Battery Wear from Disparate Duty-Cycles: Opportunities for Electric-Drive Vehicle Battery Health Management

Electric-drive vehicles utilizing lithium-ion batteries experience wholly different degradation patterns than do conventional vehicles, depending on geographic ambient conditions and consumer driving and charging patterns. A semi-empirical life-predictive model for the lithium-ion graphite/nickel-cobalt-aluminum chemistry is presented that accounts for physically justified calendar and cycling fade mechanisms. An analysis of battery life for plug-in hybrid electric vehicles considers 782 duty-cycles from travel survey data superimposed with climate data from multiple geographic locations around the United States. Based on predicted wear distributions, opportunities for extending battery life including modification of battery operating limits, thermal and charge control are discussed.

[1]  Ralph E. White,et al.  Parameter Estimation and Life Modeling of Lithium-Ion Cells , 2008 .

[2]  R. Spotnitz Simulation of capacity fade in lithium-ion batteries , 2003 .

[3]  Thomas H. Bradley,et al.  Investigation of battery end-of-life conditions for plug-in hybrid electric vehicles , 2011 .

[4]  K. B. Chin,et al.  Storage Characteristics of Li-Ion Batteries for NASA's Missions , 2004 .

[5]  Tony Markel,et al.  Simulated fuel economy and performance of advanced hybrid electric and plug-in hybrid electric vehicles using in-use travel profiles , 2010, 2010 IEEE Vehicle Power and Propulsion Conference.

[6]  John C. Hall,et al.  Decay Processes and Life Predictions for Lithium Ion Satellite Cells , 2006 .

[7]  Eric Wood,et al.  Comparison of Plug-In Hybrid Electric Vehicle Battery Life Across Geographies and Drive Cycles , 2012 .

[8]  M. Verbrugge,et al.  Cycle-life model for graphite-LiFePO 4 cells , 2011 .

[9]  M. Safari,et al.  Multimodal Physics-Based Aging Model for Life Prediction of Li-Ion Batteries , 2009 .

[10]  J. Apt,et al.  Lithium-ion battery cell degradation resulting from realistic vehicle and vehicle-to-grid utilization , 2010 .

[11]  Ralph E. White,et al.  Solvent Diffusion Model for Aging of Lithium-Ion Battery Cells , 2004 .

[12]  Tony Markel,et al.  PHEV Battery Trade-Off Study and Standby Thermal Control (Presentation) , 2009 .

[13]  Mark W. Verbrugge,et al.  Stress and Strain-Energy Distributions within Diffusion-Controlled Insertion-Electrode Particles Subjected to Periodic Potential Excitations , 2009 .

[14]  Jeremy Neubauer,et al.  Variability of Battery Wear in Light Duty Plug-In Electric Vehicles Subject to Ambient Temperature, Battery Size, and Consumer Usage: Preprint , 2012 .