From Electrochemical Biosensors to Biomimetic Sensors Based on Molecularly Imprinted Polymers in Environmental Determination of Heavy Metals

Recent work relevant to heavy metal determination by inhibition-enzyme electrochemical biosensors and by selected biomimetic sensors based on molecularly imprinted polymers has been reviewed. General features and peculiar aspects have been evidenced. The replace of biological component by artificial receptors promises higher selectivity and stability, while biosensors keep their capability of producing an integrated response directly related to biological toxicity of the samples.

[1]  L. C. Clark,et al.  ELECTRODE SYSTEMS FOR CONTINUOUS MONITORING IN CARDIOVASCULAR SURGERY , 1962 .

[2]  G. Wallace,et al.  Poly(pyrrole-N-carbodithioate) electrode for electroanalysis , 1986 .

[3]  Antonio Turco,et al.  Inhibitive determination of metal ions by an amperometric glucose oxidase biosensor: Study of the effect of hydrogen peroxide decomposition , 2008 .

[4]  Ali R. Zanganeh,et al.  Polypyrrole-modified electrodes with induced recognition sites for potentiometric and voltammetric detection of copper(II) ion , 2008 .

[5]  Yun Zhang,et al.  Highly sensitive and doubly orientated selective molecularly imprinted electrochemical sensor for Cu(2.). , 2015, Biosensors & bioelectronics.

[6]  Nicole Jaffrezic-Renault,et al.  An enzyme biosensor based on beta-galactosidase inhibition for electrochemical detection of cadmium (II) and chromium (VI) , 2016 .

[7]  P. Kulkarni,et al.  Highly selective monitoring of metals by using ion-imprinted polymers , 2015, Environmental Science and Pollution Research.

[8]  Farzaneh Hashemi,et al.  Electrochemically induced regioregularity of the binding sites of a polyaniline membrane as a powerful approach to produce selective recognition sites for silver ion , 2016 .

[9]  G. Rounaghi,et al.  Electrochemical synthesis of Alizarin Red S doped polypyrrole and its applications in designing a novel silver (I) potentiometric and voltammetric sensor , 2015 .

[10]  M R Guascito,et al.  Heavy metal determination by biosensors based on enzyme immobilised by electropolymerisation. , 2005, Biosensors & bioelectronics.

[11]  M. K. Amini,et al.  A potentiometric and voltammetric sensor based on polypyrrole film with electrochemically induced recognition sites for detection of silver ion , 2007 .

[12]  K. Stevenson,et al.  Amperometric Detection of Aqueous Silver Ions by Inhibition of Glucose Oxidase Immobilized on Nitrogen-Doped Carbon Nanotube Electrodes. , 2015, Analytical chemistry.

[13]  E. Iwuoha,et al.  Amperometric determination of cadmium, lead, and mercury metal ions using a novel polymer immobilised horseradish peroxidase biosensor system , 2014, Journal of environmental science and health. Part A, Toxic/hazardous substances & environmental engineering.

[14]  Shaojun Dong,et al.  Chloride chemical sensor based on an organic conducting polypyrrole polymer , 1988 .

[15]  G. Palleschi,et al.  Recent advances in biosensors based on enzyme inhibition. , 2016, Biosensors & bioelectronics.

[16]  C. Brett,et al.  Poly(neutral red) based hydrogen peroxide biosensor for chromium determination by inhibition measurements. , 2014, Journal of hazardous materials.

[17]  Sergey A. Piletsky,et al.  MIP sensors – the electrochemical approach , 2012, Analytical and Bioanalytical Chemistry.

[18]  Rahele Zhiani,et al.  Selective voltammetric sensor for nanomolar detection of silver ions using carbon paste electrode modified with novel nanosized Ag(I)-imprinted polymer , 2016 .

[19]  Yan Deng,et al.  Progress on sensors based on nanomaterials for rapid detection of heavy metal ions , 2017, Science China Chemistry.

[20]  Prashant K. Sharma,et al.  Simultaneous determination of heavy metals in biological samples by a multiple-template imprinting technique: an electrochemical study , 2014 .

[21]  Y. Shim,et al.  Characterization of an EDTA bonded conducting polymer modified electrode: its application for the simultaneous determination of heavy metal ions. , 2003, Analytical chemistry.

[22]  A. Turco,et al.  XPS in development of chemical sensors , 2015 .

[23]  S. Zaidi.  Molecular imprinting polymers and their composites: a promising material for diverse applications. , 2017, Biomaterials science.

[24]  Xingjiu Huang,et al.  Stripping voltammetric detection of mercury(II) based on a surface ion imprinting strategy in electropolymerized microporous poly(2-mercaptobenzothiazole) films modified glassy carbon electrode. , 2011, Analytica chimica acta.

[25]  M. Moyo,et al.  An amperometric biosensor based on horseradish peroxidase immobilized onto maize tassel-multi-walled carbon nanotubes modified glassy carbon electrode for determination of heavy metal ions in aqueous solution. , 2014, Enzyme and microbial technology.

[26]  Nishant Verma,et al.  Enzyme Inhibition Based Biosensors: A Review , 2013 .

[27]  Huangxian Ju,et al.  Electrochemical sensing of heavy metal ions with inorganic, organic and bio-materials. , 2015, Biosensors & bioelectronics.

[28]  Antonio Turco,et al.  Screen-Printed Glucose Oxidase-Based Biosensor for Inhibitive Detection of Heavy Metal Ions in a Flow Injection System , 2009 .

[29]  M. Mazloum‐Ardakani,et al.  Preparation of Cu (II) imprinted polymer electrode and its application for potentiometric and voltammetric determination of Cu (II) , 2014, Journal of the Iranian Chemical Society.

[30]  S. Adeloju,et al.  Inhibitive potentiometric detection of trace metals with ultrathin polypyrrole glucose oxidase biosensor. , 2015, Talanta.