Novel cement systems (sustainability). Session 2 of the Fred Glasser Cement Science Symposium

The significant and persistent demand for concrete in meeting modern infrastructure requirements, particularly in developing economies, presents an increasing challenge to the global community. Portland cement is an important constituent of constructional concrete but its production emits about 0·8 t of carbon dioxide per tonne and Portland cement must now be considered together with alternative binders if environmental impacts of construction are to be reduced. The present paper addresses this sustainability issue and places the current position, in which Portland cements are commonly blended with supplementary cementitious materials, into context with binders that are emerging as candidates for more radical chemistry changes, the details of which are also presented.

[1]  C. D. Lawrence,et al.  Calcium sulfoaluminate cements—low-energy cements, special cements or what? , 1999 .

[2]  J. Phair Green chemistry for sustainable cement production and use , 2006 .

[3]  I. Richardson Tobermorite/jennite- and tobermorite/calcium hydroxide-based models for the structure of C-S-H: applicability to hardened pastes of tricalcium silicate, β-dicalcium silicate, Portland cement, and blends of Portland cement with blast-furnace slag, metakaolin, or silica fume , 2004 .

[4]  J. H. Sharp,et al.  Chemical reactions between magnesia and aluminium orthophosphate to form magnesia-phosphate cements , 1989 .

[5]  Liang Zhang,et al.  Development of the use of sulfo- and ferroaluminate cements in China , 1999 .

[6]  J. Depasse,et al.  The stability of amorphous colloidal silica , 1970 .

[7]  J. Davidovits Recent Progresses in Concretes for Nuclear Waste and Uranium Waste Containment , 1994 .

[8]  J. Deventer,et al.  Geopolymer technology: the current state of the art , 2007 .

[9]  John H. Sharp,et al.  The microstructure and mechanical properties of mortars made from magnesia-phosphate cement , 1989 .

[10]  Kostas Komnitsas,et al.  Geopolymerisation: A review and prospects for the minerals industry , 2007 .

[11]  R. Iler,et al.  The Colloid Chemistry of Silica and Silicates , 1955 .

[12]  John H. Sharp,et al.  The chemical composition of mortars made from magnesia-phosphate cement , 1988 .

[13]  L. Glasser,et al.  On the role of calcium in the alkali-aggregate reaction , 1982 .