Measurement and Correlation of High Pressure Phase Equilibria for CO2 + Alkanes and CO2 + Crude Oil Systems

An analytical apparatus with improved recirculating and sampling mechanisms was presented to investigate phase behavior of binary and multicomponent systems, which effectively avoided undesirable pressure gradients across the cell and serious disturbance of equilibrium during sampling procedure. Two one-channel magnetic recirculation pumps were designed and built to provide better mass transfer between the coexisting phases. Two six-port switching valves were used for sampling, quantitative fluid injection, and online compositional analysis by gas chromatography. The apparatus was validated by means of isothermal vapor–liquid equilibrium data for CO2 + hexane, and the results were found to be in good agreement with the literature data. High pressure phase equilibria data of CO2 + n-alkanes and CO2 + crude oil + n-alkanes were measured from 353.15 to 373.15 K. Three thermodynamic models of RR, PRSV, and YQE, based on Peng–Robinson and a modified quartic equation of state coupled with various mixing rules, ...

[1]  Martina Ziefle,et al.  Reduce, reuse, recycle: Acceptance of CO2-utilization for plastic products , 2017 .

[2]  J. Abedi,et al.  Solubility and thermo-physical properties measurement of CO2- and N2-Athabasca bitumen systems , 2017 .

[3]  A. Firoozabadi,et al.  New Three-Phase Multicomponent Compositional Model for Asphaltene Precipitation during CO2 Injection Using CPA-EOS , 2016 .

[4]  C. R. Jones,et al.  Investigating public perceptions of carbon dioxide utilisation (CDU) technology: a mixed methods study. , 2015, Faraday discussions.

[5]  Haibo Zhai,et al.  Opportunities for Decarbonizing Existing U.S. Coal-Fired Power Plants via CO2 Capture, Utilization and Storage. , 2015, Environmental science & technology.

[6]  Adisa Azapagic,et al.  Carbon dioxide utilisation for production of transport fuels: process and economic analysis , 2015 .

[7]  Zhi Yun,et al.  Fast Determination of Binary Vapor–Liquid Equilibrium of CO2-Based Mixtures at Elevated Pressures , 2015 .

[8]  M. Rahimi,et al.  Prediction of Vapor-Liquid Equilibrium of Polypropylene Oxide Solution Systems by Cubic Equations of State , 2014 .

[9]  A. Bardow,et al.  Life cycle assessment of polyols for polyurethane production using CO2 as feedstock: insights from an industrial case study , 2014 .

[10]  J. Trusler,et al.  Experimental and modeling study of the phase behavior of synthetic crude oil+CO2 , 2014 .

[11]  Zhi Yun,et al.  Vapor–Liquid Phase Equilibrium Data of CO2 in Some Physical Solvents from 285.19 K to 313.26 K , 2014 .

[12]  F. Torabi,et al.  Performance of Secondary Carbonated Water Injection in Light Oil Systems , 2014 .

[13]  A. Abedini,et al.  Parametric Study of the Cyclic CO2 Injection Process in Light Oil Systems , 2013 .

[14]  Stephen Widdicombe,et al.  Assessing the environmental consequences of CO2 leakage from geological CCS: generating evidence to support environmental risk assessment. , 2013, Marine pollution bulletin.

[15]  C. Leibovici,et al.  Reliability of the correlation allowing the kij to switch from an alpha function to another one in hydrogen-containing systems , 2013 .

[16]  R. Privat,et al.  Validation of a new apparatus using the dynamic method for determining the critical properties of binary mixtures containing CO2 and a n-alkane , 2012 .

[17]  Wilhelm Kuckshinrichs,et al.  Worldwide innovations in the development of carbon capture technologies and the utilization of CO2 , 2012 .

[18]  M. Cismondi,et al.  Phase Equilibria of CO2 + n-Alkane Binary Systems in Wide Ranges of Conditions: Development of Predictive Correlations Based on Cubic Mixing Rules , 2012 .

[19]  Amparo Galindo,et al.  Experimental and molecular modeling study of the three-phase behavior of (n-decane + carbon dioxide + water) at reservoir conditions. , 2011, The journal of physical chemistry. B.

[20]  L. A. Galicia-Luna,et al.  Vapor–Liquid Equilibria of Binary and Ternary Systems Containing Carbon Dioxide, Alkane, and Benzothiophene , 2011 .

[21]  Weiyang Fei,et al.  Solubility of CO2 in Alcohols, Glycols, Ethers, and Ketones at High Pressures from (288.15 to 318.15) K , 2011 .

[22]  Nilay Shah,et al.  An overview of CO2 capture technologies , 2010 .

[23]  Jean-Noël Jaubert,et al.  Relationship between the binary interaction parameters (kij) of the Peng–Robinson and those of the Soave–Redlich–Kwong equations of state: Application to the definition of the PR2SRK model , 2010 .

[24]  D. Geanǎ,et al.  Phase Behavior for the Carbon Dioxide + N-Pentadecane Binary System † , 2010 .

[25]  Zhigang Tang,et al.  CO2 Capture with Physical Solvent Dimethyl Carbonate at High Pressures , 2010 .

[26]  Malcolm Greaves,et al.  A review of novel techniques for heavy oil and bitumen extraction and upgrading , 2010 .

[27]  A. J. Hunt,et al.  Generation, capture, and utilization of industrial carbon dioxide. , 2010, ChemSusChem.

[28]  R. Dohrn,et al.  High-pressure fluid-phase equilibria: Experimental methods and systems investigated (2000–2004) , 2010 .

[29]  Juan G. Beltran,et al.  Equilibrium Studies for the System Methane + Carbon Dioxide + Neohexane + Water , 2008 .

[30]  J. Daridon,et al.  High-pressure phase behaviour of the binary system {CO2 + cis-decalin} from (292.75 to 373.75) K , 2008 .

[31]  Ho-mu Lin,et al.  Vapor–liquid phase equilibrium behavior of mixtures containing supercritical carbon dioxide near critical region , 2008 .

[32]  J. Daridon,et al.  Phase equilibria measurements of CO2 + methyl cyclopentane and CO2 + isopropyl cyclohexane binary mixtures at elevated pressures , 2008 .

[33]  L. A. Galicia-Luna,et al.  New isothermal vapor–liquid equilibria for the CO2 + n-nonane, and CO2 + n-undecane systems , 2007 .

[34]  J. Daridon,et al.  Bubble and Dew Points of Carbon Dioxide + a Five-Component Synthetic Mixture: Experimental Data and Modeling with the PPR78 Model , 2007 .

[35]  Jinglin Yu,et al.  Experimental determination and calculation of thermodynamic properties of CO2 + octane to high temperatures and high pressures , 2006 .

[36]  Octavio Elizalde-Solis,et al.  Experimental Vapor−Liquid Equilibria for the Carbon Dioxide + Octane and Carbon Dioxide + Decane Systems , 2006 .

[37]  Xiao-Sen Li,et al.  Investigation of vapor-liquid equilibria for supercritical carbon dioxide and hydrocarbon mixtures by perturbed-chain statistical associating fluid theory , 2006 .

[38]  I. Velasco,et al.  Dew Points of Binary Propane or n-butane + Carbon Dioxide, Ternary Propane or n-butane + Carbon Dioxide + Water, and Quaternary Propane or n-butane + Carbon Dioxide + Water + Methanol Mixtures: Measurement and Modeling , 2006 .

[39]  Jean-Noël Jaubert,et al.  Extension of the PPR78 model (Predictive 1978, Peng-Robinson EOS with temperature dependent kij calculated through a group contribution method) to systems containing naphtenic compounds , 2005 .

[40]  D. El-Hadi,et al.  Improved empirical correlation for petroleum fraction composition quantitative prediction , 2005 .

[41]  Weiyang Fei,et al.  Solubility of Carbon Dioxide in Four Mixed Solvents , 2005 .

[42]  Jean-Noël Jaubert,et al.  VLE predictions with the Peng–Robinson equation of state and temperature dependent kij calculated through a group contribution method , 2004 .

[43]  Ralf Dohrn,et al.  High-pressure fluid phase equilibria , 2002 .

[44]  Huen Lee,et al.  A new quartic equation of state , 2001 .

[45]  Rafael Eustaquio-Rincón,et al.  Solubility of n-octadecane in supercritical carbon dioxide at 310, 313, 333, and 353 K, in the range 10–20 MPa , 2001 .

[46]  Ji-Ho Yoon,et al.  Hydrate Phase Equilibria of the Carbon Dioxide, Methane, and Water System , 2001 .

[47]  Mohammad R. Riazi,et al.  Physical properties of heavy petroleum fractions and crude oils , 1996 .

[48]  Ralf Dohrn,et al.  High-pressure fluid-phase equilibria: Experimental methods and systems investigated (1988–1993) , 1995 .

[49]  Rafiqul Gani,et al.  Estimation of the acentric factor and the liquid molar volume at 298 K using a new group contribution method , 1995 .

[50]  R. Gani,et al.  New group contribution method for estimating properties of pure compounds , 1994 .

[51]  G. Brunner,et al.  Phase equilibria in systems containing hydrogen, carbon dioxide, water and hydrocarbons , 1994 .

[52]  D. Tassios,et al.  Prediction of vapor-liquid equilibrium with the LCVM model: a linear combination of the Vidal and Michelsen mixing rules coupled with the original UNIF , 1994 .

[53]  Jean-Noël Jaubert,et al.  Characterization of heavy oils , 1993 .

[54]  A. Teja,et al.  High pressure phase equilibria in the carbon dioxide-n-hexadecane and carbon dioxide-water systems , 1988 .

[55]  R. Reid,et al.  Multiphase high pressure equilibria in ternary aqueous systems , 1986 .

[56]  R. Stryjek,et al.  “PRSV — An improved peng‐robinson equation of state with new mixing rules for strongly nonideal mixtures” , 1986 .

[57]  R. Stryjek,et al.  PRSV: An improved peng—Robinson equation of state for pure compounds and mixtures , 1986 .

[58]  Ho-mu Lin,et al.  Cubic chain-of-rotators equation of state , 1986 .

[59]  Mohammad R. Riazi,et al.  Prediction of the Composition of Petroleum Fractions , 1980 .

[60]  A. Kane.  Performance Review of a Large-Scale CO2-WAG Enhanced Recovery Project, SACROC Unit Kelly-Snyder Field , 1979 .

[61]  D. Peng,et al.  A New Two-Constant Equation of State , 1976 .

[62]  G. Soave.  Equilibrium constants from a modified Redlich-Kwong equation of state , 1972 .

[63]  A. Abedini,et al.  Phase Behaviour of CO2–Brine and CO2–Oil Systems for CO2 Storage and Enhanced Oil Recovery: Experimental Studies , 2014 .

[64]  Qi Li,et al.  A Survey of Public Perception of CCUS in China , 2014 .

[65]  G. D. Holder,et al.  Phase Equilibrium in Two-Phase, Water-Rich-Liquid, Hydrate Systems: Experiment and Theory , 2008 .

[66]  Rafael Sandrea,et al.  Recovery factors leave vast target for EOR technologies , 2007 .

[67]  Ireneo Kikic,et al.  High pressure fluid phase equilibria : experimental methods and systems investigated (1978-1987) , 1990 .

[68]  G. Soave.  Improvement of the Van Der Waals equation of state , 1984 .

[69]  Amyn S. Teja,et al.  A NEW CUBIC EQUATION OF STATE FOR FLUIDS AND FLUID MIXTURES , 1982 .

[70]  R. Robinson,et al.  Vapor-liquid phase equilibrium for carbon dioxide-n-hexane at 40, 80, and 120 .degree.C , 1981 .

[71]  Takashi Katayama,et al.  Isothermal Vapor-Liquid Equilibrium Data for Binary Systems Containing Carbon Dioxide at High Pressures: Methanol-Carbon Dioxide, n-Hexane-Carbon Dioxide, and Benzene-Carbon Dioxide Systems , 1976 .