Effects of operating temperatures on performance and pressure drops for a 256 cm2 proton exchange membrane fuel cell: An experimental study

Abstract Cell performance and pressure drop were experimentally investigated for two commercial size 16 cm × 16 cm serpentine flow field proton exchange membrane fuel cells with Core 5621 and Core 57 membrane electrode assemblies at various cell temperatures and humidification temperatures. At cell temperature lower than the humidification temperature, the cell performance improved as the cell temperature increased, while reversely at cell temperature higher than the humidification temperature. At a specified cell temperature, increasing the cathode and/or anode humidification temperature improved the cell performance, and their effects weakened as cell temperature decreased. The effects of the cell and the humidification temperature on the pressure drops were closely related to the reactant feed mode. For the constant stoichiometric flow rate mode, both cathode and anode pressure drops increased as humidification temperature and average current density increased. For the constant mass flow rate mode, both cathode and anode pressure drops increased as humidification temperature increased, while anode pressure drops decreased and cathode pressure drops increased as average current density increased. The optimal cell performance occurred at cell temperature of 65 °C and humidification temperature of 70 °C. The effects of these operating parameters on the cell performance and pressure drop were analyzed based on the catalytic activity, membrane hydration, and cathode flooding.

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