Enhancement of barrier and corrosion protection performance of an epoxy coating through wet transfer of amino functionalized graphene oxide

Abstract An amino functionalized graphene oxide (FGO) was synthesized and characterized by Fourier transform infrared spectroscopy (FTIR) and X-Ray diffraction analysis (XRD). Then, FGO/epoxy composite was prepared through dispersing 0.1 wt.% of FGO in an epoxy coating through wet transfer method (WTM). The GO/epoxy and FGO/epoxy composites were applied on the mild steel substrates and their barrier and corrosion protection performance were characterized by salt spray test and electrochemical impedance spectroscopy (EIS). Incorporation of 0.1 wt.% of FGO nanosheets into the epoxy coating significantly enhanced the corrosion resistance of the coating through improving its ionic resistance as well as barrier properties.

[1]  S. Allahkaram,et al.  Corrosion resistance enhancement of Ni–P electroless coatings by incorporation of nano-SiO2 particles , 2011 .

[2]  D. Dikin,et al.  Graphene Oxide Sheets Chemically Cross-Linked by Polyallylamine , 2009 .

[3]  Yi He,et al.  Preparation of graphene oxide modified by titanium dioxide to enhance the anti-corrosion performance of epoxy coatings , 2015 .

[4]  F. Sharif,et al.  Graphene oxide‐induced polymerization and crystallization to produce highly conductive polyaniline/graphene oxide composite , 2014 .

[5]  S. Pour-Ali,et al.  Corrosion protection of the reinforcing steels in chloride-laden concrete environment through epoxy/polyaniline–camphorsulfonate nanocomposite coating , 2015 .

[6]  Derrek E. Lobo,et al.  Protecting copper from electrochemical degradation by graphene coating , 2012 .

[7]  B. Ramezanzadeh,et al.  A study on the anticorrosion performance of the epoxy–polyamide nanocomposites containing ZnO nanoparticles , 2011 .

[8]  A. M. van der Zande,et al.  Impermeable atomic membranes from graphene sheets. , 2008, Nano letters.

[9]  A. Pakdel,et al.  Influence of nanoclay particles modification by polyester-amide hyperbranched polymer on the corrosion protective performance of the epoxy nanocomposite , 2015 .

[10]  B. Ramezanzadeh,et al.  Studying the effects of micro and nano sized ZnO particles on the corrosion resistance and deterioration behavior of an epoxy-polyamide coating on hot-dip galvanized steel , 2011 .

[11]  Lian-Kui Wu,et al.  Silane-incorporated epoxy coatings on aluminum alloy (AA2024). Part 2: Mechanistic investigations , 2015 .

[12]  M. Tamilselvi,et al.  Development of nano SiO2 incorporated nano zinc phosphate coatings on mild steel , 2015 .

[13]  L. Brossard,et al.  Corrosion protective performances of commercial low-VOC epoxy/urethane coatings on hot-rolled 1010 mild steel , 1997 .

[14]  Roberto Car,et al.  Functionalized single graphene sheets derived from splitting graphite oxide. , 2006, The journal of physical chemistry. B.

[15]  F. Sharif,et al.  Enhancement of dispersion and bonding of graphene-polymer through wet transfer of functionalized graphene oxide , 2012 .

[16]  Tong Liu,et al.  Structure stability and corrosion resistance of nano-TiO2 coatings on aluminum in seawater by a vacuum dip-coating method , 2010 .

[17]  A. Ghanbari,et al.  A study on the anticorrosion performance of epoxy nanocomposite coatings containing epoxy-silane treated nano-silica on mild steel substrate , 2015 .

[18]  R. Kaner,et al.  Honeycomb carbon: a review of graphene. , 2010, Chemical reviews.

[19]  X. Sun,et al.  Graphene grown on stainless steel as a high-performance and ecofriendly anti-corrosion coating for polymer electrolyte membrane fuel cell bipolar plates , 2015 .

[20]  V. Mišković‐Stanković,et al.  The corrosion behaviour of epoxy-resin electrocoated steel , 1992 .

[21]  Yaqing Liu,et al.  Mechanical and Anticorrosive Properties of Graphene/Epoxy Resin Composites Coating Prepared by in-Situ Method , 2015, International journal of molecular sciences.

[22]  Lei Song,et al.  One-pot surface functionalization and reduction of graphene oxide with long-chain molecules: Preparation and its enhancement on the thermal and mechanical properties of polyurea , 2014 .

[23]  Y. Li,et al.  The influence of the chemically bonded interface between fillers and binder on the failure behaviour of an epoxy coating under marine alternating hydrostatic pressure , 2015 .

[24]  K. Bolotin,et al.  Graphene: corrosion-inhibiting coating. , 2012, ACS nano.

[25]  S. Keera,et al.  Effect of nano-TiO2 particles size on the corrosion resistance of alkyd coating , 2014 .

[26]  Jian-er Zhou,et al.  Separating nano graphene oxide from the residual strong-acid filtrate of the modified Hummers method with alkaline solution , 2015 .

[27]  Junyong Kang,et al.  Oxidation resistance of graphene-coated Cu and Cu/Ni alloy. , 2011, ACS nano.

[28]  William Regan,et al.  Graphene as a long-term metal oxidation barrier: worse than nothing. , 2013, ACS nano.

[29]  J. Pan,et al.  In-situ AFM and EIS study of a solventborne alkyd coating with nanoclay for corrosion protection of carbon steel , 2015 .

[30]  Cheng-Kuo Lee Fabrication, characterization and wear corrosion testing of bioactive hydroxyapatite/nano-TiO2 composite coatings on anodic Ti–6Al–4V substrate for biomedical applications , 2012 .

[31]  B. Ramezanzadeh,et al.  The application of benzimidazole and zinc cations intercalated sodium montmorillonite as smart ion exchange inhibiting pigments in the epoxy ester coating , 2015 .

[32]  M. Rajabi,et al.  Assessment of graphene oxide/epoxy nanocomposite as corrosion resistance coating on carbon steel , 2015 .

[33]  Yuzhi Zhang,et al.  Influence of SiO2 nano-particles on microstructures and properties of Ni-W-P/CeO2-SiO2 composites prepared by pulse electrodeposition , 2010 .

[34]  S. Hiromoto Self-healing property of hydroxyapatite and octacalcium phosphate coatings on pure magnesium and magnesium alloy , 2015 .

[35]  F. Sharif,et al.  Highly aligned, ultralarge-size reduced graphene oxide/polyurethane nanocomposites: Mechanical properties and moisture permeability , 2013 .

[36]  Jiang Xu,et al.  A study of the erosion–corrosion behavior of nano-Cr2O3 particles reinforced Ni-based composite alloying layer in aqueous slurry environment , 2011 .

[37]  Xiaoling Liu,et al.  Using high-temperature mechanochemistry treatment to modify iron oxide and improve the corrosion performance of epoxy coating – II. Effect of grinding temperature , 2015 .

[38]  A. Khanna,et al.  “Effect of nano-ZnO particles on the corrosion behavior of alkyd-based waterborne coatings” , 2009 .

[39]  B. Ramezanzadeh,et al.  Studying the corrosion resistance and hydrolytic degradation of an epoxy coating containing ZnO nanoparticles , 2011 .

[40]  Z. Klusek,et al.  Impact of electrolyte intercalation on the corrosion of graphene-coated copper , 2015 .

[41]  Q. Xue,et al.  Excellent tribological and anti-corrosion performance of polyurethane composite coatings reinforced with functionalized graphene and graphene oxide nanosheets , 2015 .

[42]  Lian-Kui Wu,et al.  Silane-incorporated epoxy coatings on aluminum alloy (AA2024). Part 1: Improved corrosion performance , 2015 .

[43]  B. Jena,et al.  The production of a corrosion resistant graphene reinforced composite coating on copper by electrophoretic deposition , 2013 .

[44]  Yi He,et al.  Fabrication of graphene oxide–alumina hybrids to reinforce the anti-corrosion performance of composite epoxy coatings , 2015 .

[45]  A. H. Navarchian,et al.  Investigation of corrosion protection performance of epoxy coatings modified by polyaniline/clay nanocomposites on steel surfaces , 2014 .

[46]  B. Ramezanzadeh,et al.  A study on the corrosion inhibition properties of silane-modified Fe2O3 nanoparticle on mild steel and its effect on the anticorrosion properties of the polyurethane coating , 2015, Journal of Coatings Technology and Research.

[47]  Jian-er Zhou,et al.  Effects of particle size and pH value on the hydrophilicity of graphene oxide , 2013 .

[48]  A. Khanna,et al.  Effect of nano-Fe2O3 particles on the corrosion behavior of alkyd based waterborne coatings , 2009 .

[49]  B. Ramezanzadeh,et al.  Investigation of corrosion protection properties of an epoxy nanocomposite loaded with polysiloxane surface modified nanosilica particles on the steel substrate , 2015 .

[50]  B. Ramezanzadeh,et al.  Studying the influence of nano-Al2O3 particles on the corrosion performance and hydrolytic degradation resistance of an epoxy/polyamide coating on AA-1050 , 2014 .

[51]  Roland G. S. Goh,et al.  Band‐like Transport in Surface‐Functionalized Highly Solution‐Processable Graphene Nanosheets , 2008 .

[52]  H. Sarpoolaky,et al.  Effect of heat treatment temperature on the performance of nano-TiO2 coating in protecting 316L stainless steel against corrosion under UV illumination and dark conditions , 2014 .

[53]  Jun Zeng,et al.  Preparation and anticorrosion property of poly(2,3-dimethylaniline) modified by nano-SiO2 , 2014 .

[54]  B. Mert Corrosion protection of aluminum by electrochemically synthesized composite organic coating , 2016 .

[55]  S. Bless,et al.  Stone impact damage to automotive paint finishes: An introduction to impact physics and impact induced corrosion , 1994 .

[56]  Wen Sun,et al.  Liquid-phase exfoliated fluorographene as a two dimensional coating filler for enhanced corrosion protection performance , 2016 .

[57]  B. Ramezanzadeh,et al.  Covalently-grafted graphene oxide nanosheets to improve barrier and corrosion protection properties of polyurethane coatings , 2015 .