2,5-Bis{2,2-bis[4-(dimethylamino)phenyl]ethenyl}-N,N′-diphenyl-N,N′-dipropylbenzene-1,4-diamine

The title compound, C60H68N6, was prepared by Horner olefination of a terephthaldialdehyde and a diarylmethyl phosphonate. There is one half-molecule, located on an inversion centre, in the asymmetric unit. The dihedral angle between the plane of the vinylene unit and the central ring is 36.79 (15)°, while those between the vinylene unit and the lateral phenyl rings are 53.04 (10) and 53.74 (9)°.

[1]  U. Stalmach,et al.  Acidochromism of the luminescence of bis(4-pyridylethenyl)arenes , 2004 .

[2]  G. Hadziioannou,et al.  MOLECULAR PACKING IN UNSUBSTITUTED SEMICONDUCTING PHENYLENEVINYLENE OLIGOMER AND POLYMER , 1999 .

[3]  N. A. Nemkovich,et al.  Localized excitation effect on dipole moments of oligophenylenevinylenes in their excited Franck–Condon state , 2010 .

[4]  James N. Wilson,et al.  Switching of intramolecular charge transfer in cruciforms: metal ion sensing. , 2005, Journal of the American Chemical Society.

[5]  Juan Tolosa,et al.  Bis(4'-dibutylaminostyryl)benzene: spectroscopic behavior upon protonation or methylation. , 2009, Chemistry.

[6]  E. Sugiono,et al.  Bis(pyridylvinyl)diaminobenzenes: synthesis, acidochromism and solvatochromism of the fluorescence , 2005 .

[7]  Anthony L. Spek,et al.  Structure validation in chemical crystallography , 2009, Acta crystallographica. Section D, Biological crystallography.

[8]  G. Drefahl,et al.  Untersuchungen über Stilbene, XXXIX. Die Wittig‐Reaktion mit p‐Halogenmethyl‐benzaldehyd , 1961 .

[9]  S. Barlow,et al.  A convenient method for the synthesis of electron-rich phosphonates , 2003 .

[10]  G. Gattow,et al.  Kristallographische Computer-Programme für die CDC-3300. , 1971 .

[11]  良二 上田.  J. Appl. Cryst.の発刊に際して , 1970 .

[12]  G. Sheldrick.  A short history of SHELX. , 2008, Acta crystallographica. Section A, Foundations of crystallography.

[13]  Maria Cristina Burla,et al.  SIR97: a new tool for crystal structure determination and refinement , 1999 .

[14]  B. Strehmel,et al.  The Influence of σ and π Acceptors on Two‐Photon Absorption and Solvatochromism of Dipolar and Quadrupolar Unsaturated Organic Compounds , 2003 .