Study of the 14C-Contamination Potential of C-Impurities in CuO and Fe

The carbon concentration in CuO and iron was determined by isolating C. The values were in agreement with results reported in other studies. Contaminating carbon from CuO and Fe was transformed to AMS targets and measured for 14C. C-traces in CuO were shown to be the major contribution to the 14C sample processing blank. In addition, there is a significant variability in the 14C content of CuO observed between different production batches. The combined contamination potential of CuO and Fe was found to be 4.47–8.92 μg recent carbon, whereas the more realistic estimate for AMS-target preparation conditions ranged between 1.63 and 3.24 μg recent carbon, depending on the 14C level in CuO.

[1]  K. Vandeputte,et al.  Deuteron activation analysis for the determination of carbon in iron and copper oxide, reagents for14C-dating by accelerator mass spectrometry , 1997 .

[2]  J. Plicht,et al.  AMS sample handling in Groningen , 1997 .

[3]  D. Klinedinst,et al.  Iron-Manganese System for Preparation of Radiocarbon Ams Targets: Characterization of Procedural Chemical-Isotopic Blanks and Fractionation , 1997, Radiocarbon.

[4]  W. Phillips,et al.  Studies of the production rate of cosmic-ray produced 14C in rock surfaces , 1994 .

[5]  L. A. Currie,et al.  Fossil- and bio-mass combustion: C-14 for source identification, chemical tracer development, and model validation☆ , 1994 .

[6]  L. A. Currie,et al.  Comparative study of Fe-C bead and graphite target performance with the National Ocean Science AMS (NOSAMS) facility recombinator ion source , 1994 .

[7]  R. Beukens Radiocarbon accelerator mass spectrometry: background and contamination , 1993 .

[8]  M. S. Thomsen,et al.  Examination of Background Contamination Levels for Gas Counting and AMS Target Preparation in Trondheim , 1992, Radiocarbon.

[9]  T. Boutton 10 – Stable Carbon Isotope Ratios of Natural Materials: I. Sample Preparation and Mass Spectrometric Analysis , 1991 .

[10]  D. Donahue,et al.  Radiocarbon measurements at the University of Arizona AMS facility , 1990 .

[11]  R. Hedges,et al.  THE OXFORD ACCELERATOR MASS SPECTROMETRY FACILITY: TECHNICAL DEVELOPMENTS IN ROUTINE DATING , 1989 .

[12]  J. Duplessy,et al.  14C Dating with the Gif-sur-Yvette Tandetron Accelerator: Status Report and Study of Isotopic Fractionation in the Sputter Ion Source , 1987, Radiocarbon.

[13]  L. A. Currie,et al.  preparation of microgram samples on iron wool for radiocarbon analysis via accelerator mass spectrometry: A closed-system approach , 1987 .

[14]  J. Southon,et al.  14C Background Levels in An Accelerator Mass Spectrometry System , 1987, Radiocarbon.

[15]  D. Gurfinkel An Assessment of Laboratory Contamination at the Isotrace Radiocarbon Facility , 1987, Radiocarbon.

[16]  J. Southon,et al.  Performance of catalytically condensed carbon for use in accelerator mass spectrometry , 1984 .

[17]  R. Gillespie,et al.  Sample preparation for accelerator-based radiocarbon dating , 1984 .

[18]  T. B. Pierce Charged-particle activation analysis , 1972 .