Air quality measurements from the Southern Particulate Matter Supersite in Taiwan

This study introduces the Southern Particulate Matter Supersite in Taiwan, which began operating on April 1, 2005. The supersite has one core station and three satellite stations for monitoring the properties of particulate matter (PM) and emission sources in southern Taiwan. High-time resolution (1–30 minutes) data for physical and chemical properties of ambient PM are acquired continuously. Measurement data are as follows: (1) PM2.5 (PM with aerodynamic diameters < 2.5 μm) and PM10 (PM with aerodynamic diameters < 10 μm) mass concentrations; (2) PM2.5 compositions of sulfate, nitrate and carbon; (3) particle light scattering and absorption; (4) particle number concentrations in various size fractions between 10 nm and 20 μm; (5) related precursor gases such as NOy, H2O2, and NH3; and, (6) meteorological variables. Most measurements are unique to the study area and can be used to elucidate the causes of PM pollution and evaluate PM exposure and adverse health effects. In addition to describing the sampling location, measurements and data archiving, future challenges for the supersite are discussed as well.

[1]  Chung-te Lee,et al.  Aerosol characteristics from the Taiwan aerosol supersite in the Asian yellow-dust periods of 2002 , 2006 .

[2]  J. Chow,et al.  Dilution-based emissions sampling from stationary sources: Part 1--Compact sampler methodology and performance. , 2007, Journal of the Air & Waste Management Association.

[3]  B. Brunekreef,et al.  Air pollution and health , 2002, The Lancet.

[4]  C. Sioutas,et al.  Effects of sampling artifacts and operating parameters on the performance of a semicontinuous particulate elemental carbon/organic carbon monitor. , 2006, Environmental science & technology.

[5]  R. Burnett,et al.  Lung cancer, cardiopulmonary mortality, and long-term exposure to fine particulate air pollution. , 2002, JAMA.

[6]  P. Paatero Least squares formulation of robust non-negative factor analysis , 1997 .

[7]  M. Cheng,et al.  Visibility and aerosol chemical compositions near the coastal area in Central Taiwan , 1999 .

[8]  Chung-te Lee,et al.  Ozone variations through vehicle emissions reductions based on air quality monitoring data in Taipei City, Taiwan, from 1994 to 2003 , 2006 .

[9]  Philip K Hopke,et al.  A Special Issue of JA&WMA Supporting Key Scientific and Policy- and Health-Relevant Findings from EPA’s Particulate Matter Supersites Program and Related Studies: An Integration and Synthesis of Results , 2008, Journal of the Air & Waste Management Association.

[10]  Lien-Te Hsieh,et al.  Characterization of atmospheric PM10 and related chemical species in southern Taiwan during the episode days. , 2003, Chemosphere.

[11]  Judith C. Chow,et al.  PM2.5 chemical composition and spatiotemporal variability during the California Regional PM10/PM2.5 Air Quality Study (CRPAQS) , 2006 .

[12]  M. Cheng,et al.  Evaluation of formation rates of NO2 to gaseous and particulate nitrate in the urban atmosphere , 2007 .

[13]  K S Chen,et al.  Determination of Source Contributions to Ambient PM2.5 in Kaohsiung, Taiwan, Using a Receptor Model , 2001, Journal of the Air & Waste Management Association.

[14]  Kimberly A. Prather,et al.  Real-time measurement capabilities using aerosol time-of-flight mass spectrometry , 1994 .

[15]  F. Drewnick,et al.  Semicontinuous PM2.5 Sulfate and Nitrate Measurements at an Urban and a Rural Location in New York: PMTACS-NY Summer 2001 and 2002 Campaigns , 2004, Journal of the Air & Waste Management Association.

[16]  J. Chow,et al.  Dilution-Based Emissions Sampling from Stationary Sources: Part 2—Gas-Fired Combustors Compared with Other Fuel-Fired Systems , 2007, Journal of the Air & Waste Management Association.

[17]  J. Ondov,et al.  A new pseudodeterministic multivariate receptor model for individual source apportionment using highly time-resolved ambient concentration measurements : Particulate matter supersites , 2005 .

[18]  P. Solomon,et al.  Preface to special section on Particulate Matter: Atmospheric Sciences, Exposure, and the Fourth Colloquium on Particulate Matter and Human Health , 2004 .

[19]  John G. Watson,et al.  The effective variance weighting for least squares calculations applied to the mass balance receptor model , 1984 .

[20]  Shui-Jen Chen,et al.  Water-soluble ions in nano/ultrafine/fine/coarse particles collected near a busy road and at a rural site. , 2007, Environmental pollution.

[21]  P. Solomon,et al.  Secondary Particulate Matter in the United States: Insights from the Particulate Matter Supersites Program and Related Studies , 2008, Journal of the Air & Waste Management Association.

[22]  H. Tai,et al.  Concentrations and distributions of carbonaceous species in ambient particles in Kaohsiung City, Taiwan , 2001 .

[23]  S. Friedlander,et al.  Chemical element balances and identification of air pollution sources. , 1973, Environmental science & technology.

[24]  Cliff I. Davidson,et al.  Semi-continuous PM2.5 inorganic composition measurements during the Pittsburgh air quality study , 2004 .

[25]  David S. Thomson,et al.  Particle Analysis by Laser Mass Spectrometry WB-57F Instrument Overview , 2000 .

[26]  Prakash Doraiswamy,et al.  Advances in Integrated and Continuous Measurements for Particle Mass and Chemical Composition , 2008, Journal of the Air & Waste Management Association.

[27]  M. Cheng,et al.  Characteristics of gaseous HNO2, HNO3, NH3 and particulate ammonium nitrate in an urban city of Central Taiwan , 2006 .

[28]  Paul A. Solomon,et al.  Special issue of Atmospheric Environment for Particulate Matter: Atmospheric Sciences, Exposure, and the Fourth Colloquium on PM and Human Health , 2004 .

[29]  A. Robinson,et al.  Mass balance closure and the federal reference method for PM2.5 in Pittsburgh, Pennsylvania , 2004 .

[30]  Tan Zhu,et al.  Receptor modeling application framework for particle source apportionment. , 2002, Chemosphere.

[31]  Guido Visconti,et al.  Evolution of surface ozone in central Italy based on observations and statistical model , 2007 .

[32]  A. Wexler,et al.  What Have We Learned from Highly Time-Resolved Measurements during EPA’s Supersites Program and Related Studies? , 2008, Journal of the Air & Waste Management Association.

[33]  N. Englert Fine particles and human health--a review of epidemiological studies. , 2004, Toxicology letters.

[34]  Jorma Keskinen,et al.  On-line measurement of size distribution and effective density of submicron aerosol particles , 2002 .

[35]  Judith C. Chow,et al.  Evaluation of organic markers for chemical mass balance source apportionment at the Fresno Supersite , 2006 .

[36]  Susanne V. Hering,et al.  Method for the Automated Measurement of Fine Particle Nitrate in the Atmosphere , 2000 .

[37]  P. Hopke,et al.  Measurements of Fine Particle Mass Concentrations Using Continuous and Integrated Monitors in Eastern US Cities , 2005 .

[38]  P. Hopke,et al.  Measurement of Both Nonvolatile and Semi-Volatile Fractions of Fine Particulate Matter in Fresno, CA , 2006 .

[39]  Chuen-Jinn Tsai,et al.  Direct Field Observation of the Relative Humidity Effect on the β-Gauge Readings , 2006, Journal of the Air & Waste Management Association.

[40]  R Harkov,et al.  Health effects. , 1980, Journal of the Air Pollution Control Association.

[41]  P. Hopke,et al.  Evaluation of Continuous and Filter-Based Methods for Measuring PM2.5 Mass Concentration , 2005 .

[42]  Chung-te Lee,et al.  A GC-TCD method for measuring the liquid water mass of collected aerosols , 2002 .

[43]  Kenneth L. Rubow,et al.  A Microorifice Uniform Deposit Impactor (MOUDI): Description, Calibration, and Use , 1991 .

[44]  J. Chow,et al.  Air Quality Measurements from the Fresno Supersite , 2000, Journal of the Air & Waste Management Association.

[45]  Shui-Jen Chen,et al.  Characteristics of particles sampled in southern Taiwan during the Asian dust storm periods in 2000 and 2001 , 2004 .

[46]  Pen-Chi Chiang,et al.  Seasonal Source-Receptor Relationships in a Petrochemical Industrial District over Northern Taiwan , 2005, Journal of the Air & Waste Management Association.

[47]  Sverre Vedal,et al.  Ambient particles and health: lines that divide. , 1997, Journal of the Air & Waste Management Association.

[48]  C. Stanier,et al.  Water content of ambient aerosol during the Pittsburgh Air Quality Study : Particulate matter supersites , 2005 .

[49]  Kenneth A. Smith,et al.  Development of an Aerosol Mass Spectrometer for Size and Composition Analysis of Submicron Particles , 2000 .

[50]  Kai-Lun Chang,et al.  Mass-Size Distributions of Particulate Sulfate, Nitrate, and Ammonium in a Particulate Matter Nonattainment Region in Southern Taiwan , 2005, Journal of the Air & Waste Management Association.

[51]  Y. Tsai,et al.  PM2.5 aerosol water content and chemical composition in a metropolitan and a coastal area in southern Taiwan , 2005 .

[52]  M. Cheng,et al.  Improvement of receptor model use in analytical aspect , 2007 .

[53]  J. Schauer,et al.  Source Apportionment of Wintertime Gas-Phase and Particle-Phase Air Pollutants Using Organic Compounds as Tracers , 2000 .

[54]  L. Chen,et al.  Quantifying PM2.5 source contributions for the San Joaquin Valley with multivariate receptor models. , 2007, Environmental science & technology.

[55]  Source apportionment to PM10 in different air quality conditions for Taichung urban and coastal areas, Taiwan , 2004 .

[56]  Anthony S. Wexler,et al.  On-line chemical analysis of aerosols by rapid single-particle mass spectrometry , 1995 .

[57]  P. Solomon,et al.  Preface to special section on Particulate Matter Supersites Program and Related Studies , 2006 .

[58]  H. R. Anderson,et al.  Ambient Particulate Matter and Health Effects: Publication Bias in Studies of Short-Term Associations , 2005, Epidemiology.

[59]  J. Seinfeld,et al.  A comparison of particle mass spectrometers during the 1999 Atlanta Supersite Project , 2003 .

[60]  G. Migliaretti,et al.  Urban air pollution and asthma in children , 2004, Pediatric pulmonology.

[61]  P. Solomon,et al.  PrefaceSpecial issue of Atmospheric Environment for Particulate Matter Supersites Program and Related Studies , 2006 .

[62]  A. Comrie,et al.  Extending the Kolmogorov–Zurbenko Filter: Application to Ozone, Particulate Matter, and Meteorological Trends , 2005, Journal of the Air & Waste Management Association.

[63]  J. Lin,et al.  Characterization of n-alkanes in urban submicron aerosol particles (PM1) , 2004 .

[64]  P. Hopke,et al.  Performance evaluation of continuous PM 2.5 mass concentration monitors , 2005 .

[65]  J. Chow,et al.  A Special Issue of the Journal of the Air & Waste Management Association on the Particulate Matter Supersites Program and Related Studies , 2006 .

[66]  J. Vandenberg,et al.  Research priorities: airborne particulate matter , 2001 .

[67]  Judith C. Chow,et al.  Source Apportionment: Findings from the U.S. Supersites Program , 2008, Journal of the Air & Waste Management Association.

[68]  William E. Wilson,et al.  Measurement of total PM2.5 mass (nonvolatile plus semivolatile) with the Filter Dynamic Measurement System tapered element oscillating microbalance monitor , 2005 .

[69]  Xin Wang,et al.  The Relationship between Mass and Mobility for Atmospheric Particles: A New Technique for Measuring Particle Density , 2002 .

[70]  John G. Watson,et al.  Overview of Receptor Model Principles , 1984 .

[71]  A. Robinson,et al.  Application of the Pseudo-Deterministic Receptor Model to Resolve Power Plant Influences on Air Quality in Pittsburgh , 2006 .

[72]  J. Chow,et al.  Health effects of organic aerosols. , 2008, Inhalation toxicology.

[73]  J C Chow,et al.  Measurement methods to determine compliance with ambient air quality standards for suspended particles. , 1995, Journal of the Air & Waste Management Association.

[74]  Igor G. Zurbenko,et al.  Space and Time Scales in Ambient Ozone Data , 1997 .

[75]  J. Seinfeld Atmospheric Chemistry and Physics of Air Pollution , 1986 .

[76]  R. Harrison,et al.  What is responsible for the carcinogenicity of PM2.5? , 2004, Occupational and Environmental Medicine.

[77]  D. Dockery,et al.  Health Effects of Fine Particulate Air Pollution: Lines that Connect , 2006, Journal of the Air & Waste Management Association.

[78]  G. Fang,et al.  Source identifications of PM10 aerosols depending on hourly measurements of soluble components characterization among different events in Taipei Basin during spring season of 2004. , 2006, Chemosphere.

[79]  P. Solomon,et al.  Special Issue of Aerosol Science and Technology for Particulate Matter: Atmospheric Sciences, Exposure, and the Fourth Colloquium on PM and Human Health , 2004 .

[80]  David R. Turner,et al.  Determination of pH , 2007 .

[81]  Mei-Lien Chen,et al.  The PM2.5 and PM10 particles in urban areas of Taiwan. , 1999, The Science of the total environment.

[82]  Hans Moosmüller,et al.  Emissions from laboratory combustion of wildland fuels: emission factors and source profiles. , 2007, Environmental science & technology.

[83]  M. Cheng,et al.  Characterization of chemical species in atmospheric aerosols in a metropolitan basin. , 2004, Chemosphere.

[84]  Chuan-Yao Lin,et al.  Long-range transport of aerosols and their impact on the air quality of Taiwan. , 2005 .

[85]  P. Solomon,et al.  Special Issue of Aerosol Science and Technology for Particulate Matter Supersites Program and Related Studies , 2006 .

[86]  G. Fang,et al.  Traffic aerosols (18 nm ≤particle size≤18 μm) source apportionment during the winter period , 2006 .

[87]  J. Lin Characterization of the major chemical species in PM2.5 in the Kaohsiung City, Taiwan , 2002 .

[88]  Igor G. Zurbenko,et al.  Separating Different Scales of Motion in Time Series of Meteorological Variables. , 1997 .

[89]  Anthony S. Wexler,et al.  MS of INDIVIDUAL AEROSOL PARTICLES , 1995 .

[90]  Constantinos Sioutas,et al.  Continuous and Semicontinuous Monitoring Techniques for Particulate Matter Mass and Chemical Components: A Synthesis of Findings from EPA’s Particulate Matter Supersites Program and Related Studies , 2008, Journal of the Air & Waste Management Association.

[91]  C. Lai,et al.  Trends in Concentration of Ground-Level Ozone and Meteorological Conditions during High Ozone Episodes in the Kao-Ping Airshed, Taiwan , 2004, Journal of the Air & Waste Management Association.

[92]  H Patashnick,et al.  Development of a Sample Equilibration System for the TEOM Continuous PM Monitor , 2000, Journal of the Air & Waste Management Association.

[93]  S. Liu,et al.  The continuous field measurements of soluble aerosol compositions at the Taipei Aerosol Supersite, Taiwan , 2007 .

[94]  J. Schauer,et al.  Validation of a semi-continuous instrument for elemental carbon and organic carbon using a thermal-optical method , 2004 .

[95]  J. Chow,et al.  The application of thermal methods for determining chemical composition of carbonaceous aerosols: A review , 2007, Journal of environmental science and health. Part A, Toxic/hazardous substances & environmental engineering.

[96]  Bill Taylor,et al.  Trend analysis of ground level ozone in the greater Vancouver/Fraser Valley area of British Columbia , 2003 .

[97]  Wen-Yinn Lin,et al.  Characteristics of metals in nano/ultrafine/fine/coarse particles collected beside a heavily trafficked road. , 2005, Environmental science & technology.

[98]  J. Chow,et al.  Comparison of Continuous and Filter-Based Carbon Measurements at the Fresno Supersite , 2006, Journal of the Air & Waste Management Association.

[99]  D. Dockery,et al.  Climate, traffic-related air pollutants, and asthma prevalence in middle-school children in taiwan. , 1999, Environmental health perspectives.

[100]  D. Peden The epidemiology and genetics of asthma risk associated with air pollution. , 2005, The Journal of allergy and clinical immunology.

[101]  R. Henry History and fundamentals of multivariate air quality receptor models , 1997 .