled by “water-in-salt” gel electrolyte and N-Doped graphene fiber , 2020 .

[27]  Nan Chen,et al.  Graphene-based fibers for supercapacitor applications , 2016, Nanotechnology.

[28]  R. Sun,et al.  Hierarchical nanothorns MnCo2O4 grown on porous/dense Ni bi-layers coated Cu wire current collectors for high performance flexible solid-state fiber supercapacitors , 2018 .

[29]  Zheng Liu,et al.  Flexible Sensing Electronics for Wearable/Attachable Health Monitoring. , 2017, Small.

[30]  W. Mai,et al.  A Flexible Microsupercapacitor with Integral Photocatalytic Fuel Cell for Self-Charging. , 2019, ACS nano.

[31]  Keith B. Oldham,et al.  Electrochemical Science and Technology: Fundamentals and Applications , 2011 .

[32]  Zhiyong Fan,et al.  Constructing optimized wire electrodes for fiber supercapacitors , 2014 .

[33]  Fei Zhao,et al.  Stretchable All‐Gel‐State Fiber‐Shaped Supercapacitors Enabled by Macromolecularly Interconnected 3D Graphene/Nanostructured Conductive Polymer Hydrogels , 2018, Advanced materials.

[34]  Kun Feng,et al.  All flexible electrospun papers based self-charging power system , 2017 .

[35]  G. Zou,et al.  Self‐Powered Wearable Electronics Based on Moisture Enabled Electricity Generation , 2018, Advanced materials.

[36]  J. Xue,et al.  Harmonizing Energy and Power Density toward 2.7 V Asymmetric Aqueous Supercapacitor , 2018 .

[37]  Jianli Cheng,et al.  A Fiber Supercapacitor with High Energy Density Based on Hollow Graphene/Conducting Polymer Fiber Electrode , 2016, Advanced materials.

[38]  Jing Zhang,et al.  Paper‐Based Electrodes for Flexible Energy Storage Devices , 2017, Advanced science.

[39]  S. Bianco,et al.  Self-assembly of graphene aerogel on copper wire for wearable fiber-shaped supercapacitors , 2016 .

[40]  Seungmin Hyun,et al.  Photoresponsive Smart Coloration Electrochromic Supercapacitor , 2017, Advanced materials.

[41]  Jianli Cheng,et al.  Flexible self-powered fiber-shaped photocapacitors with ultralong cyclelife and total energy efficiency of 5.1% , 2020 .

[42]  Zhibin Lei,et al.  Reduced graphene oxide/Mn3O4 nanocrystals hybrid fiber for flexible all-solid-state supercapacitor with excellent volumetric energy density , 2017 .

[43]  Huisheng Peng,et al.  An intercalated graphene/(molybdenum disulfide) hybrid fiber for capacitive energy storage , 2017 .

[44]  Q. Wang,et al.  Recent Advances in Design and Fabrication of Electrochemical Supercapacitors with High Energy Densities , 2014 .

[45]  Gengfeng Zheng,et al.  Nitrogen‐Doped Core‐Sheath Carbon Nanotube Array for Highly Stretchable Supercapacitor , 2017 .

[46]  Ke-Jing Huang,et al.  Layered MoS2–graphene composites for supercapacitor applications with enhanced capacitive performance , 2013 .

[47]  Bin Wang,et al.  Fiber-shaped solid-state supercapacitors based on molybdenum disulfide nanosheets for a self-powered photodetecting system , 2016 .

[48]  R. Baughman,et al.  Structural model for dry-drawing of sheets and yarns from carbon nanotube forests. , 2011, ACS nano.

[49]  Yang Zhao,et al.  Realizing both high energy and high power densities by twisting three carbon-nanotube-based hybrid fibers. , 2015, Angewandte Chemie.

[50]  Bowen Zhu,et al.  A Mechanically and Electrically Self‐Healing Supercapacitor , 2014, Advanced materials.

[51]  F. Wei,et al.  Carbon nanotube- and graphene-based nanomaterials and applications in high-voltage supercapacitor: A review , 2019, Carbon.

[52]  Ning Liu,et al.  Design of a Hierarchical Ternary Hybrid for a Fiber-Shaped Asymmetric Supercapacitor with High Volumetric Energy Density , 2016 .

[53]  A. Yu,et al.  All-in-One Graphene Based Composite Fiber: Toward Wearable Supercapacitor. , 2017, ACS applied materials & interfaces.

[54]  Chao Gao,et al.  Graphene fiber: a new trend in carbon fibers , 2015 .

[55]  Jianli Cheng,et al.  Interfacial Engineered Polyaniline/Sulfur-Doped TiO2 Nanotube Arrays for Ultralong Cycle Lifetime Fiber-Shaped, Solid-State Supercapacitors. , 2018, ACS applied materials & interfaces.

[56]  J. Savéant,et al.  How Do Pseudocapacitors Store Energy? Theoretical Analysis and Experimental Illustration. , 2017, ACS applied materials & interfaces.

[57]  Grzegorz Lota,et al.  Novel insight into neutral medium as electrolyte for high-voltage supercapacitors , 2012 .

[58]  Huisheng Peng,et al.  All-in-one fiber for stretchable fiber-shaped tandem supercapacitors , 2018 .

[59]  Junxiang Zhang,et al.  All-climate aqueous fiber-shaped supercapacitors with record areal energy density and high safety , 2018, Nano Energy.

[60]  Yang Zhao,et al.  Advances in Wearable Fiber‐Shaped Lithium‐Ion Batteries , 2016, Advanced materials.

[61]  G. Nie,et al.  High-Performance Asymmetric Electrochromic-Supercapacitor Device Based on Poly(indole-6-carboxylicacid)/TiO2 Nanocomposites. , 2019, ACS applied materials & interfaces.

[62]  Joselito M. Razal,et al.  Super-tough carbon-nanotube fibres , 2003, Nature.

[63]  Kai Jiang,et al.  Recent Advances in Flexible/Stretchable Supercapacitors for Wearable Electronics. , 2018, Small.

[64]  V. Presser,et al.  Carbons and Electrolytes for Advanced Supercapacitors , 2014, Advanced materials.

[65]  Fei Zhao,et al.  All-in-one graphene fiber supercapacitor. , 2014, Nanoscale.

[66]  Chao Gao,et al.  Wet-spinning of continuous montmorillonite-graphene fibers for fire-resistant lightweight conductors. , 2015, ACS nano.

[67]  Huisheng Peng,et al.  A highly stretchable, fiber-shaped supercapacitor. , 2013, Angewandte Chemie.

[68]  Huisheng Peng,et al.  Integrated Polymer Solar Cell and Electrochemical Supercapacitor in a Flexible and Stable Fiber Format , 2014, Advanced materials.

[69]  Huisheng Peng,et al.  Integration: An Effective Strategy to Develop Multifunctional Energy Storage Devices , 2016 .

[70]  Chao Gao,et al.  Coaxial wet-spun yarn supercapacitors for high-energy density and safe wearable electronics , 2014, Nature Communications.

[71]  J. Xue,et al.  Indole-based conjugated macromolecules as a redox-mediated electrolyte for an ultrahigh power supercapacitor , 2017 .

[72]  Zan Gao,et al.  Hierarchical NiCo2O4@NiO core–shell hetero-structured nanowire arrays on carbon cloth for a high-performance flexible all-solid-state electrochemical capacitor , 2014 .

[73]  Zhong Jin,et al.  MoS2‐Based All‐Purpose Fibrous Electrode and Self‐Powering Energy Fiber for Efficient Energy Harvesting and Storage , 2017 .

[74]  Songlin Xie,et al.  Biocompatible carbon nanotube fibers for implantable supercapacitors , 2017 .

[75]  Menghe Miao,et al.  High-performance two-ply yarn supercapacitors based on carbon nanotube yarns dotted with Co3 O4 and NiO nanoparticles. , 2015, Small.

[76]  Shengming Li,et al.  A Flexible Fiber-Based Supercapacitor-Triboelectric-Nanogenerator Power System for Wearable Electronics. , 2015, Advanced materials.

[77]  S. Iijima Helical microtubules of graphitic carbon , 1991, Nature.

[78]  Lai Xu,et al.  Constructing Ultrahigh-Capacity Zinc-Nickel-Cobalt Oxide@Ni(OH)2 Core-Shell Nanowire Arrays for High-Performance Coaxial Fiber-Shaped Asymmetric Supercapacitors. , 2017, Nano letters.

[79]  Zheng Liu,et al.  Wearable Electronics: Flexible Sensing Electronics for Wearable/Attachable Health Monitoring (Small 25/2017) , 2017 .

[80]  Jun Wei,et al.  Emergence of fiber supercapacitors. , 2015, Chemical Society reviews.

[81]  Maher F. El-Kady,et al.  Next‐Generation Activated Carbon Supercapacitors: A Simple Step in Electrode Processing Leads to Remarkable Gains in Energy Density , 2017 .

[82]  Husam N. Alshareef,et al.  All Pseudocapacitive MXene‐RuO2 Asymmetric Supercapacitors , 2018 .

[83]  Marina Mastragostino,et al.  New trends in electrochemical supercapacitors , 2001 .

[84]  Haowan Wu,et al.  A flexible spiral-type supercapacitor based on ZnCo2O4 nanorod electrodes. , 2015, Nanoscale.

[85]  V. Svetukhin,et al.  Influence of grain boundaries on the distribution of components in binary alloys , 2017 .

[86]  Shanyi Du,et al.  Self-stretchable, helical carbon nanotube yarn supercapacitors with stable performance under extreme deformation conditions , 2015 .

[87]  Hongxing Yang,et al.  Development of hybrid battery-supercapacitor energy storage for remote area renewable energy systems , 2015 .

[88]  P. Ajayan,et al.  High temperature electrical energy storage: advances, challenges, and frontiers. , 2016, Chemical Society reviews.

[89]  Faxing Wang,et al.  Latest advances in supercapacitors: from new electrode materials to novel device designs. , 2017, Chemical Society reviews.

[90]  Y. Gogotsi,et al.  Materials for electrochemical capacitors. , 2008, Nature materials.

[91]  Lei Zhang,et al.  Assembly of NiO/Ni(OH)2/PEDOT Nanocomposites on Contra Wires for Fiber-Shaped Flexible Asymmetric Supercapacitors. , 2016, ACS applied materials & interfaces.

[92]  Huisheng Peng Fiber-Shaped Energy Harvesting and Storage Devices , 2015 .

[93]  R. Kühnel,et al.  High-voltage aqueous supercapacitors based on NaTFSI , 2017 .

[94]  H. Erbil,et al.  Wet-spun graphene filaments: effect of temperature of coagulation bath and type of reducing agents on mechanical & electrical properties , 2018, RSC advances.

[95]  Xiaoxiao Liu,et al.  Flexible fiber-shaped supercapacitors based on hierarchically nanostructured composite electrodes , 2015, Nano Research.

[96]  Minghao Yu,et al.  New Insights into the Operating Voltage of Aqueous Supercapacitors. , 2018, Chemistry.

[97]  Qinmin Pan,et al.  Self-Healable and Cold-Resistant Supercapacitor Based on a Multifunctional Hydrogel Electrolyte. , 2017, ACS applied materials & interfaces.

[98]  X. Tao,et al.  A high performance fiber-shaped PEDOT@MnO2//C@Fe3O4 asymmetric supercapacitor for wearable electronics , 2016 .

[99]  Yang Zhao,et al.  A Shape-Memory Supercapacitor Fiber. , 2015, Angewandte Chemie.

[100]  Genevieve Dion,et al.  Textile energy storage in perspective , 2014 .

[101]  N. Wang,et al.  A self-entanglement mechanism for continuous pulling of carbon nanotube yarns , 2011 .

[102]  Zhengguang Zou,et al.  Highly Stretchable and Self-Healable Supercapacitor with Reduced Graphene Oxide Based Fiber Springs. , 2017, ACS nano.

[103]  Yingjun Liu,et al.  MXene/graphene hybrid fibers for high performance flexible supercapacitors , 2017 .

[104]  S. Saxena,et al.  Surface enhanced 3D rGO hybrids and porous rGO nano-networks as high performance supercapacitor electrodes for integrated energy storage devices , 2020 .

[105]  Mingjie Li,et al.  Photo-responsive heterojunction nanosheets of reduced graphene oxide for photo-detective flexible energy devices , 2019, Journal of Materials Chemistry A.

[106]  M. Miao,et al.  Two-ply yarn supercapacitor based on carbon nanotube/stainless steel core-sheath yarn electrodes and ionic liquid electrolyte , 2016 .