Anisotropic Thermal Diffusivity and Conductivity of La‐Doped Strontium Niobate Sr2Nb2O7

The thermal diffusivity of the La-doped layered perovskite Sr2Nb2O7 parallel and perpendicular to the perovskite layers is reported from room temperature up to 1000°C. The anisotropy persists through an incommensurate-normal ferroelectric phase transformation at 215°C and up to 1000°C, the maximum temperature of our measurements. The thermal conductivity perpendicular to the perovskite layers, derived from the diffusivity in the same direction, calculated using the density and measured heat capacity, has a constant value of 1.05±0.05 W/mK up to 1000°C. Possible explanations for the low thermal conductivity and anisotropy are described.

[1]  P. Klemens The Scattering of Low-Frequency Lattice Waves by Static Imperfections , 1955 .

[2]  C. Kittel,et al.  Interpretation of the Thermal Conductivity of Glasses , 1949 .

[3]  J. Bednorz,et al.  A Novel Semiconducting Perovskite-Related Phase: Sr5Nb5O17. , 1995 .

[4]  David R. Clarke,et al.  Stress Measurement in Single‐Crystal and Polycrystalline Ceramics Using Their Optical Fluorescence , 1993 .

[5]  J. Bednorz,et al.  Layered Perovskitic Structures in Pure and Doped LaTiO3.5-x and SrNbO3.5-x , 1993 .

[6]  David R. Clarke,et al.  Materials selection guidelines for low thermal conductivity thermal barrier coatings , 2003 .

[7]  M. Kaviany,et al.  Publisher's note: Ab initio and molecular dynamics predictions for electron and phonon transport in bismuth telluride (Physical Review D - Condensed Matter and Materials Physics (2008) 77, (125209)) , 2008 .

[8]  D. Clarke,et al.  Transformation of Electron‐Beam Physical Vapor‐Deposited 8 wt% Yttria‐Stabilized Zirconia Thermal Barrier Coatings , 2005 .

[9]  Taylor D. Sparks,et al.  Thermal Conductivity of the Rare-Earth Strontium Aluminates , 2010 .

[10]  S. Kojima,et al.  Successive Phase Transitions and Their Soft Modes in Ferroelectric Sr2Nb2O7 , 1985 .

[11]  S. N. Ruddlesden,et al.  On the crystal structure of the nitrides of silicon and germanium , 1958 .

[12]  Joseph Callaway,et al.  Effect of Point Imperfections on Lattice Thermal Conductivity , 1960 .

[13]  石沢 伸夫,et al.  La 2 Ti 2 O 7 強誘電体の相転移に伴う構造変化 , 1978 .

[14]  D. Cahill,et al.  Ultra-Low Thermal Conductivity in W/Al2O3 Nanolaminates , 2004, Science.

[15]  A. B. Thakker,et al.  Thermal Barrier Coatings for Jet Engines , 1988 .

[16]  N. Yamamoto High-resolution electron microscopy of the incommensurate structure in Sr2Nb2O2 , 1981 .

[17]  Joshua A. Kurzman,et al.  Probing Octahedral Tilting in Dion-Jacobson Layered Perovskites With Neutron Powder Diffraction and Raman Spectroscopy , 2006 .

[18]  F. Lotgering,et al.  Topotactical reactions with ferrimagnetic oxides having hexagonal crystal structures—I , 1959 .

[19]  P. Günter,et al.  Centrosymmetric or Noncentrosymmetric? Case Study, Generalization and Structural Redetermination of Sr5Nb5O17 , 1998 .

[20]  R. Newnham,et al.  La[sub 2]Ti[sub 2]O[sub 7] ceramics , 1991 .

[21]  S. Trolier-McKinstry,et al.  Densification and anisotropic grain growth in Sr2Nb2O7 , 2000 .

[22]  W. Kingery,et al.  Thermal Conductivity: XII, Temperature Dependence of Conductivity for Single-Phase Ceramics , 1955 .

[23]  Baoling Huang,et al.  Ab initio and molecular dynamics predictions for electron and phonon transport in bismuth telluride , 2008 .

[24]  D. Clarke,et al.  A numerical solution based parameter estimation method for flash thermal diffusivity measurements , 2009 .

[25]  S. Kojima,et al.  Acoustic and thermal properties of strontium pyroniobate single crystals , 2003 .

[26]  S. N. Ruddlesden,et al.  New compounds of the K2NIF4 type , 1957 .

[27]  Fujio Izumi,et al.  VESTA: a three-dimensional visualization system for electronic and structural analysis , 2008 .

[28]  M. Dressel,et al.  The incommensurate modulation of the structure of Sr2Nb2O7. , 2002, Acta crystallographica. Section B, Structural science.

[29]  David R. Clarke,et al.  Anisotropic thermal conductivity of the Aurivillus phase, bismuth titanate (Bi4Ti3O12): A natural nanostructured superlattice , 2008 .

[30]  D. Clarke,et al.  Factors affecting the fracture resistance of silicon nitride ceramics , 1995 .

[31]  R. Withers,et al.  Intergrowth polytypoids as modulated structures: a superspace description of the Sr(n)(Nb,Ti)(n)O(3n + 2) compound series. , 2001, Acta crystallographica. Section B, Structural science.

[32]  T. Kawamura,et al.  The crystal structure of Sr2Nb2O7, a compound with perovskite-type slabs , 1975 .

[33]  R. Taylor,et al.  Radiation loss in the flash method for thermal diffusivity , 1975 .